Question

State whether following reactions are spontaneous at all temperatures, low temperatures, high temperatures or not spontaneous

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Answer #1

a)
Since reaction is endothermic,
ΔHo is positive

ΔSo is negative because there are more gases in reactant side of reaction than in product side.

ΔGo = ΔHo - T*ΔSo
For reaction to be spontaneous, ΔGo should be negative

Here
ΔHo is negative
ΔSo is negative
So,
ΔGo will be negative at low temperature.
The reaction is spontaneous at low temperature.
Answer: low temperatures

b)
Since reaction is exothermic,
ΔHo is negative

ΔSo is negative because there are more gases in reactant side of reaction than in product side.

ΔGo = ΔHo - T*ΔSo
For reaction to be spontaneous, ΔGo should be negative

Here
ΔHo is positive
ΔSo is negative
So,
ΔGo will always be positive.
The reaction is spontaneous at no temperature.
Answer: not spontaneous at any temperatures

c)
Since reaction is exothermic,
ΔHo is negative

ΔSo is positive because there are more gases in product side of reaction than in reactant side.

ΔGo = ΔHo - T*ΔSo
For reaction to be spontaneous, ΔGo should be negative

Here
ΔHo is positive
ΔSo is positive
So,
ΔGo will be negative at high temperature.
The reaction is spontaneous at high temperature.
Answer: at high temperature

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