The alpha-carbon in the enol tautomer of a carbonyl compound is:
a. nucleophilic
b. electrophilic
c. amphiphilic
d. sp2 hybridized as the ketone tautomer
e. sp3 hybridized as the enol tautomer
The alpha-carbon in the enol tautomer of a carbonyl compound is: a. nucleophilic b. electrophilic c....
9) 9) Why do aldehydes undergo nucleophilic addition reactions, whereas esters undergo nucleophilic acyl substitution reactions? A) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. B) Once the nucleophile adds to an aldehyde, neither H- nor R-can be eliminated because they are strongly basic. C) Aldehydes are more sterically hindered than esters. D) The ester carbonyl carbon is sp3 hybridized while the aldehyde carbonyl carbon is sp2 hybridized. E) Once the nucleophile adds to...
Using the compound bank below, indicate the keto or enol tautomer of the given compound. Write the letter that corresponds to your answer in the blank. NOTE: refer to the bank for both the structures of the given and its tautomer. If the tautomer is not included in the bank then write NONE. A D H ОН OH como . B E H к ОН OH -OH OH C F L oi H di tautomer of compound A= tautomer of...
Choline 2. d- Sy2 Nucleophilic subst e- Carbonyl nucleophilic addn HHC a- Electrophilic addition b E2 Elimination d Sy2 Nucleophilic subst e- Carbonyl nucleophilic addn Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a- i for your answers 2. Previous +HO 2. o,SCHs g- Conjugate (nucleophilic) addn Choline 2. d- Sy2 Nucleophilic subst e- Carbonyl nucleophilic addn HHC a- Electrophilic addition b E2 Elimination d Sy2 Nucleophilic subst e-...
How are the carbon and nitrogen atoms hybridized in methylamine, CH3NH2 ? A. Both C and N are hybridized sp2 B. C is hybridized sp2 and N is hybridized sp3 C. C is hybridized sp3 and N is hybridized sp2 D. Both C and N are hybridized sp3
secti 16) The indicated carbon atom is: 16). On A) Nucleophilic because it is electron-deficient. B) Electrophilic because it is electron-deficient C) Electrophilic because it is electron-rich D) Nucleophilic because it is electron-rich. 17) The indicated bond is: 17) Нс A) Electrophilic because it is electron-rich. B) Electrophilic because it is electron-deficient. C) Nucleophilic because it is electron-deficient. D) Nucleophilic because it is electron-rich. 18) 18) Which of the following molecules can bond hydrogen to another molecule of itself? OH...
O H2N-OH 2. нса a Electrophilic addition b-E2 Elimination d- Sy2 Nucleophilic substitution-Nucleophilic subs at carbonyl(acyl Xfer) e-Electrophilic aromatic substitution h -Conjugate (nucleophilic) addn SNI Nucleophilic substitution r-Carbonyl nucleophilic addn Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a -i for your answers. 2. Submit Answor Retry Entire Group 9 more group attempts remaining
Which of the following is an enol tautomer for the ketone listed at right? OH ОН OH (a) i only (b) ii only (C) iii only (e) i and iii
37) Identify the enol tautomer of the following compound. 37) 0 OH OH IV A) I B) II C) III D) IV
4. Which tautomer of phenol is favored and why? A. enol, better hydrogen bonding C. keto, better CO resonance B. enol, aromaticity D. 1:1 both keto and enol forms are favored 5. Which base will completely and irreversibly form the enolate of the compound shown?: ? A. KOH B. NaOH C. NHS D. NaNH2
Learners will be able to perform and/or describe the following regarding Grignard reactions: Reaction to form and consume a Grignard reagent; Reactions of a carbonyl compound with a Grignard reagent to form an alcohol; Know the difference between nucleophilic reactions and electrophilic reactions; and Perform a Grignard synthesis with reasonable yield. Which statement properly states how a Grignard reaction occurs? A. The electrophilic Grignard reagent reacts with the nucleophilic carbonyl compound (i.e. aldehyde or ketone). B. The electrophilic Grignard reagent...