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Problem 1 (10 pts) Draw the major product (monoalkylation) and propose a mechanism for its formation....
Which of the reactions will yield the indicated compound as the major product? Check all that apply. CI (i) CI ♡ CI 1. HNO3, H2SO4 2. HN(CH3)2 NO2 CI (ii) 1. HNO3, H2SO4 2. HN(CH3)2 NO2 CI CI (iii) OCH3 OCH3 1. HNO3, H2SO4 2. HN(CH3)2 O2N CI (iv) OCH3 1. NaN(CH3)2, HN(CH3)2 OCHZ 2. Br2 Br H2C H2C CI (v) H3C AICI: H3C CH3 CH3 (vi) H2N 1) HNO3, H2SO4 HN 2) NaOH, H2O NO2
Question 1 20 pts What is the major product of the following reaction? CH3 + Brz/FeBr3 NO2 CH3 A. NO2 Br CH3 B. Br NO2
draw major products of the following reactions b) (3 pts) Br HNO3 H2SO4 c) (3 pts) OCH, Brz FeBrg d. (3 pts) AICI: e) (4 pts) HNO3 Cl2 H2SO4 AICI
(#2) Draw the structure of the major organic mono-substituted product. Draw all bonds except C-H. Draw all lone pairs. (~15Pts) (a) O'Bu O'Bu Cla. FeCla (b) CF3 CF3 CH,сосI AICI (c) OCH3 осн, HNO3, H2SO4 Н,с Нас CH3 CH3 (d) Br Br Me N Me N So3 В H2SO4 Bг CN CN (e) NH3CI NH3CI HNO3, H2SO4
Draw the product(s) of the following reactions HNO,/H2SO а. Br b. AICI он So/H2SO C. Он Br/FeBr3 d. HNO3/H2SO4 Br e. OCH3 H3CO. f. AICI OCH3 но g. AICI NO3 Bro/FeBr3 h.
1. Provide a reasonable mechanism to account for the following reaction. 3. Propose a reasonable mechanism for the following reactions. 7. Propose a mechanism for the formation of the following products. NO2 H2SO4 HNO; Br Br AICI: + CI Br FeBrz AICI: -CI
How many siginals in 13 C-NMR spectrum are expected from this compound? tay 10 5 8 11 ود 1) (CH3)2Culi 2) H30 What is the major product of the reaction? را O OH C ОН HNO, H2SO4 CH BINOZ Which of the following is the correct intermediate for the above reaction? Br 28 NOZ Br NO2 Br NOZ BI NO CH3 Br -& NO2 What is the best method to synthesize the above compound? Brz HNO3 CH3CI FeBra Haso. AICI:...
4. (5 pts) Draw a complete, step by step mechanism to account for the formation of following product. Draw all the resonance structures of the intermediate and indicate which one is the major resonance contributor. осна OCH3 Br2 FeBr3
12) Identify the product for the following reaction? 2 Pts осн, CN Bry/FeBry NO2 осн. OCH3 .CN OCH CN осн, CN CN Br B) A) D) Br Br Br NOZ NOZ NOZ NO2 13) Propose an efficient synthesis for the following transformations? (Multistep Synthesis) 8 Pt NO2 A) ♡ NH2 B)
7 (2 pts). Which of the following reactions will proceed well to give the indicated compounds as the major products? Check all that apply. (0) So 1. HNO3, H,SO 2. HN(CH3)2 NO2 N (ii) 1. HNO3, H2SO4 2. HN (CH3)2 NO2 ci CI N (iii) OCH OCH, 1. HNO3, H,SO 2. HN(CH3)2 ON `N (iv) Осн. Осно 1. NaN(CH3)2, HN(CH3)2 2. Brz Br нас. нас (v) H2C AICI HC CH3 CH3 vi) HN HN 1) HNO3 H2SO4 2) NaOH, H2O...