Part A
Find the [OH−][OH−] of a 0.49 M M methylamine (CH3NH2CH3NH2) solution. (The value of KbKb for methylamine (CH3NH2CH3NH2) is 4.4×10−44.4×10−4.)
Part B
Find the pHpH of a 0.49 M M methylamine (CH3NH2CH3NH2) solution.
Answer
part A :[OH-] = 0.46 M
,part B pH= 12.17
explanation:
We have been given , concentration of methyl amine = 0.49 M
Kb = 4.4*10^-4.
Writing the equilibrium equation,
CH3NH2(aq) + H2O(l) ⇌ CH3NH3+(aq) + OH−(aq) .
Kb = [ CH3NH3(+)][OH(-)] /[CH3NH2]
since, [CH3NH3+] = [ OH-]
Kb= [OH-]^2/ [CH3NH2]
[OH-]^2 = Kb *[CH3NH2]
[OH-] =√4.4*10^-4*0.49
[OH-] = 1.46*10^-2
[OH-] = 0.0146 M.
Explanation
part B : since OH - = 0.0146 M
pOH = -log [OH-]
= -log [0.0146 ]
=1.83
So,
pH = 14- pOH
pH= 14 - 1.83 = 12.17
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