find k1,
kN/kS and k-1/ks
the values are:
Steady-state approximation, competition experiments. The solvolysis of 2-octylmethane-...
Steady-state approximation, competition experiments. The solvolysis of 2-octylmethane- sulfonate (RX) in aqueous solutions containing azide ions yields a mixture of alcohol and azide 35 Two mechanisms should be considered: ROH H+ X ROH H+ X H20 H2O IR versus RX kNIN3) kNIN3] RN3 X RN Derive the steady-state rate law for each, and the expression for the product ratio, ORN3MROHI, in terms of the rate constants and IN3 J. Use the following data (in 25 percent aqueous dioxane at 36.2 C) to decide between them by means of graphs or calculations: MROH IN k,in, 10-4 s (RN 2.21 3.02 0.076 0.625 3.64 0.156 1.28 0.237 1.11 1.95