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b. Give structural formulas for the following i. diaquadiiododinitropalladium(IV) (all ligands are trans) ii. tu.cachonylbis trisacaboovlikoo(o))...
Part A Which of the following pairs of coordination compounds or complex ions are examples of...
Part A Which of the following pairs of coordination compounds or complex ions are examples of ionization isomers? [Fe(NH3)2(H20)4]Cl2 and [Fe(NH3)4(H20)2Cl2 [Cu(CO)gBr]CI and [Cu(CO), CIJBr [MnCl3Br]2- and [MnCIBr312- [Fe(NH3)2(H20)4]C12 and [Fe(NH3)2(H20)4]Br2 [Fe(CO)NO12+ and [Fe(CO) ONO]2+ Submit Previous Answers Request Answer Part A Identify the isomers that have ligands that coordinate to a metal with different donor atoms. stereoisomers cis-trans isomers linkage isomers O coordination isomers O optical isomers Submit Request Answer Which of the following is a type of constitutional...
3. For the following trans effect substitution reactions, predict the square planar products [labelled (a) through...
3. For the following trans effect substitution reactions, predict the square planar products [labelled (a) through ()]. Reminder: the complete list of trans effect ligands can be found in your textbook (Miessler, Tarr, Fischer). Be sure to indicate the arrangement of ligands by using words or pictures. (10 marks) (i) [PtC14]2-+ NO2 + (a) (a) + NH3 + (b) (ii) [PtCl3NH3] + NO2 → (c) (c) + NO2 → (d) [PtCl(NH3)3]* + NO2 → (e) (iii) (e) + NO2 →...
From the following list of metal ions and ligands, construct metal complexes with properties which match...
From the following list of metal ions and ligands, construct metal complexes with properties which match that described in each part of the question and provide a brief explanation. (Only one example is required for each part of the question, e.g. [Fe(H20)6]21). Metal ions Ligands (in order of increasing ligand field strength) [ < Br< <C1° <NO3 <OH <ox?- <H2O< Ti(IV), V(III), V(IV), Cr(II), Cr(III), Mn(II), NH3 <en <bpy < PPh3< CN=CO Mn(III), Mn(IV), Fe(II), Fe(III), Co(II), Co(III), en =...
4) Identify all the disaccharides from the following list: i) Lactose ii) Glucose iii) Ribose iv)...
4) Identify all the disaccharides from the following list: i) Lactose ii) Glucose iii) Ribose iv) Maltose A) i + li B) iii + iv C) i + iv D) ii + ili
Question 1 Which of the following hydrogens is the most acidic? II IV I III A....
Question 1 Which of the following hydrogens is the most acidic? II IV I III A. IV B. V C. III D.I E. II Question 2 What is the product, Z, of the following reaction sequence? iz H30+ T-H20)* ia. CI H307 + Z مل I II III IV A. IV B. II C. III D.V E.
19. What would be the major product(s) of the following reaction? Br EtOH 20 °C OEt IV C) I and I...
19. What would be the major product(s) of the following reaction? Br EtOH 20 °C OEt IV C) I and III A) I and II D) IV B) II and III E) None of these choices. 20. Give a detailed reaction mechanism for the reaction expected to occur when 2-bromo- methylpentane is heated with methanol. Draw clear structural formulas of all relevant species and use curved arrows to represent electron flow. Also indicate which step is likely to be rate-...
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)"....
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
(i) explain how they differ. b. (ii) Explain how the following reaction was used to deduce the mechanism of inner sphere electron transfer. [Co(NH,),Cl]Cr(Hd+SH,OCo(H,O)+ [Cr(HO),ci+5NH 8 marks]...
(i) explain how they differ. b. (ii) Explain how the following reaction was used to deduce the mechanism of inner sphere electron transfer. [Co(NH,),Cl]Cr(Hd+SH,OCo(H,O)+ [Cr(HO),ci+5NH 8 marks] (i) Given the following ligands, suggest which one you would use as a chelating agent to treat an excess of Fe(III). Explain your choice. c. HS SH он HS NH2 Ci) Assuming an octahedral geometry, draw the strueture (inecluding any possible isomers) of the neutral Fe(III) complex that would be formed if it...
16. What is the final product of the following reaction sequence? Give structural details of all...
16. What is the final product of the following reaction sequence? Give structural details of all significant intermediates. i. NaH ii. Br CO 2Et CO 2Et Br iii. NaOEt iv. NaOH, heat v. H2O7, heat Part I. Multiple Choice, select best answer. 1. In the molecule below, which of the hydrogens are the most acidic? II IV sonryer i II í V (a) 1 (b) II (c) III (d) IV 6. What would be the major product of the following...
