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PCC CHC12 RCH, OH Croj, H2SO RCH-OH PCC/CH,C1, or Croz, H2SO4 PBry SOCL-/pyridine SOClybenzene RCH-OH R...
1) + NaOH J) OH PCC CH,C1, K) H СН,ОН L) 1. Mg, ether -Br o...
1) + NaOH J) OH PCC CH,C1, K) H СН,ОН L) 1. Mg, ether -Br o 2. 3. H,0 M) OH Na Cr 0 H2SO4 4. Propose Mechanism (Show your work) (14 pts) A) CH,CH,CH,OH CHỊCH CHỊCHCHỊCOH
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20...
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20 refux 9- NH2 CH -C-Cl 10. 2.HaO кон. rMso 12- CH3 CH Ch 13- NH2 14- -78C 15- OH LiAIH 4 16- socl2 2 pyridine P2Os NH2 18- 1. NaHCO.. H2O 2. OH Br 19. 2, H30 20- 1. BH4 2. H3O 21- 22- 2. PBr 3.2 equiv. CH,CH CH&NH 23- 1. Mg Br 3. NaHCO Cl 24- 2 LAH 25-
2. List the expected spectral data of 2-ethyl-3-hydroxy-hexanal observed from an IR, a 'H-NMR and mass...
2. List the expected spectral data of 2-ethyl-3-hydroxy-hexanal observed from an IR, a 'H-NMR and mass spectrum. CH3 -CH2 CH C-Hal C-N C-o CEC Intensity CEN Aromatic C=C C=0 220 200 180 160 140 120 60 40 20 0 ppm 100 80 Chemical shift (8) Intensity Bonding C-H Type of Vibration (Stretching unless noted) alkane CH -CH, alkene w-m m w-m bending bending out-of-plane bending alkyne arene Frequency (cm) 2850-3000 1375 and 1450 1450-1475 3000-3100 650-1000 3300 3030 690-900 2720...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2 BHA 3) H,09 B) YN B 1) My C) ОН 2) 2)CO2 3) H30 4) CH3OH D) 3) E) 0 OH H 1)DBAL-H 2)Ph PCH2 3) mCPBA 1) SOCI2 2CH.NH. pyridine 3) excess LAHA 4)H,0* F) 0 O 4) OH o G) excess HB H) 5) 1) 6) H30* Δ. Mglk J) 7) OH 0 2 1,0 hp question completion Status: Н. 6) Н...
A1 A 42 NH, OEt B1 OH B B2 ОН Me Me ОН C1 Ph C2...
A1 A 42 NH, OEt B1 OH B B2 ОН Me Me ОН C1 Ph C2 C OH Give the proper reagent for each of these two-step reaction sequences. Pick the reagent from the table below. (Assume aqueous workup when needed.) 1. Br2 / uv light 2. SOCI2 / THE 3. Mg/Et20 4. Meli/hexane 5. CH3CH2MgCI 6. PhMgBr 7. NaBH4 8. LIAIH4 9. BH3 / 0x 10. POCI3/pyridine / THE 11. CrO3 / THE 12. PCC / CH2Cl2 13. H...
Multi-step synthesis ci R R NH, OEt А OH B 1. Br2 / uv light 2....
Multi-step synthesis ci R R NH, OEt А OH B 1. Br2 / uv light 2. SOCI2 / THE 3. Mg/Et20 4. Meu/hexane S. CH3CH2MgCl 6. Ph MgBe 7. NaBHA 8. LAHA 9. BH3 /OX 10. POCl/pyridine/ THF 11.03/THE 12. PCC / CH2 13.H/H20 14. ELOH/H 15. t-butaxide 16. OH/H20 17. NHS 18.CO2 19. acetic anhydride 20.HNMez/THE In each box, type out the list of reagents in proper order that will carry out the synthesis of the final product (This...
please need help with all the questions and ASAP, thank you 11. Please predict the principle...
please need help with all the questions and ASAP, thank you
11. Please predict the principle organic product of the following reactions, show stereochemistry where appropriate. Note that some reactions involve isotope-labeled compounds, in those cases the correct isotope must be used. (66') 1. LIAID 2. H,O (1) 18 1) THF (2). CH3Li + 2) HaO NaBH4 (3) CH3OD H2(excess)/Pt (4) d herd (5). - Mg Br D2O diethyl ether Br +Li (6) diethyl ether LICu(CH2CHs)2 Br (7). 1. diethyl...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the following equation. CH3OH (g) → CO(g) + 2 H2(g) AH = 90.2 kJ (7 pts.) When one adds 1.475 kJ of heat energy to a sample of gold, the temperature goes from 12.5 °C to 84.6 °C. Calculate the mass of the sample of gold. Gold has a specific heat capacity of 0.129 J/g.°C. (6 pts.) 10. Write the thermochemical equation for the standard...
