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2. (a) What is the formula and color of the complex that forms when Fe" reacts...
THE DETERMINATION OF IRON BY SPECTROPHOTOMETRY INTRODUCTION In this experiment, the red-orange colored complex formed between...
THE DETERMINATION OF IRON BY SPECTROPHOTOMETRY INTRODUCTION In this experiment, the red-orange colored complex formed between iron(II) and 1,10- phenanthroline (Eqn.) is used in determination of iron by spectrophotometry. Fe+3PhenH Fe(Phen)2 +3H red-orange (A 512 nm) An excess of reducing reagent, such as hydroxylamine or hydroquinone, is often used to reduce and maintain iron in +2 oxidation state. The complex, once formed, is very stable, and can be stored for a long time. Required Reading: Skoog and West (9E): Chapter...
A standard solution of iron was made by weighing 0.075 g of Fe(NH4)2(SO4)2 6(H2O) in 250...
A standard solution of iron was made by weighing 0.075 g of Fe(NH4)2(SO4)2 6(H2O) in 250 mL. Aliquots of this standard solution (see below) were transferred to a 100 mL volumetric flask, pH adjusted with citrate, and reacted with hydroquinone and o-phenanthroline and diluted to volume (100 mL). The absorbance was measured in a 1.0-cm cell using a Genesys 20 Spectrophotometer at 508 nm: Aliquot of standard solution Absorbance 1.0 mL 0.079 2.0 mL 0.163 5.0 mL 0.413 10.0 mL...
A solution is prepared by dissolving 0.300 g Fe(NH4)2(SO4)2*6H2O in sufficient water to produce 250.0 mL...
A solution is prepared by dissolving 0.300 g Fe(NH4)2(SO4)2*6H2O in sufficient water to produce 250.0 mL of solution. a. What is the molar concentration of Fe2+? b. What is the molar concentration of NH4+? c. What is the concentration of sulfur in mg/L?
1.1 Accurately (using an analytical balance ONLY) weigh 1.4 g of Fe(NH4)2(SO4) 2-6H20 1.2 Dissolve in...
1.1 Accurately (using an analytical balance ONLY) weigh 1.4 g of Fe(NH4)2(SO4) 2-6H20 1.2 Dissolve in 50 mL of 4% sylturisacid in a beaker. 1.3 Transfer into a 1 L volumetric flask; adjust the volume and mix well. Note the purity of the Fe(NH4)2(SO4)2.6H20 given on the label of the container. 1.4 Transfer this solution into a 1 L glass bottle. Preparation of working iron standard solution: 1.5 Pipet 10.00 mL of the iron standard stock solution into a 500.0...
Can you help me answer 4&5? Zinc(ll) and the ligand L forma 1:1 complex that absorbs...
Can you help me answer 4&5?
Zinc(ll) and the ligand L forma 1:1 complex that absorbs strongly at 600 am As long as the molar concentration of L exceeds that of Zn(II) by a factor of 5. the absorbance depends only on the cation concentration Neither Zn(ll) nor L absorbs at 600 nm A solution that is 1.59 times 10^-4 M Zn(ll) and 1.00 times 10^-3 M in L has an absorbance of 0,352 in a 1.00-cm cell at 600...
1. The wavelength at wich a substance absorbs the most light is called the wevelength max....
1. The wavelength at wich a substance absorbs the most light is called the wevelength max. The metal complex Cu(C2N2H8)2SO4 has a purple (violet) color. What would you guess as the value of wavelength max? 2.If a solution sample has an extinction coefficient of 7.53 L mol^-1 cm^-1, a pathlength of 1.30 cm, and an obsorbance of 0.569, what is the concentration of the solution in molarity? 3. How many grams of Cu(C2N2H8)2SO4 would be needed to make 250.0 ml...
LUIGIO ASSICUL Name CHEM 1090-General Chemistry Section Preparing Dilute Solutions C. V, - CV C is...
LUIGIO ASSICUL Name CHEM 1090-General Chemistry Section Preparing Dilute Solutions C. V, - CV C is the concentration of the original concentrated solution V1 is the volume of the original concentrated solution C is the concentration of the final dilute solution V2 is the volume of the final dilute solution Solution unit is mol/l which can also be written as M A solution that is 0.1 MNaonds A common solution unit is mol/l 0.1 moles NaOH for every liter of...
Can you answer question 4 & 5? The experiment and porcedure is posted below Question 4...
Can
you answer question 4 & 5? The experiment and porcedure is
posted below
Question 4 & 5
CHM3120C Analytical Chemistry Lab Lab 7. Spectrophotometric Determination of Iron in Mohr's Salt with o-Phenanthroline Required Reagents and Supplies: 50 mL of 0.0005M -0.0006 M of Mohr's solution (unknown), 10 g of Hydroxylamine hydrochloride (NH2OH, HCI), 500 mL of o-phenanthroline solution (contains 0.5 g of o-phenanthroline monohydrate), 83 g of sodium acetate (NaOAc. 3H20) in 500 mL of water (for 1.2 M...
