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1. In each of the pairs of compounds below, circle the compound that has a polar...
1. For each pair, circle the molecule with the lower pK and provide a brief explanation...
1. For each pair, circle the molecule with the lower pK and provide a brief explanation for your choice. wale wabon ---- 2. For each molecule, draw the two possible chair conformers and circle the preferred conformer. a) cis-1,3-dimethylcyclohexane trans-1,4-dimethylcyclohexane 3. Draw all distinct isomers of dimethylcyclopropane and show the relationship as enantiomer, diastereomer or meso. 4. In each of the following pairs of compounds one is chiral and the other achiral, Circle the chiral compound in each. a) CH,CHCH=CH...
For each of the following pairs of organic molecules, circle the one that would react with...
For each of the following pairs of organic molecules, circle the one that would react with a given nucleophile at a faster rate in the Sw1 reaction, and briefly explain your choice. нссн, vs. H₂C CH₂ CH Hoc tots vs. Ho C^ots 6. Each of the following carbocations can undergo a rearrangement to give a more stable carbocation. In each case, draw the structure of the rearranged carbocation, and show the mechanism of the 1,2 hydride shift or 1,2-alkyl shift...
1. Draw all resonance structures for the following compound. Circle the major contributor (to the resonance...
1. Draw all resonance structures for the following compound.
Circle the major contributor (to the resonance hybrid) and give a
brief explanation for your choice. (4 pts) 2. Determine the
configuration (show priorities and work) for any chiral centers in
the molecule below. (2 pts)
2. Determine the configuration (show priorities and work) for
any chiral centers in the molecule below. (2 pts)
1. Draw all resonance structures for the following compound. Circle the major contributor (to the resonance hybrid)...
2. Circle the compound in each of the following pairs whose molecules experience stronger London dispersion...
2. Circle the compound in each of the following pairs whose molecules experience stronger London dispersion forces. Explain your rational for each choice. (6.19) (a) C Cloor CzF6 (b) CH4 or C3H8 (c) CS2 or CO2 nteractions Involving Polar Molecules How are water molecules oriented around anions in aqueous solutions? (6.29)
3. a) Draw both chair conformations for the molecule shown below. (2pts) b) Circle the most...
3. a) Draw both chair conformations for the molecule shown
below. (2pts) b) Circle the most stable conformation above. Give a
brief explanation on why your choice is more stable. (2pts)
b) Circle the most stable conformation above. Give a brief
explanation on why your choice is more stable. (2pts)
3. a) Draw both chair conformations for the molecule shown below. (2pts) HO OH b) Circle the most stable conformation above. Give a brief explanation on why your choice is...
V. (1.5 points) 1. For the following compound identify the polar covalent bonds and indicate the...
V. (1.5 points) 1. For the following compound identify the polar covalent bonds and indicate the direction of dipole moment using 8+ and 8-. Of the polar bond you have selected, circle the mot polar bond. (0.75 point) H H 2. Indicate the atomic/hybrid orbitals that are involved in the formation of each o (sigma) and TT (pi) bond, in the following compound. The lone pairs of electrons of the nitrogen and oxygen atom are located in which orbitals? (0.75...
Home day Octo 3. Circle the stronger acid in each of the following pairs. Provide a...
Home day Octo 3. Circle the stronger acid in each of the following pairs. Provide a brief explanation 4. Write out a 3-step mechanism for the following S. I reaction 3. Circle the stronger acid in each of the following pairs. Provide a brief explanation. 4. Write out a 3-step mechanism for the following S 1 reaction. Oo - -
For each of the following pairs of compounds, circle the stronger base.
For each of the following pairs of compounds, circle the stronger base.
6. [4 points] Circle the species in each of the following pairs of atoms that has...
6. [4 points] Circle the species in each of the following pairs of atoms that has the higher first ionization energy (a) Cs or Rb (b) O or Te (c) Cl or Mg (d) Li or Ne 7. [5 points] Write the condensed electron configurations for the following ions (a) Mg Answer: (b) O Answer (c) Fe (d) Mn (e) Ni Answer Answer Answer 8. [4 points] Circle the solid in each of the following sets of ionic compounds that...
