Question

0.01M 0.01M 0.01M 0.01M 0.10M 0.10M 0.1OM 0.10M NaCl 2. 3 2 2. Answer the questions below that relate to the 8 aqueous solutions at 25° C shown above. a) Which solution has the lowest freezing point? Explain. b) Above which solution is the pressure of the water vapor the greatest? Explain.N3, c) Which solution has the lowest boiling point? Explain. d) Which solution has the highest pH? Explain. K6H e) Identify the pair of solutions that would produce a precipitate when mixed together. Write the formula of the precipitate. f) Which solution could be used to oxidize the CI (aą) ion? Identify the product of the oxidation. LIMy g) Which solution would be the least effective conductor of electricity? Explain. CHO

Disregard the pencil markings.

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Answer #1

(a) The depression of freezing point of solution is given by the formula:

deltaTf = i * Kf * M

where i is Vanthoff factor which depends on number of ions produced from the solute in solution

Kf is freezing point depression constant of solvent (here water), M is concentration in molality

here, for all solutions, Kf and M are same. So the depression in freezing point depends on i. Among the given solutes, CaCl2 produces maximum number of ions (3) in solution. So, for the solution dpression in freezing point (delTf) is highest and this solution has the lowest freezing point.

(b) CH3OH is volatile and this solution has the greatest vapor pressure.

(c)

The elevation of boiling point of solution is given by the formula:

deltaTb= i * Kb * M

where i is Vanthoff factor which depends on number of ions produced from the solute in solution

Kb is boiling point elevation constant of solvent (here water), M is concentration in molality

here, for all solutions, Kb and M are same. So the elevation of boiling point depends on i. Among the given solutes, CaCl2 produces maximum number of ions (3) in solution and it has the maximum Vanthoff factor among the given solutions. So, for the solution elevation of point (delTb) is highest and this solution has the highest boiling point.

(d) Among the given solutes, KOH is the strogest base and it has the higest pH.

(e)

NaCl solution and AgNO3 solution produce a precipitate when mixed together. The formula of the precipitate is AgCl.

(f) LiMnO4 solution is used to oxidise Cl- and the oxidised product is Cl2

(g) Among the given solution, CH3OH is expected to have least conductivity as it is completely a non-electrolyte.

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