Indicate the sign of Gº at low and high temperatures for the following reactions: Reaction Low T High T NH3(g) + HCl(g) NH4Cl(s) Hº < 0 CaCO3(s) CaO(s) + CO2(g) Hº > 0 CH3OH(l) CH3OH(g) 2Cl2(g) + 7O2(g) 2Cl2O7(l) Hº > 0
As we ∆G = ∆H-T∆S
A) low T =-
High T = +
B) low T =+
High T = -
C) low T =+
High T =-
D) low T = +
High T = +
Indicate the sign of Gº at low and high temperatures for the following reactions: Reaction Low...
6. (3 points) For each of the following reactions, predict the sign (positive or negative) for the AS and AH values. Then determine when the reaction will be spontaneous (always, never, at high temperatures, or at low temperatures). a. CH4(g) + 202 (g) → CO2 (g) + 2H20 (g) b. 4H3PO4(s) - P010 (s) + 6H20 (1) c. HCI (g) + NH3(g) → NH4Cl (s)
1. Determine the ∆Sº using Appendix G for the following reaction. C2H5OH(l) + 3 O2(g) --> 2 CO2(g) + 3 H2O(l) Report your answer to three sig figs. Omit unit labels. Only add a - number is the sign is negative. Adding a + to a positive answer messes up the grading. 2. Which of the following equations will have a negative ∆S? A. 3 H2(g)+ N2(g) --> 2 NH3(g) B. C6H6(l)--> C6H6(g) C. NH4OH(s)--> H2O(l)+ NH3(g) D. NaCl(s) -->...
this is the question b) HCl(g) + NH3(g) → NH4Cl(s) 5) Calculate AHP, AS, and Gº for the following reactions at 25°C: (30)
A) Calculate ?Hrxn for the following reaction: CaO(s)+CO2(g)?CaCO3(s) Use the following reactions and given ?H values: Ca(s)+CO2(g)+12O2(g)?CaCO3(s), ?H= -812.8 kJ 2Ca(s)+O2(g)?2CaO(s), ?H= -1269.8 kJ B) Calculate ? Hrxn for the following reaction: CH4(g)+4Cl2(g)?CCl4(g)+4HCl(g) given these reactions and their ?H values: C(s)+2H2(g) ---> CH4(g), ? H=-74.6kJ C(s)+2Cl2(g) ---> CCl4(g), ? H=-95.7kL H2(g)+Cl2----> 2HCl(g), ? H=-184.6kJ
for which of these an increase in entropy? a. caco3(s)-> Cao(s)+ co2(g) b. Nh3(g)+ Hcl(g)-> nh4cl(s) c. h20(g)-> h20(l) d.2no2(g)-> n202(g)
Exercise 18.38-Enhanced-with Feedback 7 of 13> Part E ReviewI ConstantsI Periodic Table In addition, predict under what temperatures (all temperatures, low temperatures, or high temperatures), if any the reaction in each part will be spontaneous. Without doing any calculations, iddentify the signs of ΔSays and ΔSsurr for each of the following chemical reactions. Drag the appropriate items to their respective bins. Reset Help Reaction is spontaneous at all temperatures Reaction is spontaneous at low temperatures Reaction is spontaneous at high...
12. At high temperatures, limestoned CaCO3 (s) e CaO (s) + CO2 (g,) If this reaction is run at 900°C and reaches equilibrium when [CO21-0.76 M, what is the value of Kp at this temperature? A. 0.76 B. 73 C. 56 D. 0.008 E. 96
IU. AS is positive for the reaction A) CaO (s) + CO2 (g) CaCO3 (S) B) N2 (g) + 3H2(g) → 2NH3 (g) C) 2503 (g) - 2802 (g) + O2 (g) D) Ag+ (aq) + Cl- (aq) → AgCl (s) E) H20 (1) + H20 (s) 11. AS is positive for the reaction A)2 Ca(s) + O2 (g) 2 Cao (s) B) 2 KClO3 (s) 2KCI(S) + 30 (g) C) HCl (8) + NH3 (8) ► NH4Cl (s) D)...
44" What is the sign of ΔΗ (system) and AS (system) if a chemical reaction is spontaneous at all temperatures under stan conditions? a. AH (system) is negative, and ΔS (system) is positive. b. AH (system) is negative, and AS (system) is negative. C. AH (system) is positive, and AS (system) is positive. d. AH (system) is positive, and AS (system) is negative. e. none of these 45. For which of the following reactions will the entropy of the system...
18.74 Predict the algebraic sign of the entropy change for the following reactions. (a) 12(s) → 12(g) (b) Brz(g) + 3Cl2(g) → 2BrCl3(g) (C) NH3(g) + HCl(g) → NH CI(s) (0) CaO + H2O) + Ca(OH)2(s)