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In both examples below the reactants shown are combined to bring about a nucleophilic substitution (SN1,...
In both examples below the reactants shown are combined to bring about a nucleophilic substitution (Spl,...
In both examples below the reactants shown are combined to bring about a nucleophilic substitution (Spl, S2) and/or elimination (E1, 12) reaction What is the major reaction that takes place in each case? CHCHCH,CH,Br NaOCH CH3OH SN2 E2 mixture of SN1 and E1 CH3 CH3 Сн, сансн, NaOCHE CH3OH S In both examples below the reactants shown are combined to bring about a nucleophilic substitution ( S What is the major reaction that takes place in each case? 2) and/or...
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. CH3 +...
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. CH3 + H2O Otos i. H30+ e. "OTos f. OH g. H2O h. "OS j. CH3OH k. none Which letter designates the electrophilic carbon at which substitution occurs? (If no reaction occurs enter the letter corresponding to "none.") Which letter corresponds to the leaving group? 1:1 1 .deicotill 1:1.00 Which letter corresponds to the leaving group? O Which letter designates the nucleophile?
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. Which letter...
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. Which letter designates the electrophilic carbon at which substitution occurs? (If no reaction occurs enter the letter corresponding to "none.") Which letter corresponds to the leaving group? Which letter designates the nucleophile?
[Review Topics) (References) Give an IUPAC name for the compound below. Accepted names for branched alkyl...
[Review Topics) (References) Give an IUPAC name for the compound below. Accepted names for branched alkyl groups are isopropyl, isobutyl, sec-butyl, and tert-butyl. CH2CH3 CH3CH2CH2CCH2CH3 Submit Answer Retry Entire Group 9 more group attempts remaining The two reactants shown below are combined to bring about a nucleophilic substitution reaction. Br NaOCCH, . CH3CH2CHCH 1. none h. HBr 1.H20 e. "CCH3 f. Br j. Nat 9. HOCCH3 k. "OCCH3 Which letter designates the electrophilic carbon at which substitution occurs? (If no...
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. F +...
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. F + Nal IT g. HI h. Nat i. none f. HF Which letter designates the electrophilic carbon at which substitution occurs? (If no reaction occurs enter the letter corresponding to "none.") Which letter corresponds to the leaving group? Which letter designates the nucleophile? Submit Answer Try Another Version 1 item attempt remaining
3. Shown below are a series of reactions. Predict the major product for each of them....
3. Shown below are a series of reactions. Predict the major product for each of them. Remember, you will need to first decide whether the reaction occurs by an SN2, SN1, E2, or E1 before you can determine what the product will be. Label each as SN2, SN1, E2, or E1. Hint: First decide whether S2/E2 or S1/E1 is favored, and then decide whether the reaction pathway goes by a substitution or elimination reaction. SN2 / SN1 E2/E1 Na DMSO,rt...
Br DMSO H20 N-Br OH N-H dilute H2SO4 OH h sN1 Nucleophilic substitution. a Proton transfer...
Br DMSO H20 N-Br OH N-H dilute H2SO4 OH h sN1 Nucleophilic substitution. a Proton transfer e J Electrophilic addition b Lewis acid/base i SN2 Nucleophilic substitution f*E1 Elimination c -Radical chain substitution j Electrophilic aromatic substitution g FE2 Elimination d Radical chain addition Identify the mechanism by which each of the actions above proceeds from a the mechanisms listed. Use the letters a j for your answers.
Short Answer Section (43 pts) – showing work helps! Substitution vs. Elimination (12 pts). Predict all...
Short Answer Section (43 pts) – showing work helps! Substitution
vs. Elimination (12 pts). Predict all major product(s) of each of
the following reactions and indicate the predominant mechanistic
pathways (Sn1, Sn2, E1, E2). Remember to consider rearrangements.
Mechanism #1 (10 pts). Draw a stepwise mechanism to account for the
following transformation. Br mechanism(s)? NaOH Cl mechanism(s)?
NaOEt OTs for this reaction, circle the major product mechanism(s)?
O K Cl for this reaction, circle the major product mechanism(s)?
NaOCH3 H2O...
3. Determine the mechanism of nucleophilic substitution (SNI or SN2) for each reaction and draw the products. Be aw...
3. Determine the mechanism of nucleophilic substitution (SNI or SN2) for each reaction and draw the products. Be aware of stereochemistry. 8 + CN - dletone m et och cun, DE Br + OCH₂ CH₂ DME 4. Draw all constitutional isomers formed during each elimination reaction after determining whether it is E1 or E2. habel it as El or E2. госна. a y "ocha, B b. Tă CH₃OH Br -OH
Alkyl Halides and their Reactions: Nucleophilic Substitution and Elimination l. Predict the major organic product for...
