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7) Give the mechanism including the transition state. сн.ct çı SN2 НН 8) Give the mechanism....
4.2 Give a detailed mechanism and show the products of the following reactions: OF CH3 C...
4.2 Give a detailed mechanism and show the products of the following reactions: OF CH3 C (6] a) C-H E2 ООCH H CHз H b) H3CC E1 CH3 Н-О Br 4.3 Label the following reactions as SN1, SN2, E1, or E2. . Br NaNH2 THE a) HN CI КОН Ethanol b) но Ethanol c) NaOH Ethanol P OH 4A samnle with a.concentration of 0 3 a/ml was nlaced in a cell with a lenath of 5 cm 41
What kind of reaction is this? SN1, SN2, E1? Please solve and include a transition state...
What kind of reaction is this? SN1, SN2, E1? Please solve and
include a transition state if there is one. Thank you!
2. Propose a reasonable mechanism, using curved arrow notation, for the following transformation. Include a structure for any transition state. AgNO3 Eto X Br ethanol
5. For each transformation below, name each mechanism as SN1, SN2, E1, or E2. Label your...
5. For each transformation below,
name each mechanism as SN1, SN2, E1, or E2. Label your answers in
correspondence to the reactions a) to d).
5. For each transformation below, name each mechanism as Syl, SN2, E1, or E2. Label your answers in correspondence to the reactions a) to d). [1.3 Marks a) .H H -СН3 Y CH3 + H2O+ b) + ROH + CI- "Como lag for "&- 16.5 for + Br + Br- + Br
find products for the following interactions and identify the mechanism as sn1, sn2, e1, or e2...
find products for the following interactions and identify the
mechanism as sn1, sn2, e1, or e2
A) 2-Iodo-2-phenyl butane + water CH3-CHO-Na+ / ethanol B) 2-Chloro-2-methyl propane + СН3 H3C CH C) 1-Chloro pentane + Nal / acetone + Concentrated H.SO. (No Water added) -----> D) 2-phenylbutan-2-ol ОН 10 pts) E) Write a complete mechanism for Reaction D above Be sure to show the intermediate or transition state.
20. Arrange the following molecules based on their reactivity for SN1 mechanism (the most reactive to...
20. Arrange the following molecules based on their reactivity for SN1 mechanism (the most reactive to the least reactive) [4pts] Br Br CH3Br Br 21. Considering the SN1, SN2, E1, and E2 mechanisms, the energy diagram shown below corresponds to [4Pts] a. only the SN1 mechanism b. only the E1 mechanism c. both the SN2 and E2 mechanisms d. only the SN2 mechanism. e. only the E2 mechanism f. both the SN1 and El mechanisms energy rxn coordinate 22. If...
14. Which of the following transition structures r rresents an SN2 event? ep CH3 8- Br...
14. Which of the following transition structures r rresents an SN2 event? ep CH3 8- Br CH3 NC 8 15. Which combination is most likely to give an E1 (as opposed to an E2) mechanism? (a) excellent leaving group with weak base (b) good leaving group with weak base (c) excellent leaving group with strong base (d) good leaving group with strong base
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2,...
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH₂ Na O=CH₂ Hic Br 2 Draw complete mechanism with arrows for the SNI/E1 mechanism. Check for carbocation rearrangements CH3 + H2O 3. Which is the major product for the following reaction? Y CH + NaOH CH HO HO H₃ CH₂ H₃ HOCH CH₂ H₃ CHE CH₂ CH₂ CH3 CH 4. Name the following including the R/S, E/Z...
The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which...
The rections above involve synthesis or reactions of alcohols
and ethers. Identify the mechanism by which they proceed from among
the mechanisms listed. Use the letters a - g for your answers.
a = Proton transfer b = Lewis acid/base c = Electrophilic
addition
d = E1 Elimination e = E2 Elimination f = SN1 Nucleophilic
substitution g = SN2 Nucleophilic substitution
a. )
b.)
c.)
d.)
We were unable to transcribe this imageH3C Br ње CH HaC Aqueous ethanol...
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary, or tertiary. Labe...