Preparing Dilute Solutions C1 V1 C2 V2 C1 is the concentration of the original concentrated solution...
Preparing Dilute Solutions C1 V1 C2 V2 C1 is the concentration of the original concentrated solution V1 is the volume of the original concentrated solution C2 is the concentration of the final dilute solution V2 is the volume of the final dilute solution A common solution unit is mol/L which can also be written as M. A solution that is 0.1 M NAOH has 0.1 moles Na OH for every liter of solution. Beer's Law Calibration Curve A colored solution...
Please help! Ligand X forms a complex with both cobalt and copper, cach of which has...
Please help!
Ligand X forms a complex with both cobalt and copper, cach of which has a maximum absorbance at 510 nm and 645 nm, respectively. A 0.217 g sample containing cobalt and copper was dissolved and diluted to a volume of 100.0 mL. A solution containing ligand X was added to a 50.0 mL aliquot of the sample solution and diluted to a final volume of 100.0 mL. The measured absorbance of the unknown solution was 0.493 at 510...
THE DETERMINATION OF IRON BY SPECTROPHOTOMETRY INTRODUCTION In this experiment, the red-orange colored complex formed between iron(II) and 1,10- phenanthroline (Eqn.) is used in determination of iron by spectrophotometry. Fe+3PhenH Fe(Phen)2 +3H red-orange (A 512 nm) An excess of reducing reagent, such as hydroxylamine or hydroquinone, is often used to reduce and maintain iron in +2 oxidation state. The complex, once formed, is very stable, and can be stored for a long time. Required Reading: Skoog and West (9E): Chapter...
1.1 Accurately (using an analytical balance ONLY) weigh 1.4 g of Fe(NH4)2(SO4) 2-6H20 1.2 Dissolve in 50 mL of 4% sylturisacid in a beaker. 1.3 Transfer into a 1 L volumetric flask; adjust the volume and mix well. Note the purity of the Fe(NH4)2(SO4)2.6H20 given on the label of the container. 1.4 Transfer this solution into a 1 L glass bottle. Preparation of working iron standard solution: 1.5 Pipet 10.00 mL of the iron standard stock solution into a 500.0...
Can you help me answer 4&5?
Zinc(ll) and the ligand L forma 1:1 complex that absorbs strongly at 600 am As long as the molar concentration of L exceeds that of Zn(II) by a factor of 5. the absorbance depends only on the cation concentration Neither Zn(ll) nor L absorbs at 600 nm A solution that is 1.59 times 10^-4 M Zn(ll) and 1.00 times 10^-3 M in L has an absorbance of 0,352 in a 1.00-cm cell at 600...
LUIGIO ASSICUL Name CHEM 1090-General Chemistry Section Preparing Dilute Solutions C. V, - CV C is the concentration of the original concentrated solution V1 is the volume of the original concentrated solution C is the concentration of the final dilute solution V2 is the volume of the final dilute solution Solution unit is mol/l which can also be written as M A solution that is 0.1 MNaonds A common solution unit is mol/l 0.1 moles NaOH for every liter of...
Can
you answer question 4 & 5? The experiment and porcedure is
posted below
Question 4 & 5
CHM3120C Analytical Chemistry Lab Lab 7. Spectrophotometric Determination of Iron in Mohr's Salt with o-Phenanthroline Required Reagents and Supplies: 50 mL of 0.0005M -0.0006 M of Mohr's solution (unknown), 10 g of Hydroxylamine hydrochloride (NH2OH, HCI), 500 mL of o-phenanthroline solution (contains 0.5 g of o-phenanthroline monohydrate), 83 g of sodium acetate (NaOAc. 3H20) in 500 mL of water (for 1.2 M...
Preparing Dilute Solutions C1 V1 C2 V2 C1 is the concentration of the original concentrated solution V1 is the volume of the original concentrated solution C2 is the concentration of the final dilute solution V2 is the volume of the final dilute solution A common solution unit is mol/L which can also be written as M. A solution that is 0.1 M NAOH has 0.1 moles Na OH for every liter of solution. Beer's Law Calibration Curve A colored solution...
Please help!
Ligand X forms a complex with both cobalt and copper, cach of which has a maximum absorbance at 510 nm and 645 nm, respectively. A 0.217 g sample containing cobalt and copper was dissolved and diluted to a volume of 100.0 mL. A solution containing ligand X was added to a 50.0 mL aliquot of the sample solution and diluted to a final volume of 100.0 mL. The measured absorbance of the unknown solution was 0.493 at 510...
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