Homework Answers
Answer: b. 1R,2S.
On C1 the least prior group is on solid wedge.so that,configuration is opposite to rotation.
On C2 the least prior group is on broken wedge.so that,configuration is similar to rotation.
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e based on compound A shown below: many chiral stercoisomers can be drawn for compound A...
Determine the number of chiral centers associated with the compound below, and determine the absolute configurations...
Determine the number of chiral centers associated with the compound
below, and determine the absolute configurations of five chiral
carbon centers amongst the compound below. Place the appropriate R
or S symbols next to the appropriate chiral carbon center.
Answer (# of Chiral Centers): CHCI(CH3) Cl OH e number of chiral centers (ie., Indicate by using *) associated with the compound below and determine the absolute configurations (i.e., R or S) of five chiral carbon centers amongst the compound ow....
29 Give the configurations, respectively, of the following two molecules. CH HO H and CI A. B. C....
29 Give the configurations, respectively, of the following two molecules. CH HO H and CI A. B. C. R and R R and S S and S D. S and R 30 Give the configurations, reypectively, of the folowing two molecules H CH CHy A. B. C. R and R R and S Sand S D. S and R Which one of the following groups has the highest rank as assigned by the Cahn- Ingold-Prelog system for stereogenic (chiral) carbons?...
c. cis-1-metbylbicylol0.4.4ldecan 24. Which structure is syn? d. trans-1-methylbicyclo[0.4.41derane e. not a.-d с. e. not a.-d...
c. cis-1-metbylbicylol0.4.4ldecan 24. Which structure is syn? d. trans-1-methylbicyclo[0.4.41derane e. not a.-d с. e. not a.-d 25. Monocyclic alkenes (for example, cyclepropene, cyclobutene, etc.) up to 7 carbons are all? a. b. R C. S d. Z e. not a.-d. 26. The following stereoisomer of a controlled substance is? (Hint: The alcohol is the 1 carbon.) a. 1R, 2R) b. (1R, 25) c. (1S, 2R) d. (1S, 2S) e. not a.-d 27. The carbon with the asterisk is? a. с....
3. (4 pts) Complete the Fischer projection drawn below by adding the four substituents to the chiral carbon of (s)...
3. (4 pts) Complete the Fischer projection drawn below by adding the four substituents to the chiral carbon of (s)-2-methyl-3-bromo-hexane. 4. (4 pts) Draw a wedge and dash structure representing (1R 2R,3S)-1,2- dichloro3-ethylcyclohexane. 5. (4pts) 2-bromobutane is shown below. Is this (R)-2-bromobutane or (S)-2 bromobutane? 6. (6 pts) For each chiral carbon in ascorbic acid (vitamin C), shown below, assign Ror S to each stereocenter. How many stereoisomers of ascorbic acid are possible? OH HO ОН 7. (9 pts) (Are...
15) How many asymmetric carbons are present in the compound below? нонс Ho OH OH 16)...
15) How many asymmetric carbons are present in the compound below? нонс Ho OH OH 16) How many asymmetric carbons are present in the compound below? ÇOH но- H OH H OH COZH 17) How many asymmetric carbons are present in the compound below? -ethyl-2,2,4-trimethylpentane 18) Can the molecule shown below be properly described as a meso compound? B 19) Can the molecule shown below be properly described as a meso compound? 20) Can the molecule shown below be properly...
Identify the labeled chiral carbons as Ror Sin the molecule shown below. HO. ОН Br Br...
Identify the labeled chiral carbons as Ror Sin the molecule shown below. HO. ОН Br Br IIIIII H 2) H' 1) CH3 CH, A 15.25 OB 15.2 O C 1R.25 Fullscre
I just need 16-22 explained. 15) How many asymmetric carbons are present in the compound below?...
I
just need 16-22 explained.
15) How many asymmetric carbons are present in the compound below? ttjus of atoms or greups of Atoms нон-с но Но- ОН Он 16) How many asymmetric carbons are present in the compound below? CO2H Н- OH н- OH CO2H 17) How many asymmetric carbons are present in the compound below? 3-ethyl-2,2,4-trimethylpentane 18) Can the molecule shown below be properly described as a meso compound? 19) Can the molecule shown below be properly described as...
A. aldehyde B. ketones C. carboxylic acids D. esters 7, How many stereoisomers of 2,4-pentanediol are...
A. aldehyde B. ketones C. carboxylic acids D. esters 7, How many stereoisomers of 2,4-pentanediol are possible? но он В. З A. 2 C. 4 D. 6 8.Which one of the following is a diastereomer of (2R, 3R)-2,3-dibromopentane? A. (2S,3S)-2,3-dibromopentane C.R-1,2-dibromopentane B. (2S,3R)-2,3-dibromopentane D. (2R,4R)-2,4-dibromopentane 9. Which one of the following groups has the highest rank as assigned by the Cahn-Ir Prelog system for stereogenic carbons? A. -CH-CH2 B. -CH20H C.-CH-0 D. -CH2SH 10. Which of the following statements are...
Which of the following is written correctly? A. Fisher projections are typically drawn with hydrogens on...
Which of the following is written correctly? A. Fisher projections are typically drawn with hydrogens on vertical lines and carbon chains on horizontal lines. B. In the case of a tie, atom priorities are assigned based on the functional groups attached to the next atom in the chain C. When choosing between R and S the highest priority atom should be pointing atom should be pointing toward the viewer. D. Rotation around C = C is typically hindered because of...
