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Can you explain problem 12 and 13 for me I have the right
answers I just...
Organic Lab Technique Problem Set 1) How many different sets of equivalent protons are there in...
Organic Lab Technique Problem Set 1) How many different sets of equivalent protons are there in the following compound? CI CH3CCH2C(CH3)3 CH3 5. Which or the spect A. three B. four C. five D. six 2) Which of the following gives the furthest downfield shift from TMS in its proton NMR spectrum? A. CC14 B. CHCl3 C. CH2C12 D. CH3CI 3) Which of the following has only a single peak in its proton NMR spectrum? I. (CH3)3CCI II. (CH3)2C=C(CH3)2 H,C...
can someone help me with this H-NMR? 364 Unsat. Index = (20 +2 -H -X +NY2...
can
someone help me with this H-NMR?
364 Unsat. Index = (20 +2 -H -X +NY2 = 13 6.86 700 d=2.44 ppm, Compound 18a. C, H, N 702 614 quartet, 2H 243 100 104 b = 6.85 ppm, c=3.64 ppm, a = 7.01 ppm, doublet, 2H 05 e = 1.06 ppm, doublet, 2H singlet, 2H 2.41 triplet, 3H 8, ppm 00 8.0 75 70 65 60 5.5 5.0 40 35 30 25 20 1.5 10 05 1) MeMgBr 12) H,O,...
1) What is/are the product (s) in the following reaction so,0, A) I only B) Il...
1) What is/are the product (s) in the following reaction so,0, A) I only B) Il only C) III only D) II and IV E) I and IV 2) A -NO2 substituent on the aromatic ring is a _in electrophilic aromatic substitution reactions. A) a deactivator and a m-director. B) a deactivator and an o,p-director. C) an activator and a m-director. D) an activator and an o,p-director. 3) Which compound would be expected to show a broad peak around 3000cm-1?...
if you could also explain how you can determine the answer, I would really appreciate it!...
if you could also explain how you can determine the answer, I
would really appreciate it!
1. (15 points) Assign the resonances in the spectrum shown. The resonances on the spectrum are labelled A-D. On the lines provided, write the label that corresponds to each of the groups. The multiplicity (s = singlet, d = doublet, etc) and the integrals are given for each resonance. OCH3 + S, 6H H3 C CH₂ H OCH₃ x D s, 3H d, 2H...
if anyone can check these answers for me and tell me which are right or wrong id appreciate it 0. How can p-aminobenzoic acid (a sunscreen) be synthesized from benzene? (Note that sometimes more...
if anyone can check these answers for me and tell me which are
right or wrong id appreciate it
0. How can p-aminobenzoic acid (a sunscreen) be synthesized from benzene? (Note that sometimes more than one isomer will be obtained, which is fine as long as the desired isomer is one of the major products.) several steps HOOC 4. Sn, HC 4.KMnO. .KMnO 4.Sn, HC 3.KMnO 3. CHCI, AİCİ, 3. Sn, HC . HNO, H SO 2. HNO,, H:SO4 1,...
Hi could you help me with this problem please? The following spectroscopic data were obtained for...
Hi could you help me with this problem please? The following spectroscopic data were obtained for an organic compound: i. MS (relative abundance in parentheses): M+ = 86 ; signals at 29 (92) and 41 (100) among others ii. IR (cm-1): 3100 (weak sharp), 2970 (medium sharp), 2850 (medium), 1650 (weak sharp), 1100 (strong sharp) iii. H1 NMR : Signal A at 4 ppm (3H, triplet), Signal B at 3.53 ppm (2H quartet), Signal C at 4.01...
For problems 7-12 answer the questions on the Mass Spectroscopy problem set worksheet.. Problem | Bond...
For problems 7-12 answer the questions on the Mass Spectroscopy
problem set worksheet..
Problem | Bond stretch- Molecular | Halogen/nitrogen IR frequency Ion Peak present? Explain Structure of Compound Structure of MS fragments at... m/= = 91 M = 91 3400cm m/z= 76/78 m/z = 58 m/s = 86 m/z = 58 1740 cm m/:=152/154 m/z= 107/109 m/t = 91 Compound 9 is a high-beiling liquid (boiling point 2010C) that reacts with alkoxide to yield an ether. The Man, IR,...
Please help me fill out this page I'm so lost. Please explain too, thank you! рр...
Please help me fill out this page I'm so lost. Please explain
too, thank you!
