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Solve 12-14
12. Consider the molecule shown below. OH OH f. How many stereoisomers are possible?...
Consider the molecule shown below. ch_2ohchohchohch_3, Indicate chiral centers and predict the total number of stereoisomers....
Consider the molecule shown below. ch_2ohchohchohch_3, Indicate chiral centers and predict the total number of stereoisomers. Draw them out in the Fischer projection. Build a model of one of them (orient it in the Fischer projection) so you can visualize the shape and how the chain curves. Sketch it to the best of your ability. Which of the molecules are enantiomers of each other? Are there any meso compounds? Justify your answers and draw them out. Take a pair of...
Draw all the stereoisomers (redraw the first with the proper 3-D representation) of the compounds below....
Draw all the stereoisomers (redraw the first with the proper 3-D
representation) of the compounds below. The configuration for the
first isomer you should draw is provided. Assign R or S
configuration to each chirality center in the additional isomers.
Indicate the stereochemical relationship (diastereomers,
enantiomers, meso compounds) between the first isomer and each of
the others. The configuration for the Fischer Projection has been
omitted, since stereochemistry can be determined from a 2-D
structure. You do not need to...
19-26 thanks! 19-29* PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of...
19-26 thanks!
19-29*
PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
3. Consider the molecules A and B shown. (2 points) i. How many stereoisomers are possible?...
3. Consider the molecules A and B shown. (2 points) i. How many stereoisomers are possible? ii. Draw each of the possible stereoisomers. он CI Он iii. Identify pairs of enantiomers and pairs of diastereomers. A. В
4. Consider the following Fischer Projection: CH, OH I 9 CH OH A Does this represent...
4. Consider the following Fischer Projection: CH, OH I 9 CH OH A Does this represent a monosaccharide, a disaccharide, a trisaccharide or something else? B Are any chiral carbons present? If so, circle each one. C Does this represent an aldose or a ketose? Explain your response and draw a box around the relevant functional group. D Give the molecular formula for this compound. E Is this compound classified as an L-isomer or a D- isomer? your response. Explain...
CHCH(OH)-CH(OH)-CH3 PART 3: 23-BUTANEDIOL Build as many models of 2.3-butanediol as you can. First, attach two...
CHCH(OH)-CH(OH)-CH3 PART 3: 23-BUTANEDIOL Build as many models of 2.3-butanediol as you can. First, attach two carbons with a single bond To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure. fill in the remaining hydrogen atoms. Remember, a model is not different if it is completelv superimposable on one already constructed! 13. How many stereochemically different models are possible for 2.3-butanediol? 14. What characteristic does one of these models have that makes it different?...
UUTISET Problem 5: Consider the following molecule and answer the questions below. ОНОН How many potential...
UUTISET Problem 5: Consider the following molecule and answer the questions below. ОНОН How many potential stereoisomers could this molecule have? Draw all possible stereoisomers. Is this molecule able to exist in four (4) distinct stereoisomers? Explain. Problem 6: How are the following pairs of molecules related. Choices are enantiomers, diastereomers, the same, completely different, meso forms, constitutional isomers or conformational isomers.
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that are not mirror images can exist; these are called diastereoisomers. Within this general class, there are special types of stereoisomers that are always optically inactive and are called meso forms. Construct a model with four different colored balls about a carbon center. Construct another identical to the first and verify this by the superimposition test. Now remove the same colored balls, blue (C from...
Which of the following structures is most stable? 2) How many stereoisomers does the molecule below...
Which of the following structures is most stable? 2) How many stereoisomers does the molecule below have? (СН), С+ снен снаси сна OH CH₃ br. a) 3 6) 4 c) 6 d) 8 e 9 3) Which of the following molecules below are chiral? 0) to A Boh A MOH HOS DBr e) 1, 2 and 3 a) Only 1 b) 1 and 3 c) 2 and 3 d) 1 and 3 What is the relationship between the following two...
3. 14 points: Consider the two molecules below: Molecule A Molecule B CH(CH3)2 CH(CH3)2 1 CH...