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary, or tertiary. Label the nucleophile as strong or weak. Decide whether an SN2 or an Sy1 reaction occurs. After, show the mechanism and product or products. Indicate stereochemistry where appropriate. a. Reaction of 1-bromopropane and sodium methoxide in methanol CH3 Na CH,Oн Br b. Reaction of 2-bromopropane in ethanol CH3CH2OH Br c. Reaction of (R) 3-chloro-3-methyl heptane in acetic acid Ci Cн CH,COOH но...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
4.2 Give a detailed mechanism and show the products of the following reactions: OF CH3 C (6] a) C-H E2 ООCH H CHз H b) H3CC E1 CH3 Н-О Br 4.3 Label the following reactions as SN1, SN2, E1, or E2. . Br NaNH2 THE a) HN CI КОН Ethanol b) но Ethanol c) NaOH Ethanol P OH 4A samnle with a.concentration of 0 3 a/ml was nlaced in a cell with a lenath of 5 cm 41
What kind of reaction is this? SN1, SN2, E1? Please solve and
include a transition state if there is one. Thank you!
2. Propose a reasonable mechanism, using curved arrow notation, for the following transformation. Include a structure for any transition state. AgNO3 Eto X Br ethanol
5. For each transformation below,
name each mechanism as SN1, SN2, E1, or E2. Label your answers in
correspondence to the reactions a) to d).
5. For each transformation below, name each mechanism as Syl, SN2, E1, or E2. Label your answers in correspondence to the reactions a) to d). [1.3 Marks a) .H H -СН3 Y CH3 + H2O+ b) + ROH + CI- "Como lag for "&- 16.5 for + Br + Br- + Br
find products for the following interactions and identify the
mechanism as sn1, sn2, e1, or e2
A) 2-Iodo-2-phenyl butane + water CH3-CHO-Na+ / ethanol B) 2-Chloro-2-methyl propane + СН3 H3C CH C) 1-Chloro pentane + Nal / acetone + Concentrated H.SO. (No Water added) -----> D) 2-phenylbutan-2-ol ОН 10 pts) E) Write a complete mechanism for Reaction D above Be sure to show the intermediate or transition state.
20. Arrange the following molecules based on their reactivity for SN1 mechanism (the most reactive to the least reactive) [4pts] Br Br CH3Br Br 21. Considering the SN1, SN2, E1, and E2 mechanisms, the energy diagram shown below corresponds to [4Pts] a. only the SN1 mechanism b. only the E1 mechanism c. both the SN2 and E2 mechanisms d. only the SN2 mechanism. e. only the E2 mechanism f. both the SN1 and El mechanisms energy rxn coordinate 22. If...
14. Which of the following transition structures r rresents an SN2 event? ep CH3 8- Br CH3 NC 8 15. Which combination is most likely to give an E1 (as opposed to an E2) mechanism? (a) excellent leaving group with weak base (b) good leaving group with weak base (c) excellent leaving group with strong base (d) good leaving group with strong base
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH₂ Na O=CH₂ Hic Br 2 Draw complete mechanism with arrows for the SNI/E1 mechanism. Check for carbocation rearrangements CH3 + H2O 3. Which is the major product for the following reaction? Y CH + NaOH CH HO HO H₃ CH₂ H₃ HOCH CH₂ H₃ CHE CH₂ CH₂ CH3 CH 4. Name the following including the R/S, E/Z...
The rections above involve synthesis or reactions of alcohols
and ethers. Identify the mechanism by which they proceed from among
the mechanisms listed. Use the letters a - g for your answers.
a = Proton transfer b = Lewis acid/base c = Electrophilic
addition
d = E1 Elimination e = E2 Elimination f = SN1 Nucleophilic
substitution g = SN2 Nucleophilic substitution
a. )
b.)
c.)
d.)
We were unable to transcribe this imageH3C Br ње CH HaC Aqueous ethanol...
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary, or tertiary. Label the nucleophile as strong or weak. Decide whether an SN2 or an Sy1 reaction occurs. After, show the mechanism and product or products. Indicate stereochemistry where appropriate. a. Reaction of 1-bromopropane and sodium methoxide in methanol CH3 Na CH,Oн Br b. Reaction of 2-bromopropane in ethanol CH3CH2OH Br c. Reaction of (R) 3-chloro-3-methyl heptane in acetic acid Ci Cн CH,COOH но...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
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