How many of the following compounds could exhibit cis/trans isomers? i. 2,3-dichloro-2-butene ii. 2,3-dimethyl-2-butene iii. dibromoethyne...
How many of the following compounds could exhibit cis/trans isomers? i. 2,3-dichloro-2-butene ii. 2,3-dimethyl-2-butene iii. dibromoethyne iv. (CH3)2CHCH3 V. The monomer used to form: n
Part A Which of the following pairs of coordination compounds or complex ions are examples of ionization isomers? [Fe(NH3)2(H20)4]Cl2 and [Fe(NH3)4(H20)2Cl2 [Cu(CO)gBr]CI and [Cu(CO), CIJBr [MnCl3Br]2- and [MnCIBr312- [Fe(NH3)2(H20)4]C12 and [Fe(NH3)2(H20)4]Br2 [Fe(CO)NO12+ and [Fe(CO) ONO]2+ Submit Previous Answers Request Answer Part A Identify the isomers that have ligands that coordinate to a metal with different donor atoms. stereoisomers cis-trans isomers linkage isomers O coordination isomers O optical isomers Submit Request Answer Which of the following is a type of constitutional...
3. For the following trans effect substitution reactions, predict the square planar products [labelled (a) through ()]. Reminder: the complete list of trans effect ligands can be found in your textbook (Miessler, Tarr, Fischer). Be sure to indicate the arrangement of ligands by using words or pictures. (10 marks) (i) [PtC14]2-+ NO2 + (a) (a) + NH3 + (b) (ii) [PtCl3NH3] + NO2 → (c) (c) + NO2 → (d) [PtCl(NH3)3]* + NO2 → (e) (iii) (e) + NO2 →...
From the following list of metal ions and ligands, construct metal complexes with properties which match that described in each part of the question and provide a brief explanation. (Only one example is required for each part of the question, e.g. [Fe(H20)6]21). Metal ions Ligands (in order of increasing ligand field strength) [ < Br< <C1° <NO3 <OH <ox?- <H2O< Ti(IV), V(III), V(IV), Cr(II), Cr(III), Mn(II), NH3 <en <bpy < PPh3< CN=CO Mn(III), Mn(IV), Fe(II), Fe(III), Co(II), Co(III), en =...
4) Identify all the disaccharides from the following list: i) Lactose ii) Glucose iii) Ribose iv) Maltose A) i + li B) iii + iv C) i + iv D) ii + ili
Question 1 Which of the following hydrogens is the most acidic? II IV I III A. IV B. V C. III D.I E. II Question 2 What is the product, Z, of the following reaction sequence? iz H30+ T-H20)* ia. CI H307 + Z مل I II III IV A. IV B. II C. III D.V E.
19. What would be the major product(s) of the following reaction? Br EtOH 20 °C OEt IV C) I and III A) I and II D) IV B) II and III E) None of these choices. 20. Give a detailed reaction mechanism for the reaction expected to occur when 2-bromo- methylpentane is heated with methanol. Draw clear structural formulas of all relevant species and use curved arrows to represent electron flow. Also indicate which step is likely to be rate-...
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
(i) explain how they differ. b. (ii) Explain how the following reaction was used to deduce the mechanism of inner sphere electron transfer. [Co(NH,),Cl]Cr(Hd+SH,OCo(H,O)+ [Cr(HO),ci+5NH 8 marks] (i) Given the following ligands, suggest which one you would use as a chelating agent to treat an excess of Fe(III). Explain your choice. c. HS SH он HS NH2 Ci) Assuming an octahedral geometry, draw the strueture (inecluding any possible isomers) of the neutral Fe(III) complex that would be formed if it...
16. What is the final product of the following reaction sequence? Give structural details of all significant intermediates. i. NaH ii. Br CO 2Et CO 2Et Br iii. NaOEt iv. NaOH, heat v. H2O7, heat Part I. Multiple Choice, select best answer. 1. In the molecule below, which of the hydrogens are the most acidic? II IV sonryer i II í V (a) 1 (b) II (c) III (d) IV 6. What would be the major product of the following...
How many of the following compounds could exhibit cis/trans isomers? i. 2,3-dichloro-2-butene ii. 2,3-dimethyl-2-butene iii. dibromoethyne iv. (CH3)2CHCH3 V. The monomer used to form: n
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