Option (4) is the correct answer.
The Doppler effect explains broadening of the natural width of a spectroscopic line----(4) due to movement of light source relative to the detector.
Explanation:
When movement of the light source change with respect to detector then there will be change in frequency of the light with respect to detector due to Doppler effect ---resulting in a broadening of the natural width of the spectral line due the Doppler effect.
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