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(6 pts) The -NH2 group is listed in our textbook as the strongest activator in electrophilic...
a. Is the -NO2 group an activator or a deactivator with respect to electrophilic 2. aromatic...
a. Is the -NO2 group an activator or a deactivator with respect to electrophilic 2. aromatic substitution reactions? b. Does the -NO2 group direct a second substituent ortho, meta or para? Is the -NO2 group an activator or a deactivator with respect to nucleophilic 3. aromatic substitution reactions?
1) Which of the following is an intermediate in the bromination of toluene? p) Ha BrH...
1) Which of the following is an intermediate in the bromination of toluene? p) Ha BrH 2 2) Under what reaction conditions would the electrophilic chlorination of aromatic compounds usually occur? A) Cl2, AlCl3 B) C12, CCl4 C) Cl2, H20 D) NaCl, H20 E) NaCI, CH3OH 3) 3) Which of the following is the strongest activating group in electrophilic aromatic substitution reactions? A) -CO2CH3 B)-NO2 C) -OCH3 D) -CH2CH3 E) -N(CH3)2 4) _ 4) In electrophilic aromatic substitution reactions the...
(V) 10pts. When aniline (C6H3-NH2) reacts with bromonium ion (NO2. the nitro group can become bonded...
(V) 10pts. When aniline (C6H3-NH2) reacts with bromonium ion (NO2. the nitro group can become bonded to a carbon at one of the three possible positions: ortho, meta, and para to the -NH2 group in the benzene ring. Consider meta and ortho attack and draw RESONANCE STRUCTURES for the carbocations that result when NO2 undergoes electrophilic aromatic substitution to aniline. Then, on the basis of these resonance structures, explain whether the --NH2, group.is meta director, or ortho/para director. Show which...
s (c) NH2 Rank the molecules shown in Figure 6 from H) most acidic to least acidic (example:dcba . NH2 он Figure 6...
s (c) NH2 Rank the molecules shown in Figure 6 from H) most acidic to least acidic (example:dcba . NH2 он Figure 6 ) Which of the following is most stable carbocation? i) methyl i) primary i) secondary iv) tertiany v) Hiv are approximately equal in stability J) Which of the following is not a characteristic of most aromatic compounds like benzene? i) they are cyclic li) they are planar ii) they are resonance stabilized iv) the aikenes of the...
Help me pleaseeeee! Identify the mechanism by which each of the reactions above proceeds from among...
Help me pleaseeeee! Identify the mechanism by which each of the
reactions above proceeds from among the mechanisms listed. Use the
letters a - j for your answers.
Chapter 16: Mastery [Review Topics] [References] 1. Identifying Unknown Aromatic Com... 1 pts M 2. Electrophilic Aromatic Substitution: ... 1 pts M 3. Electrophilic Aromatic Substitution: ... 1 pts M 4. Electrophilic Aromatic Substitution: ... 1 pts M CH3 _CH3 CH3 FeCl3 = 2. I T + Cl2 - + HCI 5....
D Question 11 6 pts Which structure is a major organic product of the multi-step reaction...
D Question 11 6 pts Which structure is a major organic product of the multi-step reaction shown? Recall that the numbers in front of the reagents tells the order of the addition 1) NaNHANH, 2) CH CH Br 3) HgSO4/H2SO4/H,0 // D Question 14 6 pts Which group is considered a deactivator in electrophilic aromatic substitution (EA.S.) reactions? The dashed line indicates where the group is attached to benzene. OH —ОН
use the notes provided to help answer the question above. will rate well The second step...
use the notes provided to help answer the question
above. will rate well
The second step of the synthesis transformation of the chlorosulfonyl functional group into a sulfonamide) is an example of a a. Nucleophilic displacement (substitution) b Elimination C. Electrophilic aromatic substitution d. Acid hydrolysis Esterification e. THE SULFONIC ACID GROUP AND ITS DERIVATIVES Sulfonic acids are organic analogs of sulfuric acid, a very strong acid. They are highly corrosive, react vigorously with water, and can cause skin bums....
250 ChemActivity 29 Electrophilic Aromatic Substitution no ChemActivity 29 Part A: Electrophilic Aromatic Substitution (What products...
250 ChemActivity 29 Electrophilic Aromatic Substitution no ChemActivity 29 Part A: Electrophilic Aromatic Substitution (What products are formed when a strong electrophile is added to benzene?) Model 1: (review) Electrophilic Addition of HCI Rani o g cyclohexene carbocation intermediate Run 2 U X benzene This product carbocation intermediate DOES NOT Critical Thinking Questions 1 For Rxn I (above) draw curved arrows showing the mechanism of electrophilic addition of HCl. Include an appropriate carbocation intermediate in the box above. Figure 1:...
9. For the compound below answer a b and c. a) b) c) (3 pts) is...
9. For the compound below answer a b and c. a) b) c) (3 pts) is the molecule below an aromatic or anti-aromatic estem? (4 pts) How many electrons are in the aromatic anti aromatic bratem? (4 pts). Draw an arrow () to the lone pair electron(s) that are part of the aromatic (or anti-aromatic) system. 10. (18 pts-6 pts each) Fill in the major organic product(s) for the reactions below Br+FeBr ci + CH CH CH .. 3+ AICI:...
a. Is the -NO2 group an activator or a deactivator with respect to electrophilic 2. aromatic substitution reactions? b. Does the -NO2 group direct a second substituent ortho, meta or para? Is the -NO2 group an activator or a deactivator with respect to nucleophilic 3. aromatic substitution reactions?
1) Which of the following is an intermediate in the bromination of toluene? p) Ha BrH 2 2) Under what reaction conditions would the electrophilic chlorination of aromatic compounds usually occur? A) Cl2, AlCl3 B) C12, CCl4 C) Cl2, H20 D) NaCl, H20 E) NaCI, CH3OH 3) 3) Which of the following is the strongest activating group in electrophilic aromatic substitution reactions? A) -CO2CH3 B)-NO2 C) -OCH3 D) -CH2CH3 E) -N(CH3)2 4) _ 4) In electrophilic aromatic substitution reactions the...
(V) 10pts. When aniline (C6H3-NH2) reacts with bromonium ion (NO2. the nitro group can become bonded to a carbon at one of the three possible positions: ortho, meta, and para to the -NH2 group in the benzene ring. Consider meta and ortho attack and draw RESONANCE STRUCTURES for the carbocations that result when NO2 undergoes electrophilic aromatic substitution to aniline. Then, on the basis of these resonance structures, explain whether the --NH2, group.is meta director, or ortho/para director. Show which...
s (c) NH2 Rank the molecules shown in Figure 6 from H) most acidic to least acidic (example:dcba . NH2 он Figure 6 ) Which of the following is most stable carbocation? i) methyl i) primary i) secondary iv) tertiany v) Hiv are approximately equal in stability J) Which of the following is not a characteristic of most aromatic compounds like benzene? i) they are cyclic li) they are planar ii) they are resonance stabilized iv) the aikenes of the...
Help me pleaseeeee! Identify the mechanism by which each of the
reactions above proceeds from among the mechanisms listed. Use the
letters a - j for your answers.
Chapter 16: Mastery [Review Topics] [References] 1. Identifying Unknown Aromatic Com... 1 pts M 2. Electrophilic Aromatic Substitution: ... 1 pts M 3. Electrophilic Aromatic Substitution: ... 1 pts M 4. Electrophilic Aromatic Substitution: ... 1 pts M CH3 _CH3 CH3 FeCl3 = 2. I T + Cl2 - + HCI 5....
D Question 11 6 pts Which structure is a major organic product of the multi-step reaction shown? Recall that the numbers in front of the reagents tells the order of the addition 1) NaNHANH, 2) CH CH Br 3) HgSO4/H2SO4/H,0 // D Question 14 6 pts Which group is considered a deactivator in electrophilic aromatic substitution (EA.S.) reactions? The dashed line indicates where the group is attached to benzene. OH —ОН
use the notes provided to help answer the question
above. will rate well
The second step of the synthesis transformation of the chlorosulfonyl functional group into a sulfonamide) is an example of a a. Nucleophilic displacement (substitution) b Elimination C. Electrophilic aromatic substitution d. Acid hydrolysis Esterification e. THE SULFONIC ACID GROUP AND ITS DERIVATIVES Sulfonic acids are organic analogs of sulfuric acid, a very strong acid. They are highly corrosive, react vigorously with water, and can cause skin bums....
250 ChemActivity 29 Electrophilic Aromatic Substitution no ChemActivity 29 Part A: Electrophilic Aromatic Substitution (What products are formed when a strong electrophile is added to benzene?) Model 1: (review) Electrophilic Addition of HCI Rani o g cyclohexene carbocation intermediate Run 2 U X benzene This product carbocation intermediate DOES NOT Critical Thinking Questions 1 For Rxn I (above) draw curved arrows showing the mechanism of electrophilic addition of HCl. Include an appropriate carbocation intermediate in the box above. Figure 1:...
9. For the compound below answer a b and c. a) b) c) (3 pts) is the molecule below an aromatic or anti-aromatic estem? (4 pts) How many electrons are in the aromatic anti aromatic bratem? (4 pts). Draw an arrow () to the lone pair electron(s) that are part of the aromatic (or anti-aromatic) system. 10. (18 pts-6 pts each) Fill in the major organic product(s) for the reactions below Br+FeBr ci + CH CH CH .. 3+ AICI:...
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