Question

Cyclohexane organic Laboratory Manual 18. Remove one hydrogen atom from C1 the hexane model, and one H atom plus its bond of to Co to make from cs. Bend the carbon chain around and join c cyclohexane. Mentally designate one carbon as c 19. Place the model in the chair conformation by tipping c1 up and c. 20. Check the conformation with the instructor. 21. Identify the axial and equatorial hydrogens and describe their FC Ca orientation relative to the plane of the ring. 22. Look down each successive c-c bond (as in step 16) and describe the conformation of the hydrogens eclipsed, staggered, skewed, etc) for DC each bond by filling in the table 23. Put the cyclohexane model in the boat conformation, by tipping both C and C4 up. 24. Identify the axial, equatorial and flagpole hydrogens, describe their orientations relative to the boat. CI-C 25. Repeat step 21 and give the conformation of the hydrogens around C each bond 26. Which is the more stable conformation of cyclohexane (boat or chair)? Substituted cyclohexanes 27. Put the model back into the chair conformation and replace two hydrogens with chlorines to make trans-1, xane with the chlorines. Are the chlorines axial or equatorial to the plane of the ring? 28. Now, switch the model to the other chair conformation. Describe the orientation of the c (axial or equatorial; cis or trans). 29. Now switch the chlorines to make cis-1, 2 dichlorocyclohexane and describe the orientation of the ch and c2 chlorines (axial or equatorial for each) the 30. Now switch the model to the other chair conformation and describe orientation of the chlorines at ct and c2 individually (axial or equatorial for each). 31. Summarize the effects of conformational shifts (alternate chairs) on the axial equatorial and cis-trans orientation of the chlorines. Conformation Conformatio
0 0
Add a comment Improve this question Transcribed image text
Answer #1

26. Which is the more stable conformation of cyclohexane (boat or chair)? Why?

Cuclohexane Chair Boat vansannuiar straun equartoial H axial H

The chair cyclohexane is the more stable conformation of cyclohexane. Cyclohexane adopts a spatial arrangement in chair form to avoid eclipsing between its 12 hydrogens, while the bond angles remain close to 109°. If we look along a C-C bond we can see an alternating arrangement of all substituents. This all reduces the potential energy of the conformation and makes it the most stable.

The boat shape is less stable because of the eclipsing of the 8 hydrogens at the bottom of the boat and the repulsion between the hydrogens projecting into the boat (transannular strain).

Add a comment
Know the answer?
Add Answer to:
Remove one hydrogen atom from C_1 the hexane model, and one H atom plus its bond...
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for? Ask your own homework help question. Our experts will answer your question WITHIN MINUTES for Free.
Similar Homework Help Questions
  • Help Organic Chem part 4 Cyclohexane Conformations Put your model of cis-1,3-dichlorocyclohexane into a chair conformation....

    Help Organic Chem part 4 Cyclohexane Conformations Put your model of cis-1,3-dichlorocyclohexane into a chair conformation. Sometimes the easiest way to do this is by adjusting it to make the axial bonds alternate up and down. Now convert it to the other chair structure, asking the instructor for help if needed. Is the second conformation still cis or is it trans? Are the two conformations the same or are they different? Draw chair structures of both conformations making sure to...

  • Make3 a model of cyclopentane. Does this molecule seem to have any ring strain in the...

    Make3 a model of cyclopentane. Does this molecule seem to have any ring strain in the sense that the three and four-membred rings do? The molecule is not completely strin-free because there is some eclipsing. Identify the eclipsed atoms or groups when the molecule is planar. In fact the molecule is not planar, but is puckered in either of two ways; (i) One C-atom is abover or below the plane defined by the other four coplanar C-atoms defining an envelope...

  • Using the templates provided, draw the planar representation (use wedges and dashes!) and both chair conformations...

    Using the templates provided, draw the planar representation (use wedges and dashes!) and both chair conformations of the models of 1,3-dichlorocyclohexane Is one chair conformer lower in energy? If so, circle the appropriate conformation above Are the two chlorine atoms cis- or trans- to each other? Can both chlorine atoms be axial in any chair conformation? Would a solution of model A rotate plane polarized light? Why or why not? Is model A a meso compound? Model B? Model B?...

  • Laboratory Work 1.   Draw the skeletal formulas and make models of the three constitutional isomers of...

    Laboratory Work 1.   Draw the skeletal formulas and make models of the three constitutional isomers of C5H12. 2.   Draw Kekule structures and make models of all the constitutional isomers of C2H4Cl2. 3.   Draw Kekule formulas and make models of ethane, ethene, and ethyne. How does the geometry of their structures differ? Which compound contains sp hybridized carbons?                                                                                                                       4.   Draw and label the Newman projection and make the model of the anti-conformation of 1,2-dibromoethane. Rotate around the carbon-carbon bond...

ADVERTISEMENT
Free Homework Help App
Download From Google Play
Scan Your Homework
to Get Instant Free Answers
Need Online Homework Help?
Ask a Question
Get Answers For Free
Most questions answered within 3 hours.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT