1. 2 points) Consider the following compounds. Indicate with an arrow(s) the position(s) of the next...
2. (12 points, 6 points each) Give the arrow pushing mechanism for To of the following reactions. Draw the resonance structures of the intermediate. You MUST include the mechanism for the formation of the electrophile for electrophilic substitution reactions. Do not combine steps and be sure to show arrows and charges for all steps. Gie Twoyo.coc.c.m.m.ci.e groded..ay are wotcleurly marked hwiti only gade wor A. HNO, H,So B. 1. AICI 2. H2o C. OzN NO2 NaOCH2CH 02N. heat N/A D....
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Provide the reagents necessary to carry out the following conversion. NO Br Choose the correct reagents for step 1. fuming H2SO4 Br2/ FeBr3 HNO3/ H2SO4 CH3Br / FeBr3 Choose the correct reagents for step 2 HNO3/ H2SO4 CH3Br/ FeBr3 fuming H2SO4 Br2/ FeBry Which one of the following substituents will direct the incoming group to the meta position during electrophilic aromatic substitution? -NO2 -CEN -CCl -COOH all of these O O Identify the electrophile...
1. Determine which of the following compounds are aromatic or
antiaromatic. SHOW CALCULATIONS!
2. Provide the product and a stepwise mechanism for the
following reaction. Include all intermediates, resonance
structures, and electron pushing arrows.
1. (4 points) Determine which of the following compounds are aromatic or anti- aromatic. SHOW CALCULATIONS! 0: O NO 0: 2. (8 points) Provide the product and a stepwise mechanism for the following reaction. Include all intermediates, resonance structures, and electron pushing arrows. OHC CH3NH2 CI
9. For the compound below answer a b and c. a) b) c) (3 pts) is the molecule below an aromatic or anti-aromatic estem? (4 pts) How many electrons are in the aromatic anti aromatic bratem? (4 pts). Draw an arrow () to the lone pair electron(s) that are part of the aromatic (or anti-aromatic) system. 10. (18 pts-6 pts each) Fill in the major organic product(s) for the reactions below Br+FeBr ci + CH CH CH .. 3+ AICI:...
all three questions
Application Questions 1. Draw the mechanism for the sulfonation of benzene. Use HSO as the electrophile. Draw the all the resonance structures of the stabilized cation intermediate 2. Draw the major product formed when each of the following compounds is treated with Cly/AICI, Assume chlorination only occurs in one position on the ring rather than multiple positions. COM COCX ooo 3. Predict whether toluene or chlorobenzene would undergo electrophilic aromatic substitution more quickly when treated with C1z/AICI....
1. please check what is wrong. Thank you!
Determine the product formed when each compound is treated with Br2 and FeBr3. Drag the atom labels to their appropriate positions. CN Atom labels H H Br Br2 A. FeBr Br H OH OH Br Br. Br2 FeBr3 H H Br Br H Br2 FeBr H1 H Reset T Rank the compounds in each group in order of decreasing reactivity in electrophilic aromatic substitution. CI Decreasing reactivity Rank the compounds in each...
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Provide the reagents necessary to carry out the following conversion. CCl3 Choose the correct reagents for step 1. excess Cly, heat O Cl2/FeCl3 CH3CI / AICI: dilute H2SO4 fuming H2SO4 Choose the correct reagents for step 2. fuming H2SO4 excess Cl2, heat Cl2 / FeCl3 CH3Cl / AICI dilute H2SO4 Choose the correct reagents for step 3. CH3CI / AICI dilute H2504 excess Cl2, heat fuming H2SO4 Cl2 / FeCl3 Provide the reagents necessary...
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Provide the reagents necessary to carry out the following conversion. ОСН Br Br NO2 Choose the correct reagents for step 1 fuming H2SO4 HNO3/H2S04 excess Br2/ FeBr3 dilute H2SO4 O Cl2/FeCly O CH3ONA Choose the correct reagents for step 2. Cl2/ FeCl3 HNO3/H2SO4 CH3ONA fuming H2SO4 excess Br2/ FeBr3 dilute H2SO4 Choose the correct reagents for step 3 CH3ONA HNO3/ H2SO4 O excess Br2/ FeBr3 Odilute H2S04 fuming H2SO C2/ FeCl Choose the correct...
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Which of the following reactions would produce isopropylbenzene as the major product? ОН AICI: H2SO4 H2SO4 AICI3 IV I all of these Predict the product for the following reaction fuming H2SO4 SO3H Predict the structure of the major product for the following reaction Which of the following compounds will not undergo nucleophilic aromatic substitution? 1-chloro-2,4-dinitrobenzene 1-bromo-4-nitrobenzene O-chloronitrobenzene m-chloronitrobenzene p-chloronitrobenzene Choose the correct sequence of reagents for the following transformation. 2) 3 . NH2 2)...
1. For the following compounds, label each substituent as electron donating or electron withdrawing, and indicate whether this effect is achieved via induction or resonance. ŅO2 H2N SO3H 2. Predict the TH NMR of the above benzene derivatives. For chemical shift, indicate whether the peak would likely be downfield or upfield of benzene (7.2 ppm). (Hint: think about the resonance structures that can be drawn based on your responses from above) A B # of peaks chemical shift indicate: >7.2,...