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2. Write the structure of the principal organic product(s) of the following reactions: (112 pts) (a)...
write the major product you would expect to obtain in the following reactions a. tetrahydrofuran with...
write the major product you would expect to obtain in the following reactions a. tetrahydrofuran with hrdrogen bromide b. allyl-3-chlorophenylether with heat c. ethyl alcohol with pyridiniumchloroochromate inmethylene chloride d.ethylacetate with 3-methylbutylmagnesium bromide followed by dilute aqueous acid e. 4-nitroaniline with sodium nitrate and hydrochloric acid at 5 degrees C with phenol
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic...
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenylketone) and benzaldehyde+KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (1) acetanilide and LiAlH, in diethyl ether, followed by addition of water.
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic...
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenyl ketone) and benzaldehyde + KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (1) acetanilide and LiAIH, in diethyl ether, followed by addition of water.
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic...
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenyl ketone) and benzaldehyde + KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (f) acetanilide and LiAlH4 in diethyl ether, followed by addition of water.
2. Write the major organic product expected from each of the following reactions: (120 pts) (a)...
2. Write the major organic product expected from each of the following reactions: (120 pts) (a) CH&CH CH2Br+ NaOH in acetone solvent (b) 1-methylcyclopentene + HCI (c) cyclopentanol+ H2SO4+heat (e) 1-pentyne+H2O H2SO4 (8) benzene + methyl iodide+AICI (i) 2-methyl-1-pentene+ BHo, then HOOH and NaOH () 2-bromobutane + CH,CH,ONa in ethanol (d) 1-pentene + HBr with trace peroxide (f) 1,2-bromopentane + NaNH2 in liquid ammonia (h) ethylbenzene + HNO, + HSO
Please do parts f,g,&h 2. Write the principal organic product expected from each of the following...
Please do parts f,g,&h
2. Write the principal organic product expected from each of the following reactions. Indicate stereochem where appropriate. (32 pts) (a) phenyl Grignard +acetone, then H:o (b) (CH;CH2)2CuLi+CH3l (c) tert-butyl bromide+CHsCH2Li, then H30+ (d) CHs(CH2)sCH:OH+acetic anhydride (e) salicylic acid+ acetic anhydride (t) ethyl acetate+phenyl Grignard reagent in THF solvent, then H30 (g) trans-4-chloro-tert-butylcyclohexane+ CHsCH2SNa (h) cyclohexene + OsO4 + (CHs)sCOOH+NaOH
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenylketone) and benzaldehyde+KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (1) acetanilide and LiAlH, in diethyl ether, followed by addition of water.
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenyl ketone) and benzaldehyde + KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (1) acetanilide and LiAIH, in diethyl ether, followed by addition of water.
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenyl ketone) and benzaldehyde + KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (f) acetanilide and LiAlH4 in diethyl ether, followed by addition of water.
2. Write the major organic product expected from each of the following reactions: (120 pts) (a) CH&CH CH2Br+ NaOH in acetone solvent (b) 1-methylcyclopentene + HCI (c) cyclopentanol+ H2SO4+heat (e) 1-pentyne+H2O H2SO4 (8) benzene + methyl iodide+AICI (i) 2-methyl-1-pentene+ BHo, then HOOH and NaOH () 2-bromobutane + CH,CH,ONa in ethanol (d) 1-pentene + HBr with trace peroxide (f) 1,2-bromopentane + NaNH2 in liquid ammonia (h) ethylbenzene + HNO, + HSO
Please do parts f,g,&h
2. Write the principal organic product expected from each of the following reactions. Indicate stereochem where appropriate. (32 pts) (a) phenyl Grignard +acetone, then H:o (b) (CH;CH2)2CuLi+CH3l (c) tert-butyl bromide+CHsCH2Li, then H30+ (d) CHs(CH2)sCH:OH+acetic anhydride (e) salicylic acid+ acetic anhydride (t) ethyl acetate+phenyl Grignard reagent in THF solvent, then H30 (g) trans-4-chloro-tert-butylcyclohexane+ CHsCH2SNa (h) cyclohexene + OsO4 + (CHs)sCOOH+NaOH
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