Write the structure of the principle organic product obtained on the mononitration of each of the following.
a. p-methyl benzoic acid
b. m-dichlrobenzene
c. m-dinitrobenzene
d. p-methoxy aceophenone
e. p-methylanisole
f. 2,6- dibromoanisole
Write the structure of the principle organic product obtained on the mononitration of each of the...
2. Write the structure of the principal organic product(s) of the following reactions: (112 pts) (a) 2-chloropropane + lithium in diethyl ether (b) product of (a) with cyclohexanone, followed by dilute acid (c) benzoic acid + NaOH+H2O (d) hexanoic acid + Brą + PBrz (e) ethyl acetate + CH3CH2O- Nat in ethanol (f) ethyl acetoacetate + sodium ethoxide + 1-bromobutane (g) propanal + ethanol + dissolved HCl gas (h) (CH),CO K + CH I in (CH),COH solvent (i) 2,4-pentanedione +...
if you can please draw the mechanism for b. thank you
PROBLEM 17-13 Predict the mononitration products of the following aromatic compounds (a) p-methylanisole (c) p-chlorophenol (b) m-nitrochlorobenzene (d) m-nitroanisole (continued Reactions of Aromatic Compounds 830 СНАРТER 17 e (f) CH, —С—NН -NH—С—CH, -NH2 (Consider the structures of these groups. One is activating, and the other is deactivating.) CH2 0-methylacetanilide
PROBLEM 17-13 Predict the mononitration products of the following aromatic compounds (a) p-methylanisole (c) p-chlorophenol (b) m-nitrochlorobenzene (d) m-nitroanisole (continued...
WRITE THE REACTANTS AND PRODUCT.
Write the structural formula of the major organic product of each of the following reactions. ethanoyl chloride + 2-butanol benzoic anhydride + 2-pentanol methyl benzoate + butylamine diethyl malonate (malonic ester) + NaOH + ethyl bromide product of (d) + Na0H/H_2O, then neutralization with HCI, then heating to 160 degree C butylamine + dilute HBr methyl propanoate + LDA in THF solution (-78 degree C), then methyl iodide, then H_2O N_1 N-dimethylaniline + CH_3I
22. What is the major organic product obtained from the following reaction? ho A) 2 B)4 C)3 D) 1 23. What is the correct name for the molecule below: A) 2,6-dimethyl-3-oxonon-2-ene B) B) 2,6-dimethylnona-8-oxone C) C) 4,8-dimethylnon-7-en-2-one D) 4,8-dimethyl-2-oxonon-7-ene 24. Which of the following describes a synthesis of an aldehyde? A) hydrogenation of an acid chloride using Pd/BaSO4/S as a poisoned catalyst B) reaction of a primary alcohol with Na2Cr207 C) reaction of a ketone with ozone D) treatment of...
V. Explains why it is important to control the temperature in the synthesis of 3-nitrobenzoate. If a secondary reaction happens, draw the structure of the product or products possible. VI. Write the equations involved in the mechanism of the main reaction. Draw the structures and arrows to show the movement of electrons. VII. A student obtained 7 grams of 3-nitrobenzoate corresponding to an 83% yield. How many grams of methyl benzoate reaction started? VIII. Write equations for the mononitration reaction of...
Please give a detail mechanism of 22-29
22. What is the major organic product obtained from the following reaction? 1. NalH 2 CHỊCH CHỊCH EM a. l-methyl-4-nonyne b. 2-methyl-4-nonyne c. 2-methyl-3-nonyne d. 3-methyl-4-nonyne ANSWER: d 23. What is the major organic product obtained from the following reaction? Br. CH, C=C=CH CH, CH,COOH, LIBE - a. (E) 1.2-dibromobutene b. (Z) 1,2-dibromobutene c. (E) 2,3-dibromobutene d. (Z) 2,3-dibromobutene ANSWER: C 25. What is the major organic product obtained from the following reaction?...
Write the structure of the major organic product isolated from the reaction of 3-hexyne with (a) Hydrogen (2 mol), platinum (f) Chlorine (2 mol) (b) Hydrogen (1 mol), Lindlar palladium (g) Aqueous sulfuric acid, mercury(II) sulfate (C) Hydrogen chloride (1 mol) (h) Ozone followed by hydrolysis (d) Hydrogen chloride (2 mol) (e) Chlorine (1 mol)
10. Write the structural formula for the principal organic product of each of the following reactions. (8 marks) 0 CH.CH,CH,COOH + CH- chchi- CH,CH-C-Cl CH.CH,OH b. ce CH-C-Cl + CHỊCH,CH,OH C HCOOH + CHỌCH,OH d. BONUS: Write out full reaction schemes for (a) the alka hydrolysis of methyl propanoate and sodium hydroxide, and (b) the acid hydrolysis of ethyl acetate and water. (2 bonus marks total)
What is the major organic product obtained from the following reaction? 1. PPh 2. Buli 3.CHÚCH CHO 4.H20 Br a. 2-methyl-2-pentene b. 4-methyl-1-pentene c. (Z)-3-methyl-2-pentene d. (E)-3-methyl-2-pentene QUESTION 4 What is the major organic produs obtained from the following reaction? OH Zn(HO) HCI 2 Ph Ph Ph Ph Ph ОООО a. 1 b. 2 c.3
Write the structure of the majoe organic product formed in the reaction of 1-methylcyclohexene with each of the following: f) diborane in diglyme, followed by basic hydrogen peroxide g) bromine in carbon tetrachloride