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1.

nat would be an expected proton chemical shift range for protons attached to a methyl group as shown: Ar-O-CHs? O 3.8-4.5 ppm O 3.3-3.7 ppm O 2.2-2.7 ppm O 9.0-10.0 ppm 0 4.6-6.5 ppm

2.

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