26. Which is the more stable conformation of cyclohexane (boat or chair)? Why?
The chair cyclohexane is the more stable conformation of cyclohexane. Cyclohexane adopts a spatial arrangement in chair form to avoid eclipsing between its 12 hydrogens, while the bond angles remain close to 109°. If we look along a C-C bond we can see an alternating arrangement of all substituents. This all reduces the potential energy of the conformation and makes it the most stable.
The boat shape is less stable because of the eclipsing of the 8 hydrogens at the bottom of the boat and the repulsion between the hydrogens projecting into the boat (transannular strain).
Remove one hydrogen atom from C_1 the hexane model, and one H atom plus its bond...
Help Organic Chem part 4 Cyclohexane Conformations Put your model of cis-1,3-dichlorocyclohexane into a chair conformation. Sometimes the easiest way to do this is by adjusting it to make the axial bonds alternate up and down. Now convert it to the other chair structure, asking the instructor for help if needed. Is the second conformation still cis or is it trans? Are the two conformations the same or are they different? Draw chair structures of both conformations making sure to...
Make3 a model of cyclopentane. Does this molecule seem to have any ring strain in the sense that the three and four-membred rings do? The molecule is not completely strin-free because there is some eclipsing. Identify the eclipsed atoms or groups when the molecule is planar. In fact the molecule is not planar, but is puckered in either of two ways; (i) One C-atom is abover or below the plane defined by the other four coplanar C-atoms defining an envelope...
Using the templates provided, draw the planar representation (use wedges and dashes!) and both chair conformations of the models of 1,3-dichlorocyclohexane Is one chair conformer lower in energy? If so, circle the appropriate conformation above Are the two chlorine atoms cis- or trans- to each other? Can both chlorine atoms be axial in any chair conformation? Would a solution of model A rotate plane polarized light? Why or why not? Is model A a meso compound? Model B? Model B?...
Laboratory Work 1. Draw the skeletal formulas and make models of the three constitutional isomers of C5H12. 2. Draw Kekule structures and make models of all the constitutional isomers of C2H4Cl2. 3. Draw Kekule formulas and make models of ethane, ethene, and ethyne. How does the geometry of their structures differ? Which compound contains sp hybridized carbons? 4. Draw and label the Newman projection and make the model of the anti-conformation of 1,2-dibromoethane. Rotate around the carbon-carbon bond...