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Activating group are those which increases electron density in aromatic ring. So they activate ring for electrophilic aromatic substitution reaction. +M , +H and +I group are activating group.
Deactivating group deactivate ring for electrophilic aromatic substitution reaction. -M , -H and -I groups are deactivating group.
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Please answer as soon as possible Select the statement that is true about the electrophilic aromatic...
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring deactivating? Select one: -CIN 0 -NH₂ O NO₂ O-CO₂H
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring deactivating? of Select one: O -NH2 O-SO3H O-1 0 -CN O-OCH3
6. (9 pts) In regards to an electrophilic aromatic substitution reaction, define the 3 compounds shown below as either: a) Activating, ortho, para director b) Deactivating, ortho para director, c) Activating, meta director, d) Deactivating, meta director. CH -ОН -N-CH3 CH3 7. Answer a-c for compounds A-F below dos a. (5 pts) Which compound(s) have an aromatic carbocation intermediate if it underwent an Snl or E1 reaction? b. (5 pts) Which compound(s) would have an anti-aromatic carbocation intermediate if it...
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring ?deactivating اختر أحد الخيارات CI- CO2H- NO - O NH2- OH-
Which of the following is not a correct statement about the electrophilic aromatic substitution mechanism. Select one: a. Benzene functions as a nucleophile. b. Aromaticity is regained by the loss of H+. c. All carbons in the ring of the arenium intermediate are sp2 hybridized. d. An activating group will decrease the nucleophilicity of benzene. e. All statements are correct.
to form Which of the following possible Birch reduction products would not be expected CH3 CH3 0 CH3 A. B. C. Which of the following substrates would most likely undergo a successful nucleophilic aromatic substitution reaction with diethylamine? NO2 NO 2 NO 2 A. B. C. D. Which of the following resonance structures does not depict stabilization of the negative charge in the Meisenheimer complex? 0 A. The nitro group has which of the following effects in electrophilic aromatic substitution?...
Activating/Deactivating Substituents Below is a list of different substituents and experimental results from attempted electrophilic aromatic substitution. PhNR, PHCN PhCHO PhF PhMe PhoMe PhNH Deactivating Activating PhNO, PhSozH Phl PhH PNHAC POH • Is the aromatic ring an [ electrophile / nucleophile ] in these reactions? Which substituents 'activate the ring (i.e. make it more reactive? 0 Alkyl substituents: Activate OR Deactivate o Halide substituents: Activate OR Deactivate o OH, NH substituents: Activate OR Deactivate o carbonyl groups: Activate OR...
Friedel - Craft Acylation Synthesis of 4-Methoxiacetophenone Background Information 1.- What is an electrophilic aromatic substitution? 2.- Give three examples of activating groups. Explain why they activate the ring for substitution. 3.- Give three examples of deactivating groups. Explain why they deactivate the ring for substitution. 4.- Describe the difference between a Friedel-Craft alkylation and Acylation. Synthesis of 4-Methoxiacetophenone For this Friedel-Craft acylation we will react Anisole with Acetic Anhydride. Write the mechanism and the structure of the final product....
Please help... Need a detail Mechanism of this reaction. Thanks... Electrophilic aromatic substitution describes the reaction where a hydrogen from a benzene ring is replaced by an electrophile. Halogenation, nitration, sulfonation, alkylation and acylation are all possible using this type of reaction. The electrophile attacks the pi electrons of the aromatic ring, yielding a benzenonium ion. The substituted aromatic product is obtained when a proton is lost, restoring the aromatic system. If there is a substituent on the aromatic ring...
12. Dialkyl ethers (e.g., diethyl ether) are typically unreactive with all of the following classes of reagents except: d. reducing agents c. nucleophiles b. strong bases a. strong acids 13. The carbonyl carbon of (C 0) of aldehydes and ketones has a high degree of (positive or negative) charge which provides a good site for attack of (electrophiles or nucleophiles). a. negative, electrophiles b. negative, nucleophiles a. positive, electroph b. positive, nucleophiles 14. Which of the following is the major...