5-13) NaBH(OA), + HN 5-14) Lotho 8 5-15) 1) excess CH, 2) Ag,0 3) A 5-16...
2) Fill in each of the following boxes with the structure of the major reaction product(s) from each of the following reactions. (28 points total). a) Pd(PPhale NaOH b) + Pd(OA) (CH CHN CN 1. NaBH 2. H2O HH OH но -н H- OH HH OH CH,OH HNO, но NH,OH trace of acid 1. CHI (excess 2. Ag,0 H2O, heat CI 1 CRUS POY Grubbs catalyst) Page 2 of 5
2. Predict the product. CH,CHINH Or . 1. excess CH 1 2. Ag,0,H,O heat 5. Match the reagents to the corresponding reaction. G. H20 H. xs CH3CH2NH2 A. SOCI2, pyridine B. Ethanol, pyridine C. 1) xs LAH 2) H20 D. 1) xs CH,CHMgBr 2) H30 E. 1) NaOH 2) H30* F. 1) DIBAH 2) H20 1. 1) LiAl(OR)2) H20 J. (CH2CH2) Culi K. xs NH3 L. 1) NaOH 2) CHÚCHỊCHÚCOCI M. Butanol, H
Devise a 3-step synthesis of the product from the starting material shown. 1. reagent 1 2.reagent 2 3. reagent 3 Select reagent 1: Select reagent 2: HOCH,CH,OH, cal. H CH,CHỌ, cai. HÀ KMnO H.Pd NaOH 0,H,O, Zn NaBH, LAH LAIH CH,CH,OH,H,O, neat Select reagent 3: H.Pd H,O, H, NaBH KMnO, NAOH In line Wrap textBreak text
H,Cro SOCI: H,0 Pyridine PCC CH,CI, HIO HR Peroxide 2. H,0,HCI NES CH- - HN CH,I, Zn(Cu) ether 1.0, 2. (CH) KCN HCN 1.00 2. NaHSO, H,0 HO 2. HCI, H20 H.SO 1. BH. THE 2. H,O, NaOH 1. HgOAC), 2,0 2. NaBH, HUNCH, 1. NBH 2. H.O
-NH2 PCC, CH2Cl2 NaBH CN OH 8 Br 1. 3 equiv. 12 4 equiv. NaOH 1. LiAlH4 2. H2O 2. H30* 9 10 2 equiv. (CH3)2NH 1. LiAIH 2. H20 11 12 H2O 1. CH,MgCI 2. H30 13 14
2 3 tab 4 % 5 Q W E con lo R page 16 8 14. Provide all of the organic products for the following transformations: A Br, CHCI B 1. Ho(OAc), H20 2.NaBH OH SOCI2 CH3 C Me 1. BH 2, NaOH, HOA D
please help! will give rating. thank you! L. 1.CH,Br 2. H,0 M. NaBH CH, OH 0. Brz P. Hz, Pd N. 1. KCN 2. LIAIHA 3. H2O ОН Q. NaOH, Bra B. 1, KCN 2. HCI 3. cat NaOH H2O S. NHA mild H+ I. NH3 NaBH3CN U. 1. CHgMgBr 2. H2O, H Determine the reagents necessary to carry out each of the following transformations. The reagent choices are listed in the text box above this question (reagents L-U). You...
14. (4 points each) Complete the following reactions showing the major organic product). 2 CH,NH CH CH,OH Ci pyridine 2. 2CH,NH2 Ci AICl I. excess CH,MgBr 2. H CH,CH,CH OH NaOH 14. (4 points each) Complete the following reactions showing the major organic product). 2 CH,NH CH CH,OH Ci pyridine 2. 2CH,NH2 Ci AICl I. excess CH,MgBr 2. H CH,CH,CH OH NaOH
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20 refux 9- NH2 CH -C-Cl 10. 2.HaO кон. rMso 12- CH3 CH Ch 13- NH2 14- -78C 15- OH LiAIH 4 16- socl2 2 pyridine P2Os NH2 18- 1. NaHCO.. H2O 2. OH Br 19. 2, H30 20- 1. BH4 2. H3O 21- 22- 2. PBr 3.2 equiv. CH,CH CH&NH 23- 1. Mg Br 3. NaHCO Cl 24- 2 LAH 25-
select and match HO-CH NH2 H3C-CH2-OH 1 Me Et Me H 2. 3 4 9 Ag(NH3)2 10 Zn(Hg)/HCI 11 NabH./EtOH 12 NaNO lacetone 13 CH2N2 14 MeMgCI Me OH CN OH Me Me Me Me Me un O 6 7 8 A: gives tertiary alcohol (reactant, reagent, product) B: compounds which give aldimine (reactant, reagent, product) C: gives carboxylic acid (reactant, reagent, product) D: gives a secondary alcohol (reactant, reagent, product)