7.A We know that
Molarity (M)=moles of solute(n)/Volume of solution(L)
Moles of solute (n)= mass of solute(m)/molar mass of solute(MW)
Given,
Mass of CuSO4 added = 30.00 g
Volume of solution after dilution = 500.0 mL = 0.5 L
(1L=1000 mL)
Molar mass of CuSO4= 159.609 g/mol
Moles of CuSO4 (n) = Mass of CuSO4(m)/Molar mass of CuSO4(MW)
Moles of CuSO4(n) = (30.00 g)/(159.609 g/mol)=0.188 mol
Molarity (M) = moles of CuSO4(n)/Volume of solution(L)
Molarity(M) = 0.188 mol/0.5 L = 0.376 mol/L = 0.376 M
Hence, the molarity of CuSO4 stock is 0.376 M
7.B As the molarity of the solution to be prepared is lower than that of stock solution. So, using the dilution formula, we can calculate the amount of stock solution to be taken.
M1V1=M2V2 .......(1) dilution formula
M1=Molarity of stock solution =0.376 M
V1=Volume of stock solution = ?
M2=Molarity of solution to be prepared =0.100 M
V2=Volume of solution to be prepared = 2.50 L
Using (1), we get
0.376 M x V1 = 0.100 M x 2.50 L
=> V1 = (0.100 M x 2.50 L)/(0.376 M) = 0.665 L = 665 mL
To prepare the 2.50 L of 0.100 M CuSO4, the technician needs 665 mL stock CuSO4 solution. But the technician prepared only 500 mL stock solution. He needs to prepare more stock solution.
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