(Organic chemistry 2) 8. Mark and Tom serendipitously prepared a novel organic compound “X”. 1 H NMR spectroscopic analysis of X revealed six signals including (a) singlet (integration = 9H), (b) doublet (integration = 3H), (c) doublet of doublet of quartet (integration = 1H), (d) doublet of doublet (integration = 1H); (e) doublet of doublet (integration = 1H); (f) broad singlet (integration = 1H).
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(Organic chemistry 2) 8. Mark and Tom serendipitously prepared a
novel organic compound “X”. 1 H...
2. Use the 'H NMR and IR data to determine the structure of the following compounds...
2. Use the 'H NMR and IR data to determine the structure of the following compounds and name them. Compound A Molecular formula: CroH IR absorptions at N/A H NMR data: 1.3 (singlet, 9H), 7.0 to 7.5 (multiplet, 5H) ppm Compound B Molecular formula: CHO IR absorptions at 1H NMR data: 1735-1745, 1050 cm 0.93 (doublet, 6H), 1.52 (multiplet, 2H), 1.69 (multiplet, 1H), 2.04 (singlet, 3H), and 4.10 (triplet,2H) ppm Compound C Molecular ion: IR absorptions at 1710 cm 1H...
4. Consider the following two diastercomers: Both compounds generate 'H NMR spectra with the following signals:...
4. Consider the following two diastercomers: Both compounds generate 'H NMR spectra with the following signals: A multiplet between 7.20-7.63 ppm with an integration of 5H Two separate doublets between 5.70-6.50 ppm, each with an integration of 1H A singlet around 1.30 ppm with an integration of 9H Despite the similarities, how could you differentiate between the H NMR spectra of these isomers? 5. Assign each set of protons to their appropriate signals in the 'H NMR spectrum shown below....
and draw the Structures Determine the Hydrogen Deficiency Index Challenges: C4H8O2 1.2 8: 3H triplet 3.0...
and draw the Structures Determine the Hydrogen Deficiency Index Challenges: C4H8O2 1.2 8: 3H triplet 3.0 8: 2H quartet 3.6 8: 3H singlet CoH14 1.3 8: 9H singlet 7.2 8:5H multiplet C&H;N 3.7 8:2H singlet 7.2 8:5H singlet C.H.CI,O2 1.4 8: 3H triplet 4.3 8: 2H quartet 5.9 8: 1H singlet CsH1002 1.2 8:6H doublet 2.0 8:3H singlet 5.0 8: 1H septet 'H NMR Practice Problems Best thing is to first determine the Hydrogen Deficiency Index so you know the...
formula: C10H12O2 determine structure given the IR and H NMR Compound 2 Data Page Compound 2...
formula: C10H12O2
determine structure given the IR and H NMR
Compound 2 Data Page Compound 2 Exact Mass: 164.0837 amu Compound 2 FTIR Compound 2 1H-NMR Coupling Pattern Coupling Constant, J (Hz) 10 Signal Chemical Shift Relative Integration (ppm) A 6.83 B 6. 82 1 C 6. 811 D 6 .291 1 E 6.049 1 F 5. 731 G3. 8123 J 1.830 3 Singlet Doublet Doublet Doublet of quartets Doublet of quartets Broad Singlet Singlet Doublet of Doublets Not determined...
2. An organic compound E has the molecular formula C12Hi7NO gives spectroscopic data as follow: a)...
2. An organic compound E has the molecular formula C12Hi7NO gives spectroscopic data as follow: a) IR (KBR Disc): Amux 3296, 1642 cm b) 'H NMR (CDCl) : 6 0.93 (, 3H); 1.48 (d, 3H); 1.66 (sextet, 2HD) 2.15 (G, 2H); 5.14 (q, 1H):5.74 (broad, s, exchange with D20, 1H); 7.42-7.23 (m, 5H) i3C NMR (CDCl;) : δ 13.7 (q); 19.1 (t); 21.7 (q); 38.8 (t); 48.5 (d); 126.1 (d): 127.3 (d); 128.6 (d); 143.0 (s); 172.0 (s) c) d)...
