Name:. Date: Lab Section: 4. The blank solution used to calibrate the spectrophotometer is 5.0 mL...
Canvas +→ COD cuvet Question 11 25 pts A reaction mixture of 4.00 mL of 0.00200 M SCN and 5.00 mL of 0.00200 M Fetis diluted to 10.00 mL with 0.1 MHNO, to form the blood-red FeNCS complex. The equilibrium molar concentration of the FeNCS?determined from a calibration curve, is 1.5 x 10 mol/L. Calculate the equilibrium constant for the reaction shown below. Fe3+ (aq) + SCN-(aq) + FENCS?+ (aq) HINT: Be sure to account for the dilutions of the...
4.81 mL of 0.00200 M Fe(NO3)3, 2.85 mL of 0.00200 M KSCN and 2.34 mL of distilled water were mixed. The resulting solution was allowed to attain equilibrium at 24 oC. The absorbance of the equilibrium solution was recorded, and the [FeSCN2+] was determined graphically to be 7.58 x 10-5 M. Part A: Calculate the number of moles of Fe3+ initially added to the solution. Part B: Calculate the number of moles of FeSCN2+ formed in the solution at equilibrium....
A 25.0 mL volume of 0.0200 M Fe(NO3)3 is mixed with 50.0 mL of 0.00200 M NaSCN and 25.0 mL of 0.100 HNO3. The blood-red FeSCN2+ ion forms and the equilibrium is established: Fe3+(aq) + SCN-(aq) <---> FeSCN2+(aq) The equilibrium concentration of FeSCN2+ ([FeSCN2+]) was measured spectrophotometrically and found to be 7.0 x 10-4 mol/L. To calculate the equilibrium constant (Kc) for thr equilibrium system, proceed through the following steps: A. Moles of Fe3+, initial B. Moles of SCN-, initial...
I. Write the equilibrium constant expression, K for the following reaction Fe"(ag) FENCS(ag) SCN (ag) + CFENCS D 2. In part A of Experiment 34, it was assumed that all of the SCN added to the reaction mixture was converted to product (FeNCS). Which of the following best explains why that assumption was valid? A) The moles of Fe added equaled the moles of SCN- added. B) In part A, the SCN was the limiting reactant whereas in part B,...
Standard solutions of [Fe(SCN)2-] were prepared and their absorbance measured in order to study the Keq for the reaction Fe3+ + SCN- <=> FeNCS2+ A plot of absorbance verses concentration of [Fe(SCN)2-] is shown below. To determine the Keq for the above reaction, 10.00 mL of 0.00200 M Fe(NO3)3 solution is mixed with 5.00 mL of 0.0020 M KSCN and diluted with 5.0 mL 0f 0.10 M HNO3. The absorbance of this red solution is found to be 0.322....
Determination of an Equilibrium Constant 1) If 20.0 mL of 0.00200 M Fe(No3)3 is diluted to 50.0 mL, what is the concentration of Fe^+3 in the diluted solution? 2) Write the equilibrium for the following reaction. Co^+2 +4SCN^-1 <--> Co(SCN)4 ^-2 3) How many mmoles of SCN^-1 ion are there in 3.0 mL of 0.00200 M KSCN?
3. Experimental Procedure, Part A.1. For preparing a set of standard solutions of FeNCS, the equilibrium molar con- centration of FeNCS is assumed to equal the initial molar concentration of the SCN in the reaction mixture. Why is this assumption valid? A. A Set of Standard Solutions to Establish a The set of standard solutions is used to determine the absorbance of known molar con- centrations of FeNCS2. A plot of the data, known as a calibration curve, is used...
누 4. After completing Part A of this experiment, a student determines the slope of their calibration graph of absorbance versus [FeSCN"] to be 5140 M1. In Part B, a student combines 2.00 mL of a 0.00200 M solution of KSCN with 5.00 mL of 0.00200 M solution of Fe(NO,), and 3.00 mL of water. The following equilibrium is established. Fe (aq)+ SCN (aq) - FeSCN (aq) The absorbance of the equilibrium solution is measured as 0.246. What is the...
4 please in part 1 gires us absorbance values for each sample , changes in concentration and absorbance will cause a curve 1. For each new concentration of FeSCN2+ a new absorbance will be plotted. 4. After completing Part A of this experiment, a student determines the slope of their calibration graph of absorbance versus (FeSCN to be 5140 M". In Part B, a student combines 2.00 mL of a 0.00200 M solution of KSCN with 5.00 mL of a...
Section Name Experiment 23 Advance Study Assignment: Determination of the Equilibrium Constant for a Chemical Reaction 1. A student mixes 5.00 mL 2.00 X 10M Fe(NO), with 5.00 ml 2.00 x 10-M KSCN. She finds that in the equilibrium mixture the concentration of FeSCN is 1.40 x 10M. Find K for the reaction Fe(aq) + SCN (aq) FeSCN2(aq). Step 1 Find the number of moles Fe and SCN initially present. (Use Eq. 3.) (5.00 x103 LX (300X163) = (x 103...