3) Provide structural formulas for A. B, C, D and E (15 points). PCC CH3CH2-NH2 -H20...
3) Draw the products of the following hydrolysis reactions. (A) Heat CH3CH2-CH-C-NH-CH3 + HCl + H20 (B) CH, CH, CH, CẠNH CHI Heat + NaOH CH2CH, Heat + HCl + H20 - (D) | " , , wa wo wa – Heat CH3-C-NH2 + HCl + H20 - Heat CH3-C-NH2 + NaOH
3. Draw the structural formulas for the following compounds. (10 points, 2 each) a. 2-propanol b. 2-methyl-5-hexene-2-ol c. 3-cyclohexenol d. 4-nitrophenol e. phenol 4. Classify the following substituents as ortho/para or meta directing and activating or deactivating (two part answer for each group) (note the line 34 indicates where the group is attached to the benzene ring. (12points, 2 each) NH2 Ooh &r HC-CH₃ No? QH
Complete the following structural formulas by adding the proper number of Hydrogen atoms: C-C(NH2)-COOH
5. Match the reagents to the corresponding reaction. I Cl NH2 OH II NH2 G. H20 A. SOCI2, pyridine B. Ethanol, pyridine H. xs CH3CH2NH2 I. 1) LIAI(OR)sH 2) H2O C. 1) xs LAH 2) H20 J. (CH3CH2)2CuLi D. 1) xs CH3CH2MgBr 2) H2O K. xs NH3 E. 1) NaOH 2) H30 L. 1) NaOH 2) CH3CH2CH2COCI F. 1) DIBAH 2) H20 M.Butanol, H
What is the conjugate base of each of the following acids? (a) NH3 (b) H20 (c) H2 (d) HC=CH (e) CH3OH (f) H307 What is the conjugate acid of each of the following bases? (a) HS04 (6) H2O (C) CH3NH2 (d) NH2 (e) CH3CH2 (f) CH3CO2
CompleProducs 13 MB 1) NaB 2) H20, At b) C) OH d) H PCO e) f) 2) H30 3) PCC 3) 430+ 1) LAM 20 h) SIGNATURE
provide the major product in the following reaction NH2 NaBH3CN a. NaNg, EtOH b. H20, A ОН 1. SOCI2, pyridine 2. NaN3, DMF 3. LIAIH4, Et20
10. (10 points) Provide the IUPA C name for each of the following compounds. a) b) c) d) e) Br Br 11. (8 points) DRAW, using line angle formulas, and NAME, FOUR (4) different structural isomers with the molecular formula CHI
Provide the reagents necessary to carry out the following conversion. A) B). C) Đ) E) 1. H2O/ H2SO4, 2. PCC/CH2Cl2 PCC/ CH2Cl2 1. BH3, 2. H2Oz/NaOH/H2O 1. 03, 2. Zn/acetic acid 1. BH3, 2. H2Oz/NaOH/H20, 3. PCC for the following reaction
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20 refux 9- NH2 CH -C-Cl 10. 2.HaO кон. rMso 12- CH3 CH Ch 13- NH2 14- -78C 15- OH LiAIH 4 16- socl2 2 pyridine P2Os NH2 18- 1. NaHCO.. H2O 2. OH Br 19. 2, H30 20- 1. BH4 2. H3O 21- 22- 2. PBr 3.2 equiv. CH,CH CH&NH 23- 1. Mg Br 3. NaHCO Cl 24- 2 LAH 25-