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If two solutions at the same temperature are mixed and the resulting solution is cooler than...

If two solutions at the same temperature are mixed and the resulting solution is cooler than the original temperature of the two solutions, what is the most likely explanation for the temperature change?

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Answer #1

When solution A is mixed with solution B, the interactions in the mixture AB are different than the interactions in pure A or pure B. These interactions refers to intermolecular interactions. Since the interactions are different, heat is either absorbed or evolved. This heat is called enthalpy of mixing. Due to this enthalpy of mixing, the temperature of mixture AB is different from the temperature of pure A or pure B.

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