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One drop has a volume of about 0.05 mL, thus the concentration of Cu2+ in the...

One drop has a volume of about 0.05 mL, thus the concentration of Cu2+ in the dilute half-cell is about (0.05 mL/25 mL)(0.1 M)=2x10-4 M. At 298K use this equation:

E= -(0.0592/n)xlog(An+ Mdil/ An+ Mconc) to calculate it.

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Answer #1

Molarity of Cu+2 in dilute solution = 2 x 10^-4 M

molarity of Cu+2 in concentration solution = 0.1 M

number of electrons trnasfered = 2 = n

E= -(0.0592/n) x log(An+ Mdil/ An+ Mconc)

E = (-0.0592 / 2 ) x log ( 2 x 10^-4 / 0.1)

E = 0.0799 V

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