Drag the omitted molecule/reagent into the appropriate box. HO 1) EtOH, H+ 2) Et Culi 1)...
Predict the products. 16. K2Cr207 (excess) H2SO4, H2O HO 1. Phli, Et20 2. HCI, H20 3. SOCI2, Etz 4. NaOAC 1. Mg (1 eq), Et O Br 2. (1 eq) | C-CHO 3. HCI, H20 1. NaBH, MeOH, 0°C 2. PBrz. THE 3. LiAIDA, THE 4. HCI, H20 1. SOCI, NEtz, THE CHO 2. 2 eq Li, hexane 3. HCI, H20 hint: multiple steps 1. LiAlH4, THE 2. HCI, H2O 3. PBr3, THE 1. PCC, DCM OH 2. Mg, Eto...
Question 3 (20 points) – Fill in the missing reagent, reactant, or product Y 1)CH,CIAICI: 2) KMnO /H, SO 3 SOCI Cl2 (3 eq) Fecig 1) (CH2CH2),Culi 2) H2O/H,O* Michael Acceptor PCC ii.
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4) H NET,...
5,6,7,8th please 5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4)...
Question 3 (20 points) – Fill in the missing reagent, reactant, or product V 1) CH,CVAICI, 2) KMnO4/H2SO4 3 SOCI, CI(3 eq) FeCl2 1) (CH2CH2),Culi 2) H,O/H3O+ Michael Acceptor PCC i. 1) KOC(CH):/HOC(CH): 2) mCPBA الد 3) CH,MgBr 4) H2O/HO* NH A 1) NH, TH,SO4 (cat.) 2) NADH 1) 2) 3)
3. For each of the following transformations select the most appropriate reagent(s). (6 points) . سئو -- 0 A. B. CrOz/acetone-H2O 1) DMSO, (COCI), 2) Et3N C. PCC/CHgCl2 (NOTE: PCC = o=وه D. Na2Cr20/ H2SO4 - H20 - . و وهده E. DMP/CH2Cl2 (NOTE: DMP = F. None of the above . سند - G. All of the above
In each reaction box, place the best reagent and conditions from the list below. M 1) Bra 2) 2 equiv. NaNH, HBO 3) 4) H.O., NaOH, H20 BHYTHF CHOBI Hz. Lindlar catalyst bromocyclohexane H30. H SOL. HgSO4 NaBHA CH CH Br excess NaNH3, then H20 SOCI
Choose the most appropriate reagent(s) for the conversion of the amide to the amine target molecule. SOCI2 Ph OH Ph CI HN Ph N reagent(s) I- I- A H2, Pd B NaBH4, CH3OH © NaNH2, NHz 1. LiAIH4 2. H*, H20 E NH2NH2, KOH
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
K2Cr2O, (excess) HASOHO 1. Phli, Et 2. HCI, H2O 3. SOCI, EIN 4. NaOAC 1. Mg (1 eg). Et, 2. i (19) -CHO 3. HCI, H20 1. NaBH4, MeOH, 0°C 2. PB.. THE 3. LIAID, THE 4. HCI, H20 1. SOCI, NE. THE 2. 2 eq Li, hexane 3. HCI, H20 Pintuicio sops 1. LiAlH. THE 2. HCI, H2O 3. PB. THE 1. PCC, DCM OH 2. Mg, Et20 3.HCI, H20 1. MsCl, pyr 2. KO'Bu, 'BuOH