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2. Write the major organic product expected from each of the following reactions: (120 pts) (a)...
5. Complete the following reactions showing the major pro than one: Cz H (1) NaNH2 (2) 1-Bromopropane CH b, 2-pentyne H2 -→ Lindlar catalyst C7 → c. 3,4-dimethyl-1-pentene + HBr ttl Br ーーーラ C-C-C-C-C d. 2-methyl-1-butene + H20> H2SO4 C.
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2) Sn/HCl(aq) 3) HO 1) (CH3)2CHCI/AICI: 2) NBS/hv 1) Cly/FeCl3 2) HNO,/H2SO4 1) CH3CH,COCI/AICI 2) H20 оооооооо 3) Zn(Hg)/HCl(aq) 1) SOZ/H,SO 2) Bry/FeBrz 1) (CH3)3CCI/AICI: 2) KMnO/HOIA 2) H30* 1) CH,COCIAICI: 2) H, 3) Bry/FeBry COH 1) SOCI_/pyridine 2) PhCH/AICI 3) H20 1. Br JFeBry 2. Mg/Eto 3. oxirane 4, HO* 1) Bry/FeBry 2) s09/H230 1) NBS/hv 2) PhoNa (1 CH3COCI / AIC وا (2...
2. Write the structure of the principal organic product(s) of the following reactions: (112 pts) (a) 2-chloropropane + lithium in diethyl ether (b) product of (a) with cyclohexanone, followed by dilute acid (c) benzoic acid + NaOH+H2O (d) hexanoic acid + Brą + PBrz (e) ethyl acetate + CH3CH2O- Nat in ethanol (f) ethyl acetoacetate + sodium ethoxide + 1-bromobutane (g) propanal + ethanol + dissolved HCl gas (h) (CH),CO K + CH I in (CH),COH solvent (i) 2,4-pentanedione +...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Part II - Reactions (16 marks] Draw the expected major product(s) for each of the following reactions. Question Answer 8. 1. NaH OH ? 2. OTs 9. NBS ? major product 10. Nal Br ? Acetone Br 11. 1. NaNH2 H3C-CECH ? 2. OTS 12. OH Br NaOH ? cyclic compound 13. OH HBT ? 14. ? OH cat. H2SO4 H20 Room temp. 15. Br MeOH
For letters h & i : For each of the following reactions, predict the major mechanistic pathway (SN1/SN2/E1/E2) and the major organic products 1. (cont.) (h) НСОН CHB -CHBr HCOH - (0) CH,CH,CH,CH,Br- NH 2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (CH),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH...
What is the major Organic product from the following sequence of reactions? 1) NaNH2 2) Br W u on ou oh oh oh NH (a) (d) (e ) a. a b.b d. d e. e f. f Arrange the following species in order of increasing nucleophile strength in an SN 2 reaction. h:1-, CH3NH2, CH301- O a. (Weakest nucleophile) CH3NH2 < CH301- <H:1- (Strongest Nucleophile) O b. (Weakest nucleophile) CH3NH2 <H:1- < CH301- (Strongest Nucleophile) OC (Weakest nucleophile) CH301- <h:1-...
Please do parts f,g,&h 2. Write the principal organic product expected from each of the following reactions. Indicate stereochem where appropriate. (32 pts) (a) phenyl Grignard +acetone, then H:o (b) (CH;CH2)2CuLi+CH3l (c) tert-butyl bromide+CHsCH2Li, then H30+ (d) CHs(CH2)sCH:OH+acetic anhydride (e) salicylic acid+ acetic anhydride (t) ethyl acetate+phenyl Grignard reagent in THF solvent, then H30 (g) trans-4-chloro-tert-butylcyclohexane+ CHsCH2SNa (h) cyclohexene + OsO4 + (CHs)sCOOH+NaOH