1)
hex-3-ene react with Br2 to give cyclic bromonium ion then it will react with water molecule
followed by deprotonation to give 4-bromohexan-3-ol. water molecule acts as nucleophile
2)
hex-3-ene react with Br2 to give cyclic bromonium ion then it will react with Br-
to give 3,4-dibromohexane
3) hex-3-ene reduced with Pd/C H2 (via Syn hydrogenation reaction) to give n-hexane
4)- H added to double bond of hex-3-ene to give carbocation followed by nucleophilic addition to give 3-chlorohexane. Cl- act as nucleophile
5) Hydroboration are converts alkene into a alcohol Via Anti markovnikov addition ,regioseltctive and Syn stereochemistry
hex-3-ene react with BH3 to give boron complex followed by oxidation and hydrolysis to hexan-3-ol
Complete the following reactions. Br2 H2 Pd/C HCI 1. BH3 2. H202/NaOH
1) Determine the major product(s) of the following reactions. Show all appropriate stereochemistry. HCI Br2 1) BH3 w o dd 2) H202, NaOH (aq) Br2, H20
Draw the product(s) of the following reactions. 1. BH3/THF CEC-H 2. H202/ aqueous NaOH
Name: 230 Exam 3 past Q2 1. Complete the following reactions (no mechanisms). 1. BH3 THE 2. H2O/OH 1. mCPBA 2. H+/H.O 1. Os04 2. NaHSO, H2, Pd/C ha porc O Brz Br2
From the following list, determine the missing reagents. a. NaOH. b. Hz, Pd/C C. NaOH, H202 d. NaoMe, MeOH e. Na, NH3 f. H2SO4 H20 g. NaNH2 h. CrO2, H2SO4 (aq) 1. NaBH4, MeOH H2SO4, MeOH k. C PK I. Met m. Phli n. H2, Lindlar's catalyst O. BH3, THE p. Nah q. H30+ workup r. PCC s. OsO4, H2O2 t 03. -78 °C - H - K
Reagents Available a. H20, H2SO4, HgSO4 b. BH3 then H202 c. NANH2 d. CH3CH2Br e. HCI, ether f. H2, Lindlar catalyst g. Li, NH3 (ia) h. CH2l2, Zn(Cu) i. H2, Pd/C 1. Вrz. СH2Cl Select reagents from the above table to carry out each of the following reactions. If only a single step is required, select (none) from the drop down list. ? CH-CH-CH2C3CСН3 CH,CH-CH2CH2CH-CHз Reaction 1: Step 1: G Step 2: 0 CH3CH2CH2C CH CH,CH2CH2CH2CНО t Reaction 2: Step...
Complete the following reactions. 2. Complete the following reactions. (7) H2/Pt HNO3 Br2(1) Sn, HClI benzene2SOA H2SO4FeBrs (2) NaOH b. Heat OH (CH3)3 C. CH3o 0 NH2+ d.
Predict the products of the following reactions: Pd/C H2 Pd/C H2 Pd/C H2 Pd/C H2 Pd/C OH H2 Pd/C
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
2. Provide the major products from the following reactions. Starting Material Reagent(s) Product? Br2 Place appropriate groups H, Br CH, on scaffold) HCI Place appropriate groups (H, Br, CH, on scaffold) CH Brz/H20 Place appropriate groups H, Br CHs on scaffold] 1) O3 2) Zn/HOÁC LICH H2, Pd/C CH₂ 1. BH3 2. H2O2, NaOH(aq) CH2 hot KMnO4 in H2O - CH₂ CH3CO3H Product from above H30+, H2O
Complete the following reactions. Br 2) g) NaOMe NaCN H2, Pd/C CI