3. 14 points: Consider the two molecules below: Molecule A Molecule B CH(CH3)2 CH(CH3)2 1 CH I ICH₃ 27 [ 2 CH3 a. Molecules A and B both have three chiral carbons (labeled 1, 2, and 3). How many unique stereoisomers does 1-isopropyl-2,3-dimethylcyclohexane have? b. Molecules A and B are pairs. C. Determine the configuration (R or S) of chiral carbons 1, 2, and 3 for both molecules. Chiral Carbon Molecule A Molecule B d. Draw the two 'chair' conformers...
Consider the molecule shown below. ch_2ohchohchohch_3, Indicate chiral centers and predict the total number of stereoisomers. Draw them out in the Fischer projection. Build a model of one of them (orient it in the Fischer projection) so you can visualize the shape and how the chain curves. Sketch it to the best of your ability. Which of the molecules are enantiomers of each other? Are there any meso compounds? Justify your answers and draw them out. Take a pair of...
Draw all the stereoisomers (redraw the first with the proper 3-D
representation) of the compounds below. The configuration for the
first isomer you should draw is provided. Assign R or S
configuration to each chirality center in the additional isomers.
Indicate the stereochemical relationship (diastereomers,
enantiomers, meso compounds) between the first isomer and each of
the others. The configuration for the Fischer Projection has been
omitted, since stereochemistry can be determined from a 2-D
structure. You do not need to...
19-26 thanks!
19-29*
PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
3. Consider the molecules A and B shown. (2 points) i. How many stereoisomers are possible? ii. Draw each of the possible stereoisomers. он CI Он iii. Identify pairs of enantiomers and pairs of diastereomers. A. В
4. Consider the following Fischer Projection: CH, OH I 9 CH OH A Does this represent a monosaccharide, a disaccharide, a trisaccharide or something else? B Are any chiral carbons present? If so, circle each one. C Does this represent an aldose or a ketose? Explain your response and draw a box around the relevant functional group. D Give the molecular formula for this compound. E Is this compound classified as an L-isomer or a D- isomer? your response. Explain...
CHCH(OH)-CH(OH)-CH3 PART 3: 23-BUTANEDIOL Build as many models of 2.3-butanediol as you can. First, attach two carbons with a single bond To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure. fill in the remaining hydrogen atoms. Remember, a model is not different if it is completelv superimposable on one already constructed! 13. How many stereochemically different models are possible for 2.3-butanediol? 14. What characteristic does one of these models have that makes it different?...
UUTISET Problem 5: Consider the following molecule and answer the questions below. ОНОН How many potential stereoisomers could this molecule have? Draw all possible stereoisomers. Is this molecule able to exist in four (4) distinct stereoisomers? Explain. Problem 6: How are the following pairs of molecules related. Choices are enantiomers, diastereomers, the same, completely different, meso forms, constitutional isomers or conformational isomers.
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that are not mirror images can exist; these are called diastereoisomers. Within this general class, there are special types of stereoisomers that are always optically inactive and are called meso forms. Construct a model with four different colored balls about a carbon center. Construct another identical to the first and verify this by the superimposition test. Now remove the same colored balls, blue (C from...
Which of the following structures is most stable? 2) How many stereoisomers does the molecule below have? (СН), С+ снен снаси сна OH CH₃ br. a) 3 6) 4 c) 6 d) 8 e 9 3) Which of the following molecules below are chiral? 0) to A Boh A MOH HOS DBr e) 1, 2 and 3 a) Only 1 b) 1 and 3 c) 2 and 3 d) 1 and 3 What is the relationship between the following two...
3. 14 points: Consider the two molecules below: Molecule A Molecule B CH(CH3)2 CH(CH3)2 1 CH I ICH₃ 27 [ 2 CH3 a. Molecules A and B both have three chiral carbons (labeled 1, 2, and 3). How many unique stereoisomers does 1-isopropyl-2,3-dimethylcyclohexane have? b. Molecules A and B are pairs. C. Determine the configuration (R or S) of chiral carbons 1, 2, and 3 for both molecules. Chiral Carbon Molecule A Molecule B d. Draw the two 'chair' conformers...
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