In the experiment on the synthesis of mercury
tetrathiocyanatocobaltate (II):
1. draw the dn- orbital spliting diagram
2. calculate the spin-only magnetic moment for the complex after
determining the number of unpaired electrons for the complex.
3. Draw the Lewis structure for NCS- . and discuss with examples
the different modes of coordination of NCS-. Do these ligands have
dirrerent steric features?
In the experiment on the synthesis of mercury tetrathiocyanatocobaltate (II): 1. draw the dn- orbital spliting...
Draw the Lewis structure for NCS-. Discuss with examples the different modes of coordination of NCS-. Do these ligands have different steric features
1. a) draw orbital diagrams for the high and low spin configurations for Tris(ethylenediamine)cobalt(III) chloride dihydrate, and Hexaammineruthenium(III) chloride b) Calculate the effective magnetic moment (μeff) for each spin configuration using the number of unpaired electrons
1.- Define what are complex ions 2.- Using NiCl as a reactant look in a book or in the web for a reaction to form a complex ion, indicate which is the Lewis acid and which is the Lewis base. An example of your answer is this: Ag (aq) + 2NH, (aq) - Ag(NH),(aq) Lewis acid Lewis base 3.- Using the rules of nomenclature name the complex you have proposed in question 2 4.- Indicate the coordination number and geometry...
1- Draw the molecular orbital diagram of transition metal ion in high-spin Mn(H2O)4(OH)2 complex, also determine the number of unpaired electron. 2- Draw the molecular orbital diagram of transition metal ion in low-spin [Cr(en)2(NH3)2].Cl2 complex, also determine the number of unpaired electron. 3- Draw the molecular orbital diagram of transition metal ion in high-spin K.[Mn(CO)3(OH)3] complex, also determine the number of unpaired electron.
5) Draw d orbital splitting of an octahedral complex. Calculate CFSE for a high spin Fe(II) complex in an octahedral geometry. Calculate spin only magnetic moment for the complex too. 6
Could you show how to do step by step,please?
2. Consider (Cr((Cl).]": (donor/acceptor) --Cl is a strong/weak)-field ligand because of interactions with the metal ion --In this complex, Cr-* is a d ion Therefore, the number of unpaired electrons in Cr((Cl).].is Draw an orbital diagram showing the distribution of electrons: Calculate the spin-only magnetic moment of Cr((Cl).]" (in His units): Calculate (i) the Ligand-Field Stabilization Energy (as a function of Ao), (ii) the Coulombic energy (as a function of II.)...
Could you show how to do step by step,please?
3. Consider (Cr(CN).]*: (donor/acceptor) --CN is a _ (strong/weak)-field ligand because of interactions with the metal ion --In this complex, Cr-* is a d ion Therefore, the number of unpaired electrons in (Cr(CN).)" is Draw an orbital diagram showing the distribution of electrons: Calculate the spin-only magnetic moment of [Cr((CN).]" (in his units): Calculate (i) the Ligand-Field Stabilization Energy (as a function of Ac), (ii) the Coulombic energy (as a function...
5. The [NI(CN)412- ion has a square-planer geometry, whereas the INca diagrams (with d-orbital labels) for these twe complexes and determine if the compound is paramognetic or diamognet ion is tetrahedral. Drow the crystal field splitting 6. The absorption maximum for the complex ion (Co( Hale ccurs at 410 m. Predict the coler of this complex.Explain your reasoning. the Lewis structure of each and state whether the following are monodentate or bide ntate ligands a. c2042 (oxalate ion, ox) b,sar...
4. In Part 1 of this experiment, CoCl, 6H,O reacts with ammonium chloride, ammonium hydroxide, and hydrogen peroxide to produce [Co(NH3)Cl3 and water. a) Write the balanced equation for this reaction. b) What is the purpose of adding the charcoal? c) To the test tube containing CoCl2 6H20, NH Cl, and NH OH, 3 mL of 10% H2O2 is added. Why must the H2O, be added slowly, in 1 mL portions? What is the purpose of adding the H2O2? Go...
The first two pages are the background of the lab. I would
appreciate any help with the pre-lab questions, even if you cannot
answer them all, so I could continue to the post-lab on my own.
Experiment Thermodynamics: Entropy vs. Enthalpy OH, Background The formation of a Lewis Acid-Base complex occurs when you have a lone pair of electrons being donated to an electropositive ion or atom. Common examples are the Lewis Acid-Base complexes that most metal ions form in...