Homework Answers
e) A thioester is more
reactive than an ester, for example,
because a thiolate (RS-) is a weaker base and better leaving group
than an alkoxide (RO-).
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d. CIRCLE the ONE diene that would react with HCl the fastest, assuming sterics are not...
For each of the following pairs of organic molecules, circle the one that would react with...
For each of the following pairs of organic molecules, circle the one that would react with a given nucleophile at a faster rate in the Sw1 reaction, and briefly explain your choice. нссн, vs. H₂C CH₂ CH Hoc tots vs. Ho C^ots 6. Each of the following carbocations can undergo a rearrangement to give a more stable carbocation. In each case, draw the structure of the rearranged carbocation, and show the mechanism of the 1,2 hydride shift or 1,2-alkyl shift...
of the following acids, which one would be least likely to donate urs proton due to...
of the following acids, which one would be least likely to
donate urs proton due to the unstable conjugate base?
1. which is the donatable hydrogen for each of the given
structures?
2. what is the hybridization of the atom to which the
donatable hydrogen is attached?
3. do any of the atoms identified in question 2 have a
positive charge? if so explain why this is not a good thing and
makes the hydrogen more donatable as opposed to...
commond in PRACTICE SHEET NH2 04/04/2018 OH a. Which H is the most acidic ? (circle...
commond in PRACTICE SHEET NH2 04/04/2018 OH a. Which H is the most acidic ? (circle it) b. What product forms when the compound is treated with HCI ? (Draw it above) c. How many sp3 hybridized carbons does this molecule have? d. How many H's are on the attached to the N? 10 a. Indicate the strongest IMF available to each of the compounds below. Oligo H A B b. Which compound would you expect to have a greater...
kar 10-1 12. What sort of titration is the adjacent titration curve? Circle the correct response...
kar 10-1 12. What sort of titration is the adjacent titration curve? Circle the correct response and explain your choice. SA/SB, SA/WB, SB/WA pH 13. Where is the effective buffer region in this titration curve? Circle this region on the graph. 4) Estimate the Ks of the weak base being titrated in this curve. . 10 20 30 13) Why does the pink color of phenolphthalein fade away? Was the equivalence point for the SA/SB system really where you expected...
Titration: Acids and Bases 2. How can you determine which acid is diprotic? 3. using the...
Titration: Acids and Bases
2. How can you determine which acid is diprotic?
3. using the answers to questions one and two, which acid is
diprotic?
4. Which base has more hydroxide ions per molecule?
Acid Volume Base Base Initial Volume (mL) Base Final Volume (mL) Volume of Base Used (mL) Acid: Base Ratio Acid 1 20 mL Base 1 50 mL 34.5 15.5 4:3 Acid 2 20 mL Base 1 Acid 1 20 mL Base 2 Acid 2 20...
please help 4. For each pair of structures below circle the most relatively stable one. Show...
please help
4. For each pair of structures below circle the most relatively stable one. Show work by drawing relevant chair structures and/or Newman projections as needed) to clearly illustrate why. It is best practice here that only the most stable conformations for each compound are being compared in each set. For clarity. provide a few words that explain your analysis when comparing the illustrations. (12pts total for this problem) (a) ♡ va ♡ 5. (a) (3pts) Look up trans-decalin...
A buffer solution is able to maintain a constant pH when small amounts of acid or...
A buffer solution is able to maintain a constant pH when small amounts of acid or base are added to the buffer. Consider what happens when 1 mL of a 5 M solution is added or 0.005 mol of HCl are added to a 100.0 mL solution acetic acid buffer that contains 0.0100 mol of Acetic acid, HC,H,O,, and 0.0100 mol of sodium acetate, NaC,H,O,. The initial concentration of both the acid and the base are 0.0100 mol/ 0.1000 L...
Exercise 2 Separation of a Mixture Based on Acid-Base Properties One purpose of this exercise is...
Exercise 2 Separation of a Mixture Based on Acid-Base Properties One purpose of this exercise is to learn how to use a separatory funnel to extract a single component away from other compounds in solution. To do so, we will apply the principles of solubility and acid-base behavior you’re seeing in class. One of the compounds is neutral in the acid-base sense. It has no ability to either donate or accept a proton from an aqueous solution, and will remain...
