OH The compand can be prepared with on alkyl iodide & a suitable nucleophile. Identify the...
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12. Each of the following compounds can be prepared with an alkyl iodide and a suitable nucleophile. In each case, identify the alkyl iodide and the nucleophile that you would use: a) A d) "ОН SH Он b) e) SH c) f) ICN
Q1 Identify the alkyl bromide, nucleophile and solvent that you would use to prepare the following compound. (5 pts) Nucleophile Alkyl bromide Solvent
CH3CH2CH2CN can be synthesized by an SN2 reaction. Draw the structures of the alkyl chloride and nucleophile that will give this compound in highest yield. Use the wedge/hash bond tools to indicate stereochemistry. Include all valence lone pairs in your answer. Separate multiple reactants using the + sign from the dropdown menu. When a metal counterion is needed, use Na+, but draw it in its own sketcher
The ether shown can be prepared using a Williamson ether synthesis; that is, by reacting an alkoxide ion with an alkyl halide. Draw the alkoxide ion and alkyl bromide that you would combine to make the ether with the highest possible yield. You may omit the metal cation counterion that accompanies the alkoxide ion for the purposes of this question. Include all lone pairs and nonzero formal charges. 1 stattomat
CH&CH PH2 can be synthesized by an S:2 reaction. Draw the structures of the alkyl chloride and nucleophile that will give this compound in highest yield. Use the wedge/hash bond tools to indicate stereochemistry where it exists. . Include all valence lone pairs in your answer Separate multiple reactants using the sign from the drop-down menu. When a metal counterion is needed, use Na, but draw it in its own sketcher.
CH3OCH,C(CH3)3 can be synthesized by an Sy2 reaction. Draw the structures of the alkyl chloride and nucleophile that will give this compound in highest yield. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Include all valence lone pairs in your answer. • Separate multiple reactants using the + sign from the drop-down menu. • When a metal counterion is needed, use Na+, but draw it in its own sketcher. CHA ChemDoodle
Draw the structure of the alkyl bromide and the nucleophile that
will react in an SN2 reaction to give the product shown.
Draw the product you expect
from the reaction of (S)-3-iodohexane with
CH3CO2-.
Draw the structure
of the major organic product you would expect from the reaction of
1-bromopropane with
NaNH2.
Draw the structure of the alkyl bromide and the nucleophile that will react in an SN2 reaction to give the product shown. NH3 Br Alkyl bromide...
(12 points) Esters can be prepared by nucleophilic substitution of an alkyl halide or via acyl substitution reactions. Show the compounds required to synthesize the ester two different ways. Be sure the product will be favored. 4. H0 alkyl halide nucleophile acyl derivative nucleophile Given the information in the question above, provide appropriate reactants above. hat does a nucleophilic substitution reaction look like in general? Acyl substitution?
(12 points) Esters can be prepared by nucleophilic substitution of an alkyl halide...
Experiment 14 SN2: Synthesis of 1-Bromobutane Alkyl halides can be prepared from their corresponding alcohols via an acid catalyzed substitution reaction. The mechanism of these acid catalyzed substitution reactions are labeled as SNI (substitution, nucleophilie, unimolecular) and S2 (substitution, nucleophilie, bimolecular). Tertiary alcohols follow the Syl route, primary alcohols follow the S2, route and secondary alcohols can follow either path. Sth CyHe 81 CH? Br-CH e-OH- -C-OH OH Figure / Conversion of 1-butanol into 1-bromobutane by an Sp2 mechanism The...
(a) OH 8.35 (SYN) For each of these compounds, draw an alkyl halide that can be used to produce it in an S1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol and draw the corresponding mechanism. Toon OCH3