For each of the following pairs of compounds, circle the one that is the stronger acid:...
For each of the following pairs of compounds, circle the one that is the stronger acid: Which one of the following is the MOST stable carbocation? Circle the correct answer.
1. For each pair, circle the molecule with the lower pK and provide a brief explanation for your choice. wale wabon ---- 2. For each molecule, draw the two possible chair conformers and circle the preferred conformer. a) cis-1,3-dimethylcyclohexane trans-1,4-dimethylcyclohexane 3. Draw all distinct isomers of dimethylcyclopropane and show the relationship as enantiomer, diastereomer or meso. 4. In each of the following pairs of compounds one is chiral and the other achiral, Circle the chiral compound in each. a) CH,CHCH=CH...
For each of the following pairs of organic molecules, circle the one that would react with a given nucleophile at a faster rate in the Sw1 reaction, and briefly explain your choice. нссн, vs. H₂C CH₂ CH Hoc tots vs. Ho C^ots 6. Each of the following carbocations can undergo a rearrangement to give a more stable carbocation. In each case, draw the structure of the rearranged carbocation, and show the mechanism of the 1,2 hydride shift or 1,2-alkyl shift...
1. Draw all resonance structures for the following compound.
Circle the major contributor (to the resonance hybrid) and give a
brief explanation for your choice. (4 pts) 2. Determine the
configuration (show priorities and work) for any chiral centers in
the molecule below. (2 pts)
2. Determine the configuration (show priorities and work) for
any chiral centers in the molecule below. (2 pts)
1. Draw all resonance structures for the following compound. Circle the major contributor (to the resonance hybrid)...
2. Circle the compound in each of the following pairs whose molecules experience stronger London dispersion forces. Explain your rational for each choice. (6.19) (a) C Cloor CzF6 (b) CH4 or C3H8 (c) CS2 or CO2 nteractions Involving Polar Molecules How are water molecules oriented around anions in aqueous solutions? (6.29)
3. a) Draw both chair conformations for the molecule shown
below. (2pts) b) Circle the most stable conformation above. Give a
brief explanation on why your choice is more stable. (2pts)
b) Circle the most stable conformation above. Give a brief
explanation on why your choice is more stable. (2pts)
3. a) Draw both chair conformations for the molecule shown below. (2pts) HO OH b) Circle the most stable conformation above. Give a brief explanation on why your choice is...
V. (1.5 points) 1. For the following compound identify the polar covalent bonds and indicate the direction of dipole moment using 8+ and 8-. Of the polar bond you have selected, circle the mot polar bond. (0.75 point) H H 2. Indicate the atomic/hybrid orbitals that are involved in the formation of each o (sigma) and TT (pi) bond, in the following compound. The lone pairs of electrons of the nitrogen and oxygen atom are located in which orbitals? (0.75...
Home day Octo 3. Circle the stronger acid in each of the following pairs. Provide a brief explanation 4. Write out a 3-step mechanism for the following S. I reaction 3. Circle the stronger acid in each of the following pairs. Provide a brief explanation. 4. Write out a 3-step mechanism for the following S 1 reaction. Oo - -
For each of the following pairs of compounds, circle the stronger base.
6. [4 points] Circle the species in each of the following pairs of atoms that has the higher first ionization energy (a) Cs or Rb (b) O or Te (c) Cl or Mg (d) Li or Ne 7. [5 points] Write the condensed electron configurations for the following ions (a) Mg Answer: (b) O Answer (c) Fe (d) Mn (e) Ni Answer Answer Answer 8. [4 points] Circle the solid in each of the following sets of ionic compounds that...
For each of the following pairs of compounds, circle the one that is the stronger acid: Which one of the following is the MOST stable carbocation? Circle the correct answer.
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