A. aldehyde A. two 15. W B. ketones C. carboxylic acids D. esters 7. How many stereoisomers of 24-pentanediol are p...
A. aldehyde A. two 15. W B. ketones C. carboxylic acids D. esters 7. How many stereoisomers of 24-pentanediol are possible? HO D. 6 A. 2 B.3 C. 4 8. Which one of the following is a diastereomer of 2R 3R)-2,3-dibromopentane? B. (25,3R)-2,3-dibromopentane D. (2R, 4R)-2,4-dibromopentane A. (2S,3S)-2,3-dibromopentane C. R-1,2-dibromopentane y. Which one of the following groups has the highest rank as assigned by the Cahn-Ingold Prelog system for stereogenic carbons? A. -CH=CH2 B. -CH2OH C. -CH=0 D.-CH2SH 10. Which...
Determine the number of chiral centers associated with the compound
below, and determine the absolute configurations of five chiral
carbon centers amongst the compound below. Place the appropriate R
or S symbols next to the appropriate chiral carbon center.
Answer (# of Chiral Centers): CHCI(CH3) Cl OH e number of chiral centers (ie., Indicate by using *) associated with the compound below and determine the absolute configurations (i.e., R or S) of five chiral carbon centers amongst the compound ow....
29 Give the configurations, respectively, of the following two molecules. CH HO H and CI A. B. C. R and R R and S S and S D. S and R 30 Give the configurations, reypectively, of the folowing two molecules H CH CHy A. B. C. R and R R and S Sand S D. S and R Which one of the following groups has the highest rank as assigned by the Cahn- Ingold-Prelog system for stereogenic (chiral) carbons?...
c. cis-1-metbylbicylol0.4.4ldecan 24. Which structure is syn? d. trans-1-methylbicyclo[0.4.41derane e. not a.-d с. e. not a.-d 25. Monocyclic alkenes (for example, cyclepropene, cyclobutene, etc.) up to 7 carbons are all? a. b. R C. S d. Z e. not a.-d. 26. The following stereoisomer of a controlled substance is? (Hint: The alcohol is the 1 carbon.) a. 1R, 2R) b. (1R, 25) c. (1S, 2R) d. (1S, 2S) e. not a.-d 27. The carbon with the asterisk is? a. с....
3. (4 pts) Complete the Fischer projection drawn below by adding the four substituents to the chiral carbon of (s)-2-methyl-3-bromo-hexane. 4. (4 pts) Draw a wedge and dash structure representing (1R 2R,3S)-1,2- dichloro3-ethylcyclohexane. 5. (4pts) 2-bromobutane is shown below. Is this (R)-2-bromobutane or (S)-2 bromobutane? 6. (6 pts) For each chiral carbon in ascorbic acid (vitamin C), shown below, assign Ror S to each stereocenter. How many stereoisomers of ascorbic acid are possible? OH HO ОН 7. (9 pts) (Are...
15) How many asymmetric carbons are present in the compound below? нонс Ho OH OH 16) How many asymmetric carbons are present in the compound below? ÇOH но- H OH H OH COZH 17) How many asymmetric carbons are present in the compound below? -ethyl-2,2,4-trimethylpentane 18) Can the molecule shown below be properly described as a meso compound? B 19) Can the molecule shown below be properly described as a meso compound? 20) Can the molecule shown below be properly...
Identify the labeled chiral carbons as Ror Sin the molecule shown below. HO. ОН Br Br IIIIII H 2) H' 1) CH3 CH, A 15.25 OB 15.2 O C 1R.25 Fullscre
I
just need 16-22 explained.
15) How many asymmetric carbons are present in the compound below? ttjus of atoms or greups of Atoms нон-с но Но- ОН Он 16) How many asymmetric carbons are present in the compound below? CO2H Н- OH н- OH CO2H 17) How many asymmetric carbons are present in the compound below? 3-ethyl-2,2,4-trimethylpentane 18) Can the molecule shown below be properly described as a meso compound? 19) Can the molecule shown below be properly described as...
A. aldehyde B. ketones C. carboxylic acids D. esters 7, How many stereoisomers of 2,4-pentanediol are possible? но он В. З A. 2 C. 4 D. 6 8.Which one of the following is a diastereomer of (2R, 3R)-2,3-dibromopentane? A. (2S,3S)-2,3-dibromopentane C.R-1,2-dibromopentane B. (2S,3R)-2,3-dibromopentane D. (2R,4R)-2,4-dibromopentane 9. Which one of the following groups has the highest rank as assigned by the Cahn-Ir Prelog system for stereogenic carbons? A. -CH-CH2 B. -CH20H C.-CH-0 D. -CH2SH 10. Which of the following statements are...
Which of the following is written correctly? A. Fisher projections are typically drawn with hydrogens on vertical lines and carbon chains on horizontal lines. B. In the case of a tie, atom priorities are assigned based on the functional groups attached to the next atom in the chain C. When choosing between R and S the highest priority atom should be pointing atom should be pointing toward the viewer. D. Rotation around C = C is typically hindered because of...
A. aldehyde A. two 15. W B. ketones C. carboxylic acids D. esters 7. How many stereoisomers of 24-pentanediol are possible? HO D. 6 A. 2 B.3 C. 4 8. Which one of the following is a diastereomer of 2R 3R)-2,3-dibromopentane? B. (25,3R)-2,3-dibromopentane D. (2R, 4R)-2,4-dibromopentane A. (2S,3S)-2,3-dibromopentane C. R-1,2-dibromopentane y. Which one of the following groups has the highest rank as assigned by the Cahn-Ingold Prelog system for stereogenic carbons? A. -CH=CH2 B. -CH2OH C. -CH=0 D.-CH2SH 10. Which...
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