BDE?s for some H - X bonds are given below (from the BDE Table). Rank the...
C-H bond BDE (kJ/mol) CH3-H 439 C2H:-H 422 (CH3)2 CH-H 414 (CH3)3 C-H 405 Table of Bond Dissociation Enthalpies C-X bond BDE (kJ/mol) X2 and HX bonds BDE (kJ/mol) CH3-C1 351 CI 247 CH-C1 355 НСІ 431 (CH3)2CH-C 355 (CH3)3C-CI 355 CH3 CH3 CH3CHCHCH3 CH3CHCH2CH3 + a Cl2 CI HCI Using the table of bond dissociation energies in the first part of this question: Calculate AH for this reaction. kJ/mol Overall, this reaction is CH3 CH3CHCHCH3 CH3 CH3CHCH2CH3 + b...
Mechanisms Question 1 (22 marks) (a) Consider the radical chain reactions of the alkane shown below with Br, in the presence of light. H3C HH H C-CCHS CH3 Br2 hv 2 Different mono- bromo products 25 °C + (you will need to look up the bond dissociation energy (BDE) for the types of bonds formed and broken in this reactions) (i) Give the structures of the products from the reaction and using standard arrow conventions show the series of mechanistic...
6. Rank these carbon radicals from most stable to least stable: H C H Н—с—н (X) (W) н C H (z) (Y) 4. The equilibrium constant (Kea) for the conversion of A to B is 12.4. Which substance, A or B, is present in the larger amount at equilibrium? Next, solve for AG and decide on the spontaneity of the conversion. В A 8. What make this a chiral molecule? O H2N CH C OH CH2 HN-
rank the molecules in the table from weakest to strongest intermolecular forces and briefly justify the ranking. temperature 310 20 time (s) 40 Fig. 10.1. Sample data for an evaporative cooling process. Before You Come to Lab Based on what you know about the relationship between the structure of a molecule and the strength of its intermolecular forces, rank the molecules in the table below in order from the weakest to the strongest intermolecular forces and briefly justify your ranking...
I attached the table that was given. assignment- 80% References pt pr CH3 1 pt CH3CCH2CH3 CH3 CH3CHCH2CH3 + Cl2 + HCI Assuming that the reaction proceeds via a radical chain reaction mechanism, calculate All for the first propagation step of this reaction. J/mol This first step is In the box below, draw the structure of the species most closely resembling the transition state (ie, if the transition state resembles the products, draw the radical) . Include all valence lone...
= O SIMPLE REACTIONS Assigning oxidation numbers Some chemical reactants are listed in the table below. Complete the table by filling in the oxidation state of the highlighted atom. species oxidation state of highlighted atom SiO2(0) CuO(s) O Cu²+ (09) H,00 x 5
6. Circle the aromatic compounds from the list below. (5 points) 7. Rank the compounds below in order of reactivity to Electrophilic Aromatic Substitution. Rank the most reactive compound as compound 1 and the least reactive compound as compound 5. (5 points) 6. Circle the aromatic compounds from the list below. (5 points) OH :O: H 7. Rank the compounds below in order of reactivity to Electrophilic Aromatic Substitution. Rank the most reactive compound as compound 1 and the least...
2) Rank the nucleophiles given below based on high, mediocre, and low nucleophilicity and reason why based on their structures. HO-CH3, H2N-CH3, KO-CH3, KO-C(CH3)3 Introduction Alkyl halides can be prepared from alcohols by reactions with hydrogen halides (HCI, HBr, or HI) via nucleophilic substitution. In this type of reaction, the nucleophile displaces a leaving group from a carbon atom of an organic substrate (here the alcohol once protonated). Both electrons of the new bond to the carbon are provided by...
PLEASE EXPLAIN THANK YOU 2. Rank the following acids (underlined H) from most acidic-to-least acidic. [Note: 1 > 2 > 3 indicates that 1 is the most acidic and 3 is the least acidic.] a)1 > 2 > 3 b)1 > 3 > 2 c)2 > 1 > 3 d)2 > 3 > 1 e)3 > 1 > 2 f)3 > 2 > 1
urgent pls answer Use the References to access important values if Rank the bonds below in order of relative polarity. Use data from the electronegativity table in the OWL Table Reference, not data from your text. Click the References button and then Clear All C Li Most polar C-Zn Intermediate polarity C-Mg Least polar