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1) + NaOH J) PCC OH CHCI K) H CH OH L) 1. Mg, ether Br 2. 3. H2O M) OH I Na Cr2O7 H2SO4
please explain mechanism 42. Provide the product for the following reaction HOCH,CH,OH Mg/ether Н,0° Br H2SO4 2. Но хото го он ПІ А) 1 B) II C) III
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но он ОН он IV он у Predict the product of the following synthesis. 1. Br2, H20 2. NaOH, HO 3. CH2OH, H+ OCH, н,со OCH, A B с OCH OCH OCH, D E Predict the product for the following reaction. OH Acid Catalyst + 25 °C O А D с B
но (CH,),CHBr (CH),CH-OH (е) но (CHJ,СB (CH),C-Он acetone - сн,сH,осH,сн, + Br CH,CH,O' + CH,сH, Br аcctone Br CH,CH,SCH,CH, + CH,CH,S + CH,сң, Br (CH),СBr + кон + KBr (CH],COн ab (CH),CBr + H,о + HBr (CH,),COH CH,OH (CH,),CH-OCH, (CH,),CHBr (h) сHOн (CH),C-ОCH, (CH,),CBr HS Br Br SH +HS +Br SH Br
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
Predict the product for the following reaction sequence. Br Mg/ether H_Cro H,00 OH OH А B C D A Provide the product of the following reaction CI CH,CO Na OCH O Na
j k l m n pleaseee pleaseee HNO, H,SO, CHO (k) PCC, excess CH2Cl OH 2. (CHbS (DMS) (m) On (n) esoes снсH,он H,SO, (o)
Show each step 1. PPh; 2. Buli 0 3 он 1. PCC, CH,CI, ,H,O+ 1. 9-BBN 2. H,O, OH- 3. (2) EtOH, H2O+ 1. MeCI, AICI: 2. NBS, hv 3. NaOH 4.PCC, CH,CI, 5. KCN, HCN
Mg, ether 1-bromobutane. (D) KOH, H2O (A) Na (B) CH CH Br (C) (i) CH30CH2 3 (E) (2) H30 H2SO4, heat (F)
Fill in the blanks to complete the reaction. (3pts each) Br Н-С—с—н Mg CH3CHCH2CH3 1 Ether Br (CH),CО H 2 C CH-CH,ОH CH3CH20 + 3 E1OH CI 1. ВНз 2. NaOH, H02 ОН HO 5 (CH3CH2)2CuLi 6 OH Bi Br КОН 7 Нас NaCN DMSO