Copper(II) forms co-ordination complex with ammonia ligand in aqueous medium. The reaction is shown below.
[Cu(H2O)6]SO4 + 4 NH3 (aq) [Cu(NH3)4(H2O)2]SO4 + 4 H2O(l)
The tetraamine-Cu(II) complex is dark blue in color. Therefore the cathode cell appears darker compared to 1M CuSO4 stock solution. Due to the above reaction effective Cu2+ ion concentration in the half cell decreases below 1M as a result, Eo decreases.
E° (cal.) E° (exp.) 1. Fe(s)| Fe2+ (1 M) || Cu2+ (1 M) | Cu(s) 0.775...
Consider the cell: Zn(s)ǀ(Zn2+(0.20 M)ǁCu2+(0.20 M)ǀCu(s) with Eº(Cu2+/Cu = 0.34 v and Eº(Zn2+/Zn) = –0.76 v a) Write the cell reaction which occurs when the cell produces current and calculate Ecell. b) If each cell compartment contains 25.0 mL of the corresponding metal salt solution and 25.0 mL of 3.00 M NH3(aq) is added to the Cu2+ solution, Ecell = 0.68 v. Use these data to calculate Kf for Cu(NH3)42+. Cu2+(aq) + 4 NH3(aq) ⇄ Cu(NH3)42+
What is E for a cell where Eº=1.10 (Cu2++Zn--Cu+Zn2+), [Cu2+3=1.50 M, and [Zn2+2=0.0050 M at SATP? 0.93 V 1.27 V 1.17 V 1.03 V
Candidate l: Zn(s) | Zn2+(aq,0.500 M) I Cu2+(aq, 1.00 M) Cu(s) Candidate 2: Pb(s) | Pb2+(aq, 0.500 M) || Cu2+(aq, 1.00 M) Cu(s) Candidate 3: Mg(s) | Mg2+(aq, 0.500 M) | Pb2+(aq, 1.00 M)| Pb(s) (a) 6 pts) Choose one of the candidate voltaic cells #1, #2, or #3. Draw a schematic cell diagram for the candidate voltaic cell of choice. Clearly label anode, cathode, electrodes, ions and their concentrations, salt bridge, and the flow of electrons. (b) (5 pts)...
Choose the correct Nernst equation for the cell Zn + Cu2+ à Zn2+ + Cu E = E° - 0.0296 log(Cu / Zn) E=E° - 0.059 log([Zn2+] / [Cu2+]) E = E° - 0.0296 log(Zn / Cu) E = E° - 0.0296 log([Zn2+] / [Cu2+]) E = E° - 0.0296 log([Cu2+] / [Zn2+]) 20 points
1. Zn, Zn2+ || Cu, Cu2+ 2. Cu, Cu2+ || Pt, Fe2+, Fe3+ 5. Zn, Zn2+ || Pt, I-, I2 6. Cu, Cu2+ || Ag, Ag+ 7. Zn, Zn2+ || Ag, Ag+ WRITE DOWN THE OXIDATION REACTION AND REDUCTION REACTIONS FOR THE ABOVE REACTIONS PLEASE
9) A sol'n in an electrolytic cell contains the ions Cu2+, Fe2+ & Zn2+. If the voltage (initially very low) is turned up, in which order will the metals be plated out onto the cathode? Cu2+(aq)2e-Cu(s); E0.34V Fe"(aq) + 2e-→ Fe(s);E"--0.44V Zn2+(aq) + 2e-→ Zn(s): E。--0.76V 10) How long will it take to produce a sol'n of pH 2.00 by electrolysis of 500 mL of 0.100 M AgN03(aq) at 0.240 Amperes? Anode: 2H2O(l) → 4H-(aq) + O2(g) + 4e-, E°...
What is E for a cell where E°=1.10 (Cu2++Zn→Cu+Zn2+), [Cu2+]=1.25 M, and [Zn2+]=0.0075 M at SATP? 1.25 V 0.95 V 1.03 V 1.17 V
- Zn2+ Choose... Choose... (1pts) Identify the complete redox reaction for a ZnZn2+1|Cu2+1Cu cell. A. Zn(s) + Cu?+ (aq) (aq) + Cu(s) B. Zn(s) + Cu(s) → Zn2+ (aq) + Cu2+ (aq) C. Zn2+ (aq) + Cu(s) Zn(s) + Cu2+ (aq) D. Zn (s) + 2 Cu(s) — Zn2+ (aq) + 2 Cu2+ (aq) (1pts) Identify the complete redox reaction for a Zn/Zn2+||Pb2+1Pb cell. A. Zn (s) + Pb(s) Zn2+ (aq) + Pb2+ (aq) B. Zn2+ (aq) + Pb(s) Zn(s)...
Separate galvanic cells are made from the following half-cells: cell 1: H+(aq)/H2(g) and Pb2+(aq)/Pb(s) cell 2: Fe2+(aq)/Fe(s) and Zn2+(aq)/Zn(s) Which of the following is correct for the working cells? Standard reduction potentials, 298 K, Aqueous Solution (pH = 0): Cl2(g) + 2e --> 2C1-(aq); E° = +1.36 V Fe3+(aq) + e --> Fe2+(aq); E° = +0.77 V Cu2+(aq) + 2e --> Cu(s); E° = +0.34 V 2H+(aq) + 2e --> H2(g); E° = 0.00 V Pb2+(aq) + 2e --> Pb(s);...
1- Consider the following redox reaction: Fe(s) + Cu2+(aq) --> Fe2+(aq) + Cu(s) EoCell = 0.78 V If [Cu2+] = 0.3 M, what [Fe2+] is needed so that Ecell = 0.76 V 2- Calculate the Eocell for the following redox reaction: Cu(s) + 2Ag+(aq) --> Cu2+(aq) + 2Ag(s)