Primary alcohols can be dehydrated to form ethers. Complete the following reactions. Show all the following...
Write structures for products. Pay attention to siereochemistry TsCI NaOH Pyridine SH2 OH TsCI LiCI Pyridine 1) BH, THIF 2) H02. OH NaH OH 5) Primary alcohols can be dehydrated to form ethers. Complete the following reactions. Show all the possible products where applicable H,SO,, 180 c OH H,SO,, 180 C
compare the compounds shown below and select all primary alcohols and all ethers Compare the compounds shown below and select all primary alcohols and all ethers. CH, OH | CH-CH-CH-CH, CH3-CH-CH-CH CH3-CH=CH-CH-CH2OH CH, CH -CH-CH, CH, OH CH3-CH-CH-O-CH3 CH, CH OH CH OV
Chapter 11. Reactions of Alcohols, Amines, Ethers, and Epoxides 14) What is the major product for the following reaction? HO H2SO4 heat Answer: Section: 15) Rank the following alcohols in decreasing order of relative ease of dehydration: OH OH CH-OH A) A > B>C>D B)D>C> A>B C) C> A >D>B D) B>D>C>A E) A > C>D>B Answer: Section:
Complete the following reactions which form ethers (A and B) and cyclic ethers (C-E) as major products. SHOW MECHANISMS FOR ALL A) (1R, 2R)1,2-dimethylpropan-1-ol (2 has a dash Methyl and 1 has a wedge methyl) reacts with NaH/CH3CH2Br B) 3-methylpent-3-ene reacts with Hg(OAc)2/ CH3CH2OH, NaBH4 C) 2-cyano-6-methyl cyclohept-1,4,6-triene-4-al reacts with MCPBA/CH2Cl2 D) (2R,3S)- 2-bromo-butan-3-ol reacts with NaOH E) Cyclobutyl as the base chain with (CH2OH attached at Carbon 1 and CH2CH2Br attached at carbon 2) reacts with KOH F) 2-methylcyclohexene...
Compare the compounds shown below and select all primary alcohols and all ethers CH CH CHOH сн, a-a-a,-a-a, C-H--C CH-CH-CH-CH al-CH-CH- CH,-CH-C-0-CH Cll OH Cll CH V II IV MacBook Air o00 F2 F3 F4 F6 F7 $ % 2 3 4 5 6 8 U W E R T o 7
Pls help with all three questions! 1. Primary and secondary alcohols can be converted to alkyl chlorides using SOCI. OH SOCI pyridine Show the mechanism and predict the product of the reaction 2. Tertiary alcohols can be synthesized from the reaction of Grignard reagents with ketones (1) CH CH CH MgBr (2)H,0 Show the mechanism and predict the product of the reaction. 3. Complete the following reaction: TSCI NaCl CH;OʻNa CH,OH 7 он
4. Predict the possible organic product(s) from the following reactions. Where relevant, show all stereoisomers. Pay particular attention to any information given in the product boxes. explair wnswers daw aroustolz OH Can you + HCI substitution AND elimination products + Н,о но., HCI only products with formula C1ghH1C +H2O H2SO4 OH only products with formula CeH120 HBr + 6 mono-addition products including stereoisomers 1 1
Question 5) Write a complete stepwise mechanism to account for the following reactions. Show all intermediate structures and all electron flow with curved arrows. (10 points each) 1) O2, heating OH 2) H2SO4, H2o
Chem 322L Assignment 4 1. Classify each of the following alcohols as primary, secondary, or tertiary. нс Үсн, OH a) Hzc? H2C CH CH c) HO 2. Identify (Circle) and name the three functional groups in the following molecule. CO2H HOC 3. Provide the products of the following reactions. COOH + CHOCH.CH w a CH HO b) 4. Complete the solution of the exercise below by writing out the mechanism step by step. Tetrahedral intermediate 5. Give the structure of...
"Complete the reactions showing all Major Products, both substitution and elimination, that can form based on the reaction conditions. Be sure to show stereochemistry where appropriate. Fill in each table with reaction conditions." w upiete the following reactions showing all products, both substitution and elimination, that can form, then circle the MAJOR Foduct(s). Under each reaction, draw the step by step mechanism showing how each porduct is formed. Show or indicate stereochemistry where appropriate. Fill in each table with reaction...