answer
a) MCl2Br2 is C2V
Plane of symmetry: Plane passing through Cl-M-Cl and Plane passing through Br-M-Br. (two plane of symmetry)
Cn axis: C2 axis passing through angle bisector of Cl-M-Cl and another through angle bisector of Br-M-Br (two axis)
b) XeF4 is D4h
Plane of symmetry:
Plane passing through all five atoms.
plane passing through opposite F atoms
plane passing through angle bisector of F-Xe-F bonds.
Centre of symmetry: Xe is centre of symmetry
Cn axis: C4 axis passing through Xe and perpendicular to all Xe-F bonds
C2 axis passing through angle bisector of F-Xe-F and in plane of all atoms.
C) SF4 is C2V
Plane of symmetry: passing through F-S-F bond (Fs are not adjecent)
Symmetry axis: Passing through sulfur (S) and lying along lone par of S
D) it is D3h
Plane: Passing through Fe and three CO groups
another Passing through each F-CO bond and perpendicular to the other plane
Axis: one passing through Cl-Fe-Cl bond and other three axis passing through each F-CO bond.
E) it is C2V
Plane : Passing through Cl-Fe-Cl; anther passing through Three CO and Fe
Axis: passing through angle bisector of Cl-Fe-Cl
1. Assign the point group to each of the following molecules below by identifying all of...
All parts please!!
1. Determine the point group for each of the following molecules. If the molecule has a C,axis, draw and label the axis on the molecular structure. Similarly, draw all mirror planes that are present in the molecule. Feel free to draw multiple copies of a molecule to show the symmetry elements more clearly. NH3 b) Br NH / 111111 -Cr F- Cr. OH OH2 ço e) Çih f) CO IZ ОН CO g) F.
1. (6 points) Assign the following molecules to their much work as needed. appropriate point group. Show as Point Croup PFs HCl O-C-C-C-O (linear) TeCl 1,1-dichlorocyclobutane --al CI
Symmetry point groups
Question 8 time 12 minutes] Identify the symmetry point group of the following molecules and specify if they can have a permanent electric dipole moment (a) ortho-phenanthroline (C12N2H&) (b) BrFs F Br F F FI Ni (d) PFs (c) mer-OsCl3(CO)3 CI Cl F-p.F F Co OC L C L 8 8
1. Assign the point group structures of the following main group molecules: (i) NF3, (ii) PFs, (iii) N-O* and (iv) NOj
Determine the molecular point group for each of the following ions or molecules: 1) ClF3, 2) IF5, 3) I3-, 4)XeO4, 5)XeOF4, 6)XeF4, 6) SF2
Find and list all symmetry elements present in the molecules
below, and assign a point group to each. Indicate the principal
axis (z axis) on each drawing. Note: Different resonance structures
involving p-bonds do not destroy symmetry elements. You can assume
the highest level of symmetry depicted in the drawings.
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please answer highlighted questions
Problems 85 3.9 Which of the following species contain a C4 axis and 3.27 Six of the nine vibrational degrees of freedom of SiF are IR active. Why are IR absorptions observed only at 389 and 1030 cm for this compound? 3.10 How many mirror planes do each of the following molecules contain: (a) SF" (b) H2S; (c) SF" (d) 3.28 AICİ6 belongs to the D2hpoint group: SOF: () SO () SO,? 3.11 (a) What structure...
Assign an EIZ designation to each of the molecules below. NH₂ H₃C ci IO B O A = Z, B = 2 A =E, BEZ A = Z, B = E A = E, B = E
Assign R, S configurations to each indicated chirality center in the molecules below. A. OH B. COOH НО. ---H co CHANH CH; HAN HO H norepinephrine alaine 0 D. C. H E. HOC OH moje H н. CH3 H2C H НО CO H CH2 tartaric acid dihydrocaryone
11) Assign the point group for the following molecules and indicate whether you expect the molecule to be polar or not. Be sure to show your work. (20 points) (a) HOF (b) CIFs (c) HCN (d) trans-PCLF
11) Assign the point group for the following molecules and indicate whether you expect the molecule to be polar or not. Be sure to show your work. (20 points) (a) HOF (b) CIFs (c) HCN (d) trans-PCLF