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13. (4 points) Circle the lower energy 2-chlorobutane: w, CH3 CH3 H3C
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13. in the structures, circled one is more stable.because here the bulky groups are away from each other.so the steric hindrance is minium,therefore the structure attains more stability and posses lower energy.

22. by increasing pka of acid , acidic strength decreases.so that in the given backward reaction is favourable,but not forward.

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