1) + NaOH J) OH PCC CH,C1, K) H СН,ОН L) 1. Mg, ether -Br o 2. 3. H,0 M) OH Na Cr 0 H2SO4 4. Propose Mechanism (Show your work) (14 pts) A) CH,CH,CH,OH CHỊCH CHỊCHCHỊCOH
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20 refux 9- NH2 CH -C-Cl 10. 2.HaO кон. rMso 12- CH3 CH Ch 13- NH2 14- -78C 15- OH LiAIH 4 16- socl2 2 pyridine P2Os NH2 18- 1. NaHCO.. H2O 2. OH Br 19. 2, H30 20- 1. BH4 2. H3O 21- 22- 2. PBr 3.2 equiv. CH,CH CH&NH 23- 1. Mg Br 3. NaHCO Cl 24- 2 LAH 25-
2. List the expected spectral data of 2-ethyl-3-hydroxy-hexanal observed from an IR, a 'H-NMR and mass spectrum. CH3 -CH2 CH C-Hal C-N C-o CEC Intensity CEN Aromatic C=C C=0 220 200 180 160 140 120 60 40 20 0 ppm 100 80 Chemical shift (8) Intensity Bonding C-H Type of Vibration (Stretching unless noted) alkane CH -CH, alkene w-m m w-m bending bending out-of-plane bending alkyne arene Frequency (cm) 2850-3000 1375 and 1450 1450-1475 3000-3100 650-1000 3300 3030 690-900 2720...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2 BHA 3) H,09 B) YN B 1) My C) ОН 2) 2)CO2 3) H30 4) CH3OH D) 3) E) 0 OH H 1)DBAL-H 2)Ph PCH2 3) mCPBA 1) SOCI2 2CH.NH. pyridine 3) excess LAHA 4)H,0* F) 0 O 4) OH o G) excess HB H) 5) 1) 6) H30* Δ. Mglk J) 7) OH 0 2 1,0 hp question completion Status: Н. 6) Н...
A1 A 42 NH, OEt B1 OH B B2 ОН Me Me ОН C1 Ph C2 C OH Give the proper reagent for each of these two-step reaction sequences. Pick the reagent from the table below. (Assume aqueous workup when needed.) 1. Br2 / uv light 2. SOCI2 / THE 3. Mg/Et20 4. Meli/hexane 5. CH3CH2MgCI 6. PhMgBr 7. NaBH4 8. LIAIH4 9. BH3 / 0x 10. POCI3/pyridine / THE 11. CrO3 / THE 12. PCC / CH2Cl2 13. H...
Multi-step synthesis ci R R NH, OEt А OH B 1. Br2 / uv light 2. SOCI2 / THE 3. Mg/Et20 4. Meu/hexane S. CH3CH2MgCl 6. Ph MgBe 7. NaBHA 8. LAHA 9. BH3 /OX 10. POCl/pyridine/ THF 11.03/THE 12. PCC / CH2 13.H/H20 14. ELOH/H 15. t-butaxide 16. OH/H20 17. NHS 18.CO2 19. acetic anhydride 20.HNMez/THE In each box, type out the list of reagents in proper order that will carry out the synthesis of the final product (This...
please need help with all the questions and ASAP, thank you
11. Please predict the principle organic product of the following reactions, show stereochemistry where appropriate. Note that some reactions involve isotope-labeled compounds, in those cases the correct isotope must be used. (66') 1. LIAID 2. H,O (1) 18 1) THF (2). CH3Li + 2) HaO NaBH4 (3) CH3OD H2(excess)/Pt (4) d herd (5). - Mg Br D2O diethyl ether Br +Li (6) diethyl ether LICu(CH2CHs)2 Br (7). 1. diethyl...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the following equation. CH3OH (g) → CO(g) + 2 H2(g) AH = 90.2 kJ (7 pts.) When one adds 1.475 kJ of heat energy to a sample of gold, the temperature goes from 12.5 °C to 84.6 °C. Calculate the mass of the sample of gold. Gold has a specific heat capacity of 0.129 J/g.°C. (6 pts.) 10. Write the thermochemical equation for the standard...
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