1. In both the sodium iodide test and the silver nitrate test, why does 2-bromobutane react faster...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification Reactions Q: Calculate the expected mass of both methyl salicylate and aspirin assuming 100% yield. EXPERIMENT7 PREPARATION OF PHARMACEUTICALS...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification
Reactions
Q: Calculate the expected mass of both methyl salicylate and
aspirin assuming 100% yield.
EXPERIMENT7 PREPARATION OF PHARMACEUTICALS Fischer Esterification Reactions Almost 2500 years ago, physicians such as Hippocrates recommended that patients chew on the bark of the willow to alleviate pain. The active ingredient in willow bark was found to be salicin, a compound made of a molecule of salicyl alcohol bonded to a p-D-glucose molecule. In the stomach, the bond between...
For each of the following pairs of organic molecules, circle the one that would react with a given nucleophile at a faster rate in the Sw1 reaction, and briefly explain your choice. нссн, vs. H₂C CH₂ CH Hoc tots vs. Ho C^ots 6. Each of the following carbocations can undergo a rearrangement to give a more stable carbocation. In each case, draw the structure of the rearranged carbocation, and show the mechanism of the 1,2 hydride shift or 1,2-alkyl shift...
of the following acids, which one would be least likely to
donate urs proton due to the unstable conjugate base?
1. which is the donatable hydrogen for each of the given
structures?
2. what is the hybridization of the atom to which the
donatable hydrogen is attached?
3. do any of the atoms identified in question 2 have a
positive charge? if so explain why this is not a good thing and
makes the hydrogen more donatable as opposed to...
commond in PRACTICE SHEET NH2 04/04/2018 OH a. Which H is the most acidic ? (circle it) b. What product forms when the compound is treated with HCI ? (Draw it above) c. How many sp3 hybridized carbons does this molecule have? d. How many H's are on the attached to the N? 10 a. Indicate the strongest IMF available to each of the compounds below. Oligo H A B b. Which compound would you expect to have a greater...
kar 10-1 12. What sort of titration is the adjacent titration curve? Circle the correct response and explain your choice. SA/SB, SA/WB, SB/WA pH 13. Where is the effective buffer region in this titration curve? Circle this region on the graph. 4) Estimate the Ks of the weak base being titrated in this curve. . 10 20 30 13) Why does the pink color of phenolphthalein fade away? Was the equivalence point for the SA/SB system really where you expected...
Titration: Acids and Bases
2. How can you determine which acid is diprotic?
3. using the answers to questions one and two, which acid is
diprotic?
4. Which base has more hydroxide ions per molecule?
Acid Volume Base Base Initial Volume (mL) Base Final Volume (mL) Volume of Base Used (mL) Acid: Base Ratio Acid 1 20 mL Base 1 50 mL 34.5 15.5 4:3 Acid 2 20 mL Base 1 Acid 1 20 mL Base 2 Acid 2 20...
please help
4. For each pair of structures below circle the most relatively stable one. Show work by drawing relevant chair structures and/or Newman projections as needed) to clearly illustrate why. It is best practice here that only the most stable conformations for each compound are being compared in each set. For clarity. provide a few words that explain your analysis when comparing the illustrations. (12pts total for this problem) (a) ♡ va ♡ 5. (a) (3pts) Look up trans-decalin...
A buffer solution is able to maintain a constant pH when small amounts of acid or base are added to the buffer. Consider what happens when 1 mL of a 5 M solution is added or 0.005 mol of HCl are added to a 100.0 mL solution acetic acid buffer that contains 0.0100 mol of Acetic acid, HC,H,O,, and 0.0100 mol of sodium acetate, NaC,H,O,. The initial concentration of both the acid and the base are 0.0100 mol/ 0.1000 L...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification
Reactions
Q: Calculate the expected mass of both methyl salicylate and
aspirin assuming 100% yield.
EXPERIMENT7 PREPARATION OF PHARMACEUTICALS Fischer Esterification Reactions Almost 2500 years ago, physicians such as Hippocrates recommended that patients chew on the bark of the willow to alleviate pain. The active ingredient in willow bark was found to be salicin, a compound made of a molecule of salicyl alcohol bonded to a p-D-glucose molecule. In the stomach, the bond between...
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