Reaction A is highly energetic and energetically disfavored due to formation of BH2- which is unstable
Reaction B is less energetic and energetically favorable due to formation of BH3-OH- ion in which the central atom get octet of electrons
Question 2 (24 pts.) For the following reactions A and B a) Add the curved arrows...
a) Give a full curved-arrow pushing mechanism, indicate the Lewis and Bronsted acids/bases for each intermoelcular step as appropriate, indicate the rate determining step. Give the number of sets of intermediates and the number of transition states included in your mechanism. HO: H20 HCI (catalytic) # of sets of intermediates # of transition states b) Draw a reaction energy diagram, do not draw the transition states for each step but indicate their positions on the diagram and also the positions...
3. Indicate the nucleophilic group and the electrophilic group in each of the following reactions, then draw curved arrows to show the electron flow: (a) H- N H -CH: (D) - (C) NH :CI: CI-APë: :CA: 1-ci: A-CI: 4. The following reaction has a small, positive AG and takes place slowly at room temperature: H3C-CI H-OH - H3C-OH - H-CI (a) The mechanism for the reaction is shown below. Which bond is being broken in the slowest step? Which bond...
Propose a detailed mechanism for the following transformation. Use curved arrows to show movement of electron pairs and be sure to draw structures of all important reaction intexmediates, State the name of the reaction below. NaOH, EtOH, A OCH3 OCH (11 marks] Draw a reaction energy diagram, and label the product (P), reactant (R), transition states CTS. TS, etc), intermediates (INT1, INT2, etc.) and activation energies (AG', AG , etc.) for a reaction with the following criteria: i. A three-step,...
Chapter Exhibit 6-5 Add curved arrows to the following reactions to indicate the flow of electrons in each. = 23. --H + H2C - M9Br - CH + H : MgBx Exhibit 6-9 Use the reaction energy diagram below to answer the following question(s).
2. Consider the following SNl reaction: H3 CHs CH3 CH3 i. Draw a mechanism using curved arrows. Show all step(s) involved in bond breaking& forming. ii. Draw an energy diagram. Label the axes, the reactants, products, Ea, and AH. Assume that the reaction is exothermic. ili Draw the structure of the intermediate product at the correct position in the energy diagram.
Draw curved arrows for each step of the following reactions and indicate the type of curved arrow drawn (e.g nucleophilic attack, hydride shift, etc.). Please solve and explain. Thank you. 2. Draw curved arrows for each step of the following reactions and indicate the type of curved arrow drawn (e.g. nucleophilic attack, hydride shift, etc.) (8 pts). B: OH Li-Me
Draw curved arrows to show electron reorganization for the reaction step below. Arrow-pushing Instructions Visited GN=C: + Học : – GN=C–CH+ :: reg (References] Draw curved arrows to show electron reorganization for the reaction step below. Arrow-pushing Instructions Visited 210g 2re :o: H3c-c-c: :0-H :o: H3C-©-OH + :C: For the reaction below: H2C=CHCH2-H – OH H2C=CHCH2 + H-OH a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click...
(a) Draw a stepwise, detailed mechanism for the following reaction. Used curved arrows to show the movement of electrons. Br CN NaCN DMF NaBr (b) Assign the configuration (Ror S) of the chiral centre in the substrate and product (c) List the bonds broken and formed in this reaction (d) Assume that this is an endothermic reaction. Draw an energy diagram for this reaction. Label the axes, reactants, products, E, and AH. Draw the structure for both transition states.
4. Add curved arrows to show the movement of electrons in each of the following reactions. Note that you should draw in any lone pairs that are relevant to the mechanism. (a) OCH2 CH3 -O. H + (b) CH3 IN OH CH2 + +
2. Draw the following the energy diagrams: a. exothermic reaction with small activation energy b. endothermic reaction with large activation energy c. exothermic reaction with large activation energy d. endothermic reaction with small activation energy