A precipitate forms when a solution that is 0.10 M in Cu2+, Pb2+, and Ni2+ is saturated with H2S and adjusted to pH = 1. What sulfides are present in the precipitate?
[H2S] = 0.10 M; for H2S, Ka1 ´ Ka2 = 1.1 ´ 10–24
Ksp: CuS = 8.5 ´ 10–45, PbS = 7.0 ´ 10–29, NiS = 3.0 ´ 10–21
(The answer is D, Could anyone explain it by steps?)
A) |
CuS, PbS, and NiS |
B) |
PbS and NiS |
C) |
NiS |
D) |
CuS and PbS |
E) |
CuS |
A precipitate forms when a solution that is 0.10 M in Cu2+, Pb2+, and Ni2+ is...
Precipitation question. A mixture contains 1.0 x 10^-3 M Cu2+ and 1.0 x 10^-3 Mn2+ and is saturated with 0.10 H2S. Determine a pH where CuS precipitates but MnS does not precipitate. Ksp for CuS is 8.5 x 10^-45, and Ksp for MnS is 2.3 x 10^-13. Ka1 of H2S is 8.9 x 10^-8 and Ka2 is 1 x 10^-19. Please show all your work.
What is the pH of a buffered solution saturated with hydrogen sulfide ([H2S] = 0.10 M) at 25°C if PbS (s) is precipitated, leaving [Pb2+] = 1.0 × 10–7 M, without precipitating any MnS (s)? The original solution is 0.030 M in both Pb2+ (aq) and Mn2+ (aq). Ksp = 8.0 × 10–28 M2 for PbS (s),Ksp = 2.5 × 10–13 M2 for MnS (s), andSelect one:a. 0.03b. 2c. 0.4d. 7
please solve and show work! A solution of 0.10 M (each) Ni2+ and Cu2+ are separated using selective precipitation by the addition of solid Na2CO3. Assuming no volume change upon this addition, how much of the first precipitated ion remains at the point where the second ion begins to precipitate? Ksp of NiCO3 = 1.4'10-7 Ksp of CuCO3 = 2.510-10 A. 1.4 x 10-6 M CUCO3 B. 1.2 x 102 M CUCO3 C. 1.8x 10-4M NICO D. 1.4 x 106...
A solution is 0.0100 M in each of the metal ions in the following table:Metal sulfideKspaFeS6×102NiS8×10-1PbS3×10-7CuS6×10-16HCl is added to the solution so that the H3O+ concentration is 0.300 M. H2S gas is bubbled through the solution to attain a H2S concentration of 0.100 M. Predict which of the sulfides precipitate under the given conditionsDrag each item to the appropriate bin.Will percipitate Will Not percipitate
Question 4 1 pts A solution has 0.10 M of Ni2+ and 0.10 Mof Ca2+. When Na2CO3 is added to the solution, which compound will precipitate first? Ksp (NICO3) = 1.4 x 10-7 Ksp (CaCO3) = 8.7x10-9 NaCO3 NICO o Сасоз Nica CaNa
A solution of potassium sulfide is added very slowly to a solution that is 0.1 M eachin cadmium, nickel (II), zinc, and copper (II). Which substance will precipitate first? A. CdS (Ksp= 3.6 x 10^-29) B. NiS (Ksp=3.0 x 10^-20) C. ZnS (Ksp=4.9 x 10^-18) D. CuS (Ksp=8.7x10^-36)
A 1.0 L solution of 0.30 M in H3O+(aq) containing Mn2+(aq), Cd2+(aq), and Fe2+(aq), all at 0.010 M, was saturated with H2S(g) at room temperature. Assume that the pH of the solution remains constant and that the [H2S]sat = 0.10 M. The Ksp for MnS9S) is 2.5 x 10-13 , Ksp for CdS(s) is 8.0 x 10 -27 and Ksp for FeS(s) is 6.3 x10-18 . For H2S:Ka1=1.3 x 10-7. Ka2=8.5 x 10-14. Calculate the equilibrium concentrations of Mn2+(aq),Cd2+(aq), and...
16/ For PbCl2 (K.p = 2.4 x 10), will a precipitate of PbCl2 form when 0.10 L of 3.0 x 102M Pb(NO3)2 is added to 400 mL of 9.0 x 10-2 M NaCl? Pb (NO3)₂ + Nach a Yes, because > Ksp. b. No, because Q = Kp. 100 c. No, because Q<Kip. d. Yes, because Q<K poll, + NaNO3 2. u* 10 = Pb (1 ke Q 17. Over what range of pH is a HOCI - NaOCI buffer...
28) What is the molar solubility of Mg(OH)2 in a basic solution with a pH of 11.18? Ksp for Mg(OH)2 is 5.6x 10-12 B) 5.6x 10-10 M D) 1.1 x 10-4 M C) 2.4 x 10-6 M A) 5.6 x 10-8 M 29) What is the molar solubility of AgCl in 0.10 M NaCN if the colorless complex ion Ag(CN) 2- forms? Ksp for AgCl is 1.8 x 10-10 and Kf for Ag(CN) 2- is 1.0 x 1021, D) 0.050...
15. A 100.0 mL sample of 0.10 M Ca(OH)2 is titrated with 0.10 M HBr. Determine the pH of the solution after the addition of 100.0 mL HBr. a. 12.70 b. 1.30 7.00 d. 12.00 16/ For PbCl2 (Kip = 2.4 x 10), will a precipitate of PbCl2 form when 0.10 L of 3.0 x 10 PM Pb(NO3)2 is added to 400 mL of 9.0 x 10-2 M NaCl? Pb(NO3)₂ + Nach a. Yes, because Q > Ksp. b. No,...