1) Label each of the following molecule as optically active (OA) or optically inactive (OD? (Type...
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Question 1 2 pts Determine whether the molecule below is optically active. cannot determine O optically active O optically inactive Question 2 2 pts Determine the relationship between the two molecules below NH2 HO H3COOH identical enantiomers constitutional isomers diastereomers Question 3 2 pts Determine the relationship between the two molecules below H HOW enantiomers O identical constitutional isomers diastereomers D Question 4 2 pts Determine the total number of stereoisomers represented by the bond line drawing...
Draw the structure of the products formed when the sugar below is reacted with sodium borohydride followed by water. On the lines provided, indicate whether each product is optically active (O.A.) or optically inactive (O.I.).Show the mechanism.
Classify the following as "optically active" (some positive or negative rotation) or optically inactive" (optical rotation of zero). 12. a) A solution of 1-iodohexane b) A solution of (S)-2-iodohexane c) A solution of 40% (S)-3-chlorohexane and 60% (R)-3-chlorohexane d) A solution of equal quantities of (R) and (S) 3-chlorohexane
5. (a) Draw the structure of (15.25,5R)-5-ethyl-2-isobutylcyclohexanol. Use solid and dashed wedges to show the proper configurations of the chiral centers. (0.4 pts) (b) Draw both chair conformations for this structure (0.4 pts) (c) Draw a box around the most stable chair conformation (0.2 pts) 6. Compounds A, B, and C are stereoisomers of 1,3-dimethylcyclopentane. Characterize the following solutions as optically active or optically inactive: (1) an equal mixture of B and C and (2) an equal mixture of A...
7. (9 pts) (Are the following optically active or meso? meso HyCHC OH HO opticaly actve active opti call active 8. (3 pts) How many stereoisomers are there of 2,3-dibromobutane? 4 sleeoisamvers (8 pts) Circle the letter of the statements that are true. a. Racemic mixtures are optically active Enantiomers have specific rotations that are equal, but have opposite signs 9. o adtc) Achiral molecules are optically inactive d Meso compounds contain equal amounts of enantiomers 4pts) Complete the Fischer...
19) Would a 50/50 mixture of the two compounds below be optically active? Briefly explain your answer CH3 H-Br Br CH3 OH
10) Which of the following are optically inactive? A) a 50-50 mixture of Rand Senantiomers B) a racemic mixture C) every achiral compound D) a meso compound E) all the above 11) If (S)-glyceraldehyde has a specific rotation of -8.7, what is the specific rotation of (R)-glyceraldehyde? A) +8.7 B) -8.7 C) 0.0 D) cannot be determined from the information given 12) What is the relationship between the following compounds? HCI CH - CH₂ CH3 HEC HCI HEC X сін...
31 Multiple Choice Problems: 16 questions, 4 pts each =64 total. 1. Circle optically active molecules from the list below: HO Br H Br H HC 2. What is the relationship of the following two molecules, one in bond-line structure and one in Fischer projection? Br Me Me Cl CA Br Same molecule with same rotational conformation a. b. Same molecule with different rotational conformation C. Constitutional isomers d. Enantiomers Diastereomers e. Identify the resonance pattern for the following curved...
Practice Problem 07.71 When the following optically active alcohol is treated with HBr, a racemic mixture of alkyl bromides is obtained OH Br HBr + H2O Racemic mixture Draw the mechanism of the reaction. Step 1 Get help answering Molecular Drawing questions. Incorrect, Did you follow the instructions exactly when drawing this mechanistic step, what type of mechanism step is shown here? Is it a Loss of Leaving Group or Nucleophilic Attack or Proton Tranfer or Rearrangement? Draw step 1...
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13. Consider the following reaction. Which choice below best describes the stereochemistry of the product(s) (circle one)? (A) R major product, and optically active (B) S major product, and optically active (C) Both S and R, and optically inactive (D) S major product, and optically inactive soci, pyridine Product(s) OH