One mole of ideal diatmic gas with Cv,m= 2.5 R at 27 C and .100 MPA is compressed adiabatically and reversibly to a final pressure of 1.00 MPa. Calculate the final temp, q,w, Delta U, and Delta H, and Delta S for the process.
One mole of ideal diatmic gas with Cv,m= 2.5 R at 27 C and .100 MPA...
One mole of ideal gas initially at 27 degree C is compressed adiabatically from 6 dm^3 to 3 dm^3 against constant external pressure of 15 atm. Calculate Delta E, Delta H, Q, and W for this process.
One mole of an Ideal Gas, for which Cv,m = 3/2R, initially at 20.0 C and 1.00 x106 Pa undergoes a two-stage transformation: Stage 1: The gas is expanded isothermally and reversibly until the volume doubles. Stage 2: Beginning at the end of the first stage, the temperature is raised to 80.0 C at constant volume. For each stage, calculate the final pressure, heat(q), work(w), change in internal energy (ΔU), and enthalpy (ΔH). Calculate the total q, w, ΔU, and...
2. One mole of an ideal gas, CP - (7/2)R and CV - (5/2)R, is compressed adiabatically in a piston/cylinder device from 2 bar and 25°C to 7 bar. The process is irreversible and requires 35% more work than a reversible, adiabatic compression from the same initial state to the same final pressure. What is the entropy change of the gas?
Suppose that we allow 3.50 mol of an ideal gas with Cv=5R/2 to expand isothermally and reversibly from 100 atm, 10 L to 10.0 atm and then the gas is allowed to expand adiabatically and reversibly to a final pressure of 1.00 atm. Calculate q, w, ΔU and ΔH for each step and the total values for the two steps. Suppose now that the processes are carried out irreversibly with pressure dropping discontinuously from 100 atm to 10.0 atm in...
W 2. One mole of an ideal gas initially at 37°C and 2 bar pressure is heated and allowed to expand reversibly at constant pressure until the final temperature is 287°C. For this gas, Cum = 2.5R, constant over the temperature range. a. Derive related thermodynamic equations (q, w, U, and H) for an ideal gas, when the temperature is changed (5 points). b. Calculate w (work done on the ideal gas), 9 (the amount of heat absorbed by the...
Consider one mole of an ideal gas at 25.0degree C. Calculate q, w, delta E, delta H, delta S, and delta G for the expansion of this gas isothermally and irreversibly from 2.45 times 10^-2 atm to 2.45 times 10^-3 atm in one step. Calculate q, w, delta E, delta H, delta S, and delta G for the same change of pressure as in part (a) but performed isothermally and reversibly. Calculate q, w, delta E, delta H, delta S,...
4. One mole of monoatomic ideal gas, initially at 27 oC and 1 bar, is heated and allowed to expand reversibly against constant pressure of 1 bar until the final temperature is 127 °C. 4.1 What are the initial (Vi) and final (V2) volumes of the gas? 4.2 Calculate the work (w) that the gas does during this expansion. 4.3 Calculate the internal energy change (AU) of this expansion process 4.4 Calculate the enthalpy change (AH) of this expansion process.
Two moles of oxygen gas, which can be regarded as ideal with ?? = 29.4 J/(K ∙ mol) (independent of temperature), are initially at 298 K in a volume of 12.5 dm3 . The gas is expanded reversibly to 353 K at constant pressure. Calculate the final volume and q, w, ∆U, ∆H, ∆S. (25 points) 4. Suppose that the gas in question 3 is reversibly compressed to half its volume at constant temperature (298 K). Calculate the final pressure...
Two mole of ideal gas, is compressed adiabatically in a piston/cylinder device from 2 bar and 25oC to 7 bar. The process is irreversible and requires 25% more work than a reversible, adiabatic compression from the same initial state to the same final pressure. What is the entropy change of the gas? Assume Cv=(5/2)R in this calculation.
I. (30 pts.) One mole of an ideal gas with constant heat capacities and ? 5/3 is compressed adiabatically in a piston-cylinder device from T1-300 K, pi = 1 bar to p2 = 10 bar at a constant external pressure Pext"- P2 -10 bar. Calculate the final temperature, T2, and W, Q. AU, AH for this process. 2. (20 pts.) Repeat problem 1 for an adiabatic and reversible compression. 3. (20 pts.) A rigid, insulated tank is divided into two...