Question

The following thermochemical equation is for the reaction of hydrogen chloride(g) with ammonia(g) to form ammonium chloride(s
The following thermochemical equation is for the reaction of hydrogen bromide(r) with chlorine() to form hydrogen chloride) a
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Answer #1

Solution :

Part A) The given reaction is,

HCl (g)   + NH3 (g) = NH4Cl (s) , ΔH = -176 kJ/mol

Molar mass of HCl = 36.5 g mol-1

Since, 176.5 kJ heat is obtained from 36.5 g HCl

Hence, 51.9 kJ of heat required

= 51.9 kJ x 36.5 g / 176.5

= 10.73 g

Part B) The reaction of HBr and Cl2 is given as,

2HBr + Cl2 = 2HCl + Br2 , ΔH = -81.1 kJ/mol

Molar mass of HBr = 80.91 g mol-1

Since, 2 mol (2 x 80.91 g) HBr produces 81.1 kJ heat

Hence, 16.4 g will produces

= 16.4 g x 81.1 kJ / (2 x 80.91 g) = 8.219 kJ

= 8.22 kJ

Thus, 8.22 kJ heat is evolved.

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