I need help with scheme 1 please. Scheme 1: Compound 1 Compound 2 (b) OH (a)...
I need help with scheme 1 please.
Scheme 1: Compound 1 Compound 2 (b) OH (a) + OH Compound 3 Compound 4 Scheme 2: pka increased from 3 (salicylic acid) to 8.5 (Compound 1) H: 607 Laboratory Data: Compound 1: MW: 166.18 C. 65.05 0:28.88 Compound 2: MW: 167.00 C: 28.77 IR: 1739 cm (broad, strong) 'H NMR: H: 423 Br. 47.85 O: 19.15 singlet, 2H quartet, 2H triplet, 3H 2 PPM 13C NMR: 180 160 140 120 100 PPM...
give the structure 30 Unsat. Index = (2C+2-H-X + NY2 = 200 25 4.90 f 1.27...
give the structure
30 Unsat. Index = (2C+2-H-X + NY2 = 200 25 4.90 f 1.27 ppm, 20 720 Compound 18a: C, H. e = 2.00 ppm singlet, 2H d = 2.66 ppm quartet, 2H triplet, 3H 15 a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H c = 4.90 ppm, singlet, 2H 1.0 265 125 7.17 0.5 00 20 75 70 60 55 8, ppm 50 4.0 35 1 H2O, H,O*, heat 45 30 25 20...
Hi could you help me with this problem please? The following spectroscopic data were obtained for...
Hi could you help me with this problem please? The following spectroscopic data were obtained for an organic compound: i. MS (relative abundance in parentheses): M+ = 86 ; signals at 29 (92) and 41 (100) among others ii. IR (cm-1): 3100 (weak sharp), 2970 (medium sharp), 2850 (medium), 1650 (weak sharp), 1100 (strong sharp) iii. H1 NMR : Signal A at 4 ppm (3H, triplet), Signal B at 3.53 ppm (2H quartet), Signal C at 4.01...
practice quiz 1. (3 pts) For each of the following compounds, indicate whether the two protons...
practice quiz
1. (3 pts) For each of the following compounds, indicate whether the two protons shown are homotopic, enantiotopic, or diastereotopic. 2. (8 pts) Indicate the number of signals each of the following compounds would show in their 'Hand C NMR spectra: OME 'H__ _ H__ __ H__ __ H__ "C 3. (10 pts) For each of the following compounds, determine the multiplicity of each signal in the H NMR spectrum: la xiu ood ex gx x x 4....
10. Which compound is likely to have the following 'H NMR spectrum (integration is not given)?...
10. Which compound is likely to have the following 'H NMR spectrum (integration is not given)? 64 Singlet 2 quartet 1 triplet a) CHOCH.CH c) CH3OQCH.CH d) CH3CH2CCH.CH 11. Compound W has the formula CsH10. a) How many units of unsaturation does w have? Show your work b) The 'H NMR spectrum has the following signals: 1 H a 9.5 singlet 9H a 1.0 singlet What is the structure of W? Partial credit for anything you can say about the...
2. Use the 'H NMR and IR data to determine the structure of the following compounds and name them. Compound A Molecular formula: CroH IR absorptions at N/A H NMR data: 1.3 (singlet, 9H), 7.0 to 7.5 (multiplet, 5H) ppm Compound B Molecular formula: CHO IR absorptions at 1H NMR data: 1735-1745, 1050 cm 0.93 (doublet, 6H), 1.52 (multiplet, 2H), 1.69 (multiplet, 1H), 2.04 (singlet, 3H), and 4.10 (triplet,2H) ppm Compound C Molecular ion: IR absorptions at 1710 cm 1H...
