The rate constant for the enzyme-catalysed decomposition of hydrogen peroxide, H2O2, increases by a factor of...
- The rate constant for the enzyme-catalysed decomposition of hydrogen peroxide, H2O2, increases by a factor of 3.8 when the temperature is increased from 298 K to 348 K. Determine the activation energy.
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The rate constant for the enzyme-catalysed decomposition of
hydrogen peroxide, H2O2, increases by a
factor of...
1) The rate constant for the reaction 2 N,Os(9) = 4 NO (9) + O2(9) is...
1) The rate constant for the reaction 2 N,Os(9) = 4 NO (9) + O2(9) is reported in units of sl. What is the overall order of the reaction? 2) The rate law for a reaction was reported as rate=k[A] [B][C] with molar concentrations in moles per cubic decimetre and time in seconds. What are the units of k? 3) The rate constant for the pseudo first-order acid- catalysed hydrolysis of glucose is 4.07' 10-s. Calculate the half-life for the...
1) The reaction of hydrogen peroxide with iodine, H2O2(aq)+I2(aq)⇌OH−(aq)+HIO(aq) is first order in H2O2 and first...
1) The reaction of hydrogen peroxide with iodine, H2O2(aq)+I2(aq)⇌OH−(aq)+HIO(aq) is first order in H2O2 and first order in I2. If the concentration of H2O2 was increased by half and the concentration of I2 was quadrupled, by what factor would the reaction rate increase? 2) Consider the following reaction: O3(g)→O2(g)+O(g) Using the results of the Arrhenius analysis (Ea=93.1kJ/mol and A=4.36×1011M⋅s−1), predict the rate constant at 298 K . 3. The rate constant of a chemical reaction increased from 0.100 s−1 to...
The decomposition of hydrogen peroxide, H2O2, is first order with a rate constant, k=3.66 x 10-3s-1....
The decomposition of hydrogen peroxide, H2O2, is first order with a rate constant, k=3.66 x 10-3s-1. If the initial concentration of H2O2 is 1.05M. Calculate the [H2O2] after 167s.
4. Determine the activation energy for the KI-catalysed decomposition of hydrogen peroxide. Things to consider: a)...
4. Determine the activation energy for the KI-catalysed decomposition of hydrogen peroxide. Things to consider: a) What variables do you need to determine the activation energy of a reaction? b) Which variable(s) would be dependent? Which would be c) How will you measure them? d) How many measurements do you need? e) How can you distribute the measurements among the group? independent?
Rate constant for decomposition of hydrogen peroxide is 7.0 x10-5 s-1at 300.0K, with activation energy of 75...
Rate constant for decomposition of hydrogen peroxide is 7.0 x10-5 s-1at 300.0K, with activation energy of 75 kJ/mol. At what temperature would the reaction rate be doubled?
4. [Chang, 10.27) The activation energy for the decomposition of hydrogen peroxide: 2H2O2 (aq) → 2H200...
4. [Chang, 10.27) The activation energy for the decomposition of hydrogen peroxide: 2H2O2 (aq) → 2H200 + O2(g) is 42 kl.mol-1, whereas when the reaction is catalyzed by the enzyme catalase, it is 7.0 kJ. mol-1. Calculate the temperature that would cause the nonenzymatic catalysis to proceed as rapidly as the enzyme-catalyzed decomposition at 20°C. Assume the pre-exponential factor to be the same in both cases.
For the decomposition of a peroxide, the activation energy is 17.4 kJ/mol. The rate constant at...
For the decomposition of a peroxide, the activation energy is 17.4 kJ/mol. The rate constant at 25°C is 0.027 s-1. What is the rate constant at 45°C? For the decomposition of a peroxide, the activation energy is 17.4 kJ/mol. The rate constant at 25°C is 0.027 s-1. At what temperature will the rate constant be 35% greater than the rate constant at 25°C?
13. A. The decomposition of hydrogen peroxide is a first-order process with a rate constant of...
13. A. The decomposition of hydrogen peroxide is a first-order process with a rate constant of 1.06 x 10 min. How long will it take for the concentration of H2O2 to drop from 0.0200 M to 0.0120 M? <1 min 7.55 min 481 min 4550 min 31 400 min The rate constant is 5.4 C. D. E
1) Hydrogen peroxide, H2O2(aq), decomposes to H2O(l) and O2(g) in a reaction that is first order...
1) Hydrogen peroxide, H2O2(aq), decomposes to H2O(l) and O2(g) in a reaction that is first order in H2O2 and has a rate constant k = 1.06×10−3 min−1 at a given temperature. How long will it take for 15% of a sample of H2O2 to decompose? 2)The decomposition of nitrogen dioxide, NO2, into nitrogen monoxide and oxygen at a high temperature is second-order in NO2. The rate constant for this reaction is 3.40 L/mol×min. Determine the time needed for the concentration...
1a) The decomposition of hydrogen peroxide is first order in [H2O2]. After 60 min the [H2O2]...
1a) The decomposition of hydrogen peroxide is first order in [H2O2]. After 60 min the [H2O2] has fallen from 3.7 M to 3.4 M. The rate constant k, in min-1 , is A. 1.4 X 10-3 B. 6.1 X 10-4 C. 2.7 X 10-2 D. 8.3 X 10-3 E. 1.2 x 10-2 1b) What is the half-life, in seconds, of a first order reaction if 30% of the reactant has decomposed in 50 seconds? A. 50 B. 83 C. 26...
1) The rate constant for the reaction 2 N,Os(9) = 4 NO (9) + O2(9) is reported in units of sl. What is the overall order of the reaction? 2) The rate law for a reaction was reported as rate=k[A] [B][C] with molar concentrations in moles per cubic decimetre and time in seconds. What are the units of k? 3) The rate constant for the pseudo first-order acid- catalysed hydrolysis of glucose is 4.07' 10-s. Calculate the half-life for the...
4. Determine the activation energy for the KI-catalysed decomposition of hydrogen peroxide. Things to consider: a) What variables do you need to determine the activation energy of a reaction? b) Which variable(s) would be dependent? Which would be c) How will you measure them? d) How many measurements do you need? e) How can you distribute the measurements among the group? independent?
4. [Chang, 10.27) The activation energy for the decomposition of hydrogen peroxide: 2H2O2 (aq) → 2H200 + O2(g) is 42 kl.mol-1, whereas when the reaction is catalyzed by the enzyme catalase, it is 7.0 kJ. mol-1. Calculate the temperature that would cause the nonenzymatic catalysis to proceed as rapidly as the enzyme-catalyzed decomposition at 20°C. Assume the pre-exponential factor to be the same in both cases.
13. A. The decomposition of hydrogen peroxide is a first-order process with a rate constant of 1.06 x 10 min. How long will it take for the concentration of H2O2 to drop from 0.0200 M to 0.0120 M? <1 min 7.55 min 481 min 4550 min 31 400 min The rate constant is 5.4 C. D. E
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