рр 0,43 2.dl 3.01 Code Number . STRUCTURE OF UNKNOWN (Draw Below) -. PROTON MAGNETIC RESONANCE SPECTRAL DATA Complete the table below by listing the chemical shifts of all of the signal patterns in the nmr spectrum of your compound (chemical shifts of clear multiplets are single numbers at the midpoint of the pattern, chemical shifts of complex multiplets are given as ranges). Assign the...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
Thanks! On each the following IR spectra, circle and indicate the most important stretching signal from...
Thanks!
On each the following IR spectra, circle and indicate the most important stretching signal from the following choices:N-H, O-H, CEN, CEO, C-O, Top, IR spectrum of Compound 18a: C14H1402 Bottom, IR Spectrum of Compound 18b: C3H120. write your answer on the corresponding square provided (2.5 pts each, 5 pts total) mar 2000 6 18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of...
Organic Lab Technique Problem Set 1) How many different sets of equivalent protons are there in the following compound? CI CH3CCH2C(CH3)3 CH3 5. Which or the spect A. three B. four C. five D. six 2) Which of the following gives the furthest downfield shift from TMS in its proton NMR spectrum? A. CC14 B. CHCl3 C. CH2C12 D. CH3CI 3) Which of the following has only a single peak in its proton NMR spectrum? I. (CH3)3CCI II. (CH3)2C=C(CH3)2 H,C...
can
someone help me with this H-NMR?
364 Unsat. Index = (20 +2 -H -X +NY2 = 13 6.86 700 d=2.44 ppm, Compound 18a. C, H, N 702 614 quartet, 2H 243 100 104 b = 6.85 ppm, c=3.64 ppm, a = 7.01 ppm, doublet, 2H 05 e = 1.06 ppm, doublet, 2H singlet, 2H 2.41 triplet, 3H 8, ppm 00 8.0 75 70 65 60 5.5 5.0 40 35 30 25 20 1.5 10 05 1) MeMgBr 12) H,O,...
1) What is/are the product (s) in the following reaction so,0, A) I only B) Il only C) III only D) II and IV E) I and IV 2) A -NO2 substituent on the aromatic ring is a _in electrophilic aromatic substitution reactions. A) a deactivator and a m-director. B) a deactivator and an o,p-director. C) an activator and a m-director. D) an activator and an o,p-director. 3) Which compound would be expected to show a broad peak around 3000cm-1?...
if you could also explain how you can determine the answer, I
would really appreciate it!
1. (15 points) Assign the resonances in the spectrum shown. The resonances on the spectrum are labelled A-D. On the lines provided, write the label that corresponds to each of the groups. The multiplicity (s = singlet, d = doublet, etc) and the integrals are given for each resonance. OCH3 + S, 6H H3 C CH₂ H OCH₃ x D s, 3H d, 2H...
if anyone can check these answers for me and tell me which are
right or wrong id appreciate it
0. How can p-aminobenzoic acid (a sunscreen) be synthesized from benzene? (Note that sometimes more than one isomer will be obtained, which is fine as long as the desired isomer is one of the major products.) several steps HOOC 4. Sn, HC 4.KMnO. .KMnO 4.Sn, HC 3.KMnO 3. CHCI, AİCİ, 3. Sn, HC . HNO, H SO 2. HNO,, H:SO4 1,...
For problems 7-12 answer the questions on the Mass Spectroscopy
problem set worksheet..
Problem | Bond stretch- Molecular | Halogen/nitrogen IR frequency Ion Peak present? Explain Structure of Compound Structure of MS fragments at... m/= = 91 M = 91 3400cm m/z= 76/78 m/z = 58 m/s = 86 m/z = 58 1740 cm m/:=152/154 m/z= 107/109 m/t = 91 Compound 9 is a high-beiling liquid (boiling point 2010C) that reacts with alkoxide to yield an ether. The Man, IR,...
Please help me fill out this page I'm so lost. Please explain
too, thank you!
рр 0,43 2.dl 3.01 Code Number . STRUCTURE OF UNKNOWN (Draw Below) -. PROTON MAGNETIC RESONANCE SPECTRAL DATA Complete the table below by listing the chemical shifts of all of the signal patterns in the nmr spectrum of your compound (chemical shifts of clear multiplets are single numbers at the midpoint of the pattern, chemical shifts of complex multiplets are given as ranges). Assign the...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
Thanks!
On each the following IR spectra, circle and indicate the most important stretching signal from the following choices:N-H, O-H, CEN, CEO, C-O, Top, IR spectrum of Compound 18a: C14H1402 Bottom, IR Spectrum of Compound 18b: C3H120. write your answer on the corresponding square provided (2.5 pts each, 5 pts total) mar 2000 6 18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of...
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