Alkyl Halides and their Reactions: Nucleophilic Substitution and Elimination l. Predict the major organic product for each of the following. (1 major structure is all that needed in each case). (3 points each) Br CH3ONa CH3CH2ONa (for "d", show elimination product only, there will also be some substitution) NaOH e, optically active (for "e", show substitution product or products only. If both enantiomers form, draw both) Is the product solution for reaction "e" above racemic or optically active? (1 point...
In both examples below the reactants shown are combined to bring about a nucleophilic substitution (Spl, S2) and/or elimination (E1, 12) reaction What is the major reaction that takes place in each case? CHCHCH,CH,Br NaOCH CH3OH SN2 E2 mixture of SN1 and E1 CH3 CH3 Сн, сансн, NaOCHE CH3OH S In both examples below the reactants shown are combined to bring about a nucleophilic substitution ( S What is the major reaction that takes place in each case? 2) and/or...
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. CH3 + H2O Otos i. H30+ e. "OTos f. OH g. H2O h. "OS j. CH3OH k. none Which letter designates the electrophilic carbon at which substitution occurs? (If no reaction occurs enter the letter corresponding to "none.") Which letter corresponds to the leaving group? 1:1 1 .deicotill 1:1.00 Which letter corresponds to the leaving group? O Which letter designates the nucleophile?
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. Which letter designates the electrophilic carbon at which substitution occurs? (If no reaction occurs enter the letter corresponding to "none.") Which letter corresponds to the leaving group? Which letter designates the nucleophile?
[Review Topics) (References) Give an IUPAC name for the compound below. Accepted names for branched alkyl groups are isopropyl, isobutyl, sec-butyl, and tert-butyl. CH2CH3 CH3CH2CH2CCH2CH3 Submit Answer Retry Entire Group 9 more group attempts remaining The two reactants shown below are combined to bring about a nucleophilic substitution reaction. Br NaOCCH, . CH3CH2CHCH 1. none h. HBr 1.H20 e. "CCH3 f. Br j. Nat 9. HOCCH3 k. "OCCH3 Which letter designates the electrophilic carbon at which substitution occurs? (If no...
The two reactants shown below are combined to bring about a nucleophilic substitution reaction. F + Nal IT g. HI h. Nat i. none f. HF Which letter designates the electrophilic carbon at which substitution occurs? (If no reaction occurs enter the letter corresponding to "none.") Which letter corresponds to the leaving group? Which letter designates the nucleophile? Submit Answer Try Another Version 1 item attempt remaining
3. Shown below are a series of reactions. Predict the major product for each of them. Remember, you will need to first decide whether the reaction occurs by an SN2, SN1, E2, or E1 before you can determine what the product will be. Label each as SN2, SN1, E2, or E1. Hint: First decide whether S2/E2 or S1/E1 is favored, and then decide whether the reaction pathway goes by a substitution or elimination reaction. SN2 / SN1 E2/E1 Na DMSO,rt...
Br DMSO H20 N-Br OH N-H dilute H2SO4 OH h sN1 Nucleophilic substitution. a Proton transfer e J Electrophilic addition b Lewis acid/base i SN2 Nucleophilic substitution f*E1 Elimination c -Radical chain substitution j Electrophilic aromatic substitution g FE2 Elimination d Radical chain addition Identify the mechanism by which each of the actions above proceeds from a the mechanisms listed. Use the letters a j for your answers.
Short Answer Section (43 pts) – showing work helps! Substitution
vs. Elimination (12 pts). Predict all major product(s) of each of
the following reactions and indicate the predominant mechanistic
pathways (Sn1, Sn2, E1, E2). Remember to consider rearrangements.
Mechanism #1 (10 pts). Draw a stepwise mechanism to account for the
following transformation. Br mechanism(s)? NaOH Cl mechanism(s)?
NaOEt OTs for this reaction, circle the major product mechanism(s)?
O K Cl for this reaction, circle the major product mechanism(s)?
NaOCH3 H2O...
3. Determine the mechanism of nucleophilic substitution (SNI or SN2) for each reaction and draw the products. Be aware of stereochemistry. 8 + CN - dletone m et och cun, DE Br + OCH₂ CH₂ DME 4. Draw all constitutional isomers formed during each elimination reaction after determining whether it is E1 or E2. habel it as El or E2. госна. a y "ocha, B b. Tă CH₃OH Br -OH
Alkyl Halides and their Reactions: Nucleophilic Substitution and Elimination l. Predict the major organic product for each of the following. (1 major structure is all that needed in each case). (3 points each) Br CH3ONa CH3CH2ONa (for "d", show elimination product only, there will also be some substitution) NaOH e, optically active (for "e", show substitution product or products only. If both enantiomers form, draw both) Is the product solution for reaction "e" above racemic or optically active? (1 point...
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