Homework Answers
Ketone they reaction with base they form enolate ion 
7. Write the at least three differences between kinetic enolate and thermodynamic enolate. 8. Write all...
7. Write the at least three differences between kinetic enolate and thermodynamic enolate. 8. Write all possible products in the reaction given below. (Hint- Cross-aldol reaction) он-
4. (2 pts) Consider the enolate forming reaction below. Provide the structure of the enolate anion...
4. (2 pts) Consider the enolate forming reaction below. Provide the structure of the enolate anion formed in this reaction (only need to provide one resonance contributor). HiC o: H2C Нас pKa -20 pKa -33 Enolate oti (2 pts) Based on the information provided, do you expect the favored enolate to be the kinetic or thermodynamic enolate? Briefly explain.
Draw the structures of the 2 enolate products from the reaction below. One is called the...
Draw the structures of the 2 enolate products from the reaction
below. One is called the "kinetic enolate", and the other is the
"thermodynamic enolate". Which is which, and why?
+ Bi z enolates (draw structures) one called "Kinete enolate" - the other called "Thermodynamic enclate" - which is which & wity ? - Tell are
Question 2: Which of the following enolate ions is formed under thermodynamic conditions? Briefly explain your...
Question 2: Which of the following enolate ions is formed under thermodynamic conditions? Briefly explain your answer. or Enolate #1 Enolate #2
kinetic and thermodynamic products
using energy diagrams and drawing the transitions states of the mechanisms, determine the kinetic and thermodynamic products
Draw the major enolate region-isomer expected from each of these carbon acids under the reaction condition...
Draw the major enolate region-isomer expected from each of these carbon acids under the reaction condition indicated in the incomplete equations. Classify each enolate as either kinetic or thermodynamic (16 pts.) LDA. - 78 on .28 KO-t-Bu t-BUOH KO-t-Bu 1-BUOH
For each of the following reactions, give the major products (kinetic and thermodynamic). (Hint: to determine...
For each of the following reactions, give the major products (kinetic and thermodynamic). (Hint: to determine the major products, consider #2 above) 4. HC HCI a. kinetic thermodynamic kinetic thermodynamic HCI HCI d. C. kinetic thermodynamic kinetic the rm odynamic
12. Show the kinetic and thermodynamic product formed in the reaction of 1,3-dibutene with Br2 and...
12. Show the kinetic and thermodynamic product formed in the
reaction of 1,3-dibutene with Br2 and draw an energy diagram for
both products. Show both products on the same graph with energy on
the Y axis and reaction coordinates on the X axis. (4 points)
12. Show the kinetic and thermodynamic product formed in the reaction of 1,3-dibutene with Bry and draw an energy diagram for both products. Show both products on the same graph with energy on the Y...
4. Complete the kinetic and thermodynamic product of the addition of one HBr to each diene...
4. Complete the kinetic and thermodynamic product of the addition of one HBr to each diene Kinetic Thermodynamic
4. Complete the kinetic and thermodynamic product of the addition of one HBr to each diene...
4. Complete the kinetic and thermodynamic product of the addition of one HBr to each diene Kinetic Thermodynamic
7. Write the at least three differences between kinetic enolate and thermodynamic enolate. 8. Write all possible products in the reaction given below. (Hint- Cross-aldol reaction) он-
4. (2 pts) Consider the enolate forming reaction below. Provide the structure of the enolate anion formed in this reaction (only need to provide one resonance contributor). HiC o: H2C Нас pKa -20 pKa -33 Enolate oti (2 pts) Based on the information provided, do you expect the favored enolate to be the kinetic or thermodynamic enolate? Briefly explain.
Draw the structures of the 2 enolate products from the reaction
below. One is called the "kinetic enolate", and the other is the
"thermodynamic enolate". Which is which, and why?
+ Bi z enolates (draw structures) one called "Kinete enolate" - the other called "Thermodynamic enclate" - which is which & wity ? - Tell are
Question 2: Which of the following enolate ions is formed under thermodynamic conditions? Briefly explain your answer. or Enolate #1 Enolate #2
Draw the major enolate region-isomer expected from each of these carbon acids under the reaction condition indicated in the incomplete equations. Classify each enolate as either kinetic or thermodynamic (16 pts.) LDA. - 78 on .28 KO-t-Bu t-BUOH KO-t-Bu 1-BUOH
For each of the following reactions, give the major products (kinetic and thermodynamic). (Hint: to determine the major products, consider #2 above) 4. HC HCI a. kinetic thermodynamic kinetic thermodynamic HCI HCI d. C. kinetic thermodynamic kinetic the rm odynamic
12. Show the kinetic and thermodynamic product formed in the
reaction of 1,3-dibutene with Br2 and draw an energy diagram for
both products. Show both products on the same graph with energy on
the Y axis and reaction coordinates on the X axis. (4 points)
12. Show the kinetic and thermodynamic product formed in the reaction of 1,3-dibutene with Bry and draw an energy diagram for both products. Show both products on the same graph with energy on the Y...
4. Complete the kinetic and thermodynamic product of the addition of one HBr to each diene Kinetic Thermodynamic
4. Complete the kinetic and thermodynamic product of the addition of one HBr to each diene Kinetic Thermodynamic
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