4. Consider the following two diastercomers: Both compounds generate 'H NMR spectra with the following signals: A multiplet between 7.20-7.63 ppm with an integration of 5H Two separate doublets between 5.70-6.50 ppm, each with an integration of 1H A singlet around 1.30 ppm with an integration of 9H Despite the similarities, how could you differentiate between the H NMR spectra of these isomers? 5. Assign each set of protons to their appropriate signals in the 'H NMR spectrum shown below....
and draw the Structures Determine the Hydrogen Deficiency Index Challenges: C4H8O2 1.2 8: 3H triplet 3.0 8: 2H quartet 3.6 8: 3H singlet CoH14 1.3 8: 9H singlet 7.2 8:5H multiplet C&H;N 3.7 8:2H singlet 7.2 8:5H singlet C.H.CI,O2 1.4 8: 3H triplet 4.3 8: 2H quartet 5.9 8: 1H singlet CsH1002 1.2 8:6H doublet 2.0 8:3H singlet 5.0 8: 1H septet 'H NMR Practice Problems Best thing is to first determine the Hydrogen Deficiency Index so you know the...
formula: C10H12O2
determine structure given the IR and H NMR
Compound 2 Data Page Compound 2 Exact Mass: 164.0837 amu Compound 2 FTIR Compound 2 1H-NMR Coupling Pattern Coupling Constant, J (Hz) 10 Signal Chemical Shift Relative Integration (ppm) A 6.83 B 6. 82 1 C 6. 811 D 6 .291 1 E 6.049 1 F 5. 731 G3. 8123 J 1.830 3 Singlet Doublet Doublet Doublet of quartets Doublet of quartets Broad Singlet Singlet Doublet of Doublets Not determined...
2. An organic compound E has the molecular formula C12Hi7NO gives spectroscopic data as follow: a) IR (KBR Disc): Amux 3296, 1642 cm b) 'H NMR (CDCl) : 6 0.93 (, 3H); 1.48 (d, 3H); 1.66 (sextet, 2HD) 2.15 (G, 2H); 5.14 (q, 1H):5.74 (broad, s, exchange with D20, 1H); 7.42-7.23 (m, 5H) i3C NMR (CDCl;) : δ 13.7 (q); 19.1 (t); 21.7 (q); 38.8 (t); 48.5 (d); 126.1 (d): 127.3 (d); 128.6 (d); 143.0 (s); 172.0 (s) c) d)...
I need help with scheme 1 please.
Scheme 1: Compound 1 Compound 2 (b) OH (a) + OH Compound 3 Compound 4 Scheme 2: pka increased from 3 (salicylic acid) to 8.5 (Compound 1) H: 607 Laboratory Data: Compound 1: MW: 166.18 C. 65.05 0:28.88 Compound 2: MW: 167.00 C: 28.77 IR: 1739 cm (broad, strong) 'H NMR: H: 423 Br. 47.85 O: 19.15 singlet, 2H quartet, 2H triplet, 3H 2 PPM 13C NMR: 180 160 140 120 100 PPM...
give the structure
30 Unsat. Index = (2C+2-H-X + NY2 = 200 25 4.90 f 1.27 ppm, 20 720 Compound 18a: C, H. e = 2.00 ppm singlet, 2H d = 2.66 ppm quartet, 2H triplet, 3H 15 a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H c = 4.90 ppm, singlet, 2H 1.0 265 125 7.17 0.5 00 20 75 70 60 55 8, ppm 50 4.0 35 1 H2O, H,O*, heat 45 30 25 20...
practice quiz
1. (3 pts) For each of the following compounds, indicate whether the two protons shown are homotopic, enantiotopic, or diastereotopic. 2. (8 pts) Indicate the number of signals each of the following compounds would show in their 'Hand C NMR spectra: OME 'H__ _ H__ __ H__ __ H__ "C 3. (10 pts) For each of the following compounds, determine the multiplicity of each signal in the H NMR spectrum: la xiu ood ex gx x x 4....
10. Which compound is likely to have the following 'H NMR spectrum (integration is not given)? 64 Singlet 2 quartet 1 triplet a) CHOCH.CH c) CH3OQCH.CH d) CH3CH2CCH.CH 11. Compound W has the formula CsH10. a) How many units of unsaturation does w have? Show your work b) The 'H NMR spectrum has the following signals: 1 H a 9.5 singlet 9H a 1.0 singlet What is the structure of W? Partial credit for